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We demonstrate midinfrared second-harmonic generation as a highly sensitive phonon spectroscopy technique that we exemplify using $\alpha$-quartz (SiO$_2$) as a model system. A midinfrared free-electron laser provides direct access to…

Using a free-running distributed-feedback quantum cascade laser (QCL) emitting at 9.54 $\mu$m, the pressure shift parameters of four intense rovibrational transitions in the $\nu_3$ fundamental band of ozone induced by oxygen (O$_2$), air…

We present an experimental scheme that produces Doppler-free spectra of the $5s \to 6p $ second resonance transition in atomic rubidium. The experiment uses the saturation of the cascade fluorescence that occurs when thermal rubidium atoms…

Previously unobserved nitrous oxide transitions around 2.5 $\mu$m are measured by intracavity laser absorption spectroscopy (ICLAS) analyzed by time-resolved Fourier transform (TRFT) spectrometer. With an accuracy of the order of 10^-3…

Chemical Physics · Physics 2016-08-16 Hervé Herbin , Nathalie Picqué , Guy Guelachvili , Evgeni Sorokin , Irina T. Sorokina

Nanomechanical spectroscopy (NMS) is a recently developed approach to determine optical absorption spectra of nanoscale materials via mechanical measurements. It is based on measuring changes in the resonance frequency of a membrane…

We have performed measurements of the IR absorption of $\text{SiO}_2$ nanoparticles confined in an argon radio-frequency plasma discharge using an FTIR spectrometer. By varying the gas pressure of the discharge and duty cycle of the applied…

Plasma Physics · Physics 2021-11-03 Harald Krüger , Elena Thiessen , Franz Xaver Bronold , Holger Fehske , André Melzer

We report absorption and photoluminescence spectra of Si and SnO$_2$ polycrystalline nanofilms in the UV-Vis-NIR range, featuring discrete bands resulting from transverse quantum confinement. The film thickness ranged 3.9 nm to 12.2 nm,…

Mesoscale and Nanoscale Physics · Physics 2014-05-21 Vladimir I. Makarov , Igor Khmelinskii

We demonstrate coherent Doppler-free three-photon excitation of the $^{1}S_{0}$$\leftrightarrow$$^{3}P_{0}$ optical clock transition and the $^{1}S_{0}$$\leftrightarrow$$^{3}P_{1}$ intercombination transition in free-space thermal clouds of…

Atomic Physics · Physics 2024-12-24 Guglielmo Panelli , Shaun C. Burd , Erik J. Porter , Mark Kasevich

We present a versatile mid-infrared frequency comb spectroscopy system based on a doubly resonant optical parametric oscillator tunable in the 3-5.4 {\mu}m range and two detection methods, a Fourier transform spectrometer (FTS) and a…

We report the observation of interband two-photon absorption (TPA) saturation in cadmium sulfide nanocrystals (CdS NCs) under intense femtosecond laser excitation with 1.6-eV photon energy. The observation has been compared to interband TPA…

Materials Science · Physics 2007-05-23 Jun He , Jun Mi , Heping Li , Wei Ji

We present a modified approach to laser optical-feedback cavity-enhanced absorption spectroscopy. The technique involves continuously scanning the length of a high-finesse cavity to periodically lock a diode laser to the cavity resonance,…

Optics · Physics 2024-09-04 Christopher A. Curwen , Mathieu Fradet , Ryan M. Briggs

We show that the Second Derivative (SD) technique of the absorption spectra of Rb atomic vapours confined in a nanocell with a thickness $\ell= \lambda/2=398$ nm allows to achieve close to Doppler-free spectroscopy. Narrow linewidth and…

Atomic Physics · Physics 2020-08-26 Armen Sargsyan , Arevik Amiryan , Emmanuel Klinger , David Sarkisyan

We report on a comb-locked cavity ring-down spectrometer developed for high-precision, SI-traceable, molecular spectroscopy of air-broadened CO2 gas samples. The experimental setup relies on the use of a singly-resonant optical parametric…

We report the most accurate measurement of the position of the weak quadrupole S(2) 2-0 line in D$_2$. The spectra were collected with a frequency-stabilized cavity ring-down spectrometer (FS-CRDS) with an ultra-high finesse optical cavity…

We present a new technique using a frequency comb laser and optical cavities for performing ultrafast transient absorption spectroscopy with improved sensitivity. Resonantly enhancing the probe pulses, we demonstrate a sensitivity of…

Optics · Physics 2016-04-05 Melanie A. R. Reber , Yuning Chen , Thomas K. Allison

Nonlinear optical effects can be enhanced in tapered optical fibers with diameters less than the wavelength of the propagating light. Here we report on the observation of two-photon absorption using tapered fibers in rubidium vapor at power…

Quantum Physics · Physics 2010-10-22 S. M. Hendrickson , M. M. Lai , T. B. Pittman , J. D. Franson

In this paper, we present experimental techniques to resolve the closely spaced hyperfine levels of a weak transition by eliminating the residual/partial two-photon Doppler broadening and cross-over resonances in a wavelength mismatched…

Atomic Physics · Physics 2021-01-21 Elijah Ogaro Nyakang'o , Kanhaiya Pandey

We introduce a toluene-filled fiber platform for two-photon absorption measurements. By confining both the light and molecular sample inside the 5 $\mu$m hollow core of the fiber, we increase the distance over which the nonlinear…

Accurate parameters of molecular hot-band transitions, i.e., those starting from vibrationally excited levels, are needed to accurately model high-temperature spectra in astrophysics and combustion, yet laboratory spectra measured at high…

We report on the direct mapping of electron transfer in the momentum space of bulk MoS$_2$ by means of time- and angle-resolved two-photon photoemission with a high-harmonic probe. For this purpose, we have combined a high-repetition rate…

Mesoscale and Nanoscale Physics · Physics 2016-10-20 Robert Wallauer , Johannes Reimann , Nico Armbrust , Jens Güdde , Ulrich Höfer