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New generation Indium based lead-free Cs2InAgCl6 is a promising halide material in photovoltaic applications due to its good air stability and non-toxic behavior. But its wide band gap (>3 eV) is not suitable for solar spectrum and hence…

Materials Science · Physics 2022-05-10 K. C. Bhamu , Enamul Haque , C. S. Praveen , Nandha Kumar , G. Yumnam , M. Anwar Hossain , Gautam Sharma

Doping plays a key role in functionalizing semiconductor devices, yet traditional chemical approaches relying on foreign-atom incorporation suffer from doping-asymmetry, pronounced lattice disorder and constrained spatial resolution. Here,…

Materials Science · Physics 2025-05-12 Bo Zhang , Hui Xia , Zhengdong Huang , Yaqian Liu , Jun Kang , Liaoxin Sun , Tianxin Li , Su-Huai Wei , Wei Lu

We investigate how field-effect doping affects the structural properties, the electronic structure and the Hall coefficient of few-layers transition metal dichalcogenides by using density-functional theory. We consider mono-, bi-, and…

Mesoscale and Nanoscale Physics · Physics 2015-05-05 Thomas Brumme , Matteo Calandra , Francesco Mauri

We present a first-principles study of the electronic, magnetic, and transport properties of the topological insulator Bi$_{2}$Te$_{3}$ doped with Mn atoms in substitutional (Mn$_{\rm Bi}$) and interstitial van der Waals gap positions…

Materials Science · Physics 2016-06-15 K. Carva , J. Kudrnovský , F. Máca , V. Drchal , I. Turek , P. Baláž , V. Tkáč , V. Holý , V. Sechovský , J. Honolka

PbPdO$_2$, a ternary compound containing the lone-pair active ion Pb$^{2+}$ and the square-planar d$^8$ Pd$^{2+}$ ion, has attracted recent interest because of the suggestion that its electronic structure, calculated within density…

Materials Science · Physics 2011-11-03 Joshua A. Kurzman , Mao-Sheng Miao , Ram Seshadri

By a combined experimental and theoretical approach, we investigate normal state thermoelectric transport in MgB2, as a probe of selective disorder and doping in the sigma and pi bands. We calculate the temperature dependent diffusive…

Superconductivity · Physics 2023-05-01 Ilaria Pallecchi , Marco Monni , Pietro Manfrinetti , Marina Putti

Preparation of solid solutions represents an effective means to improve the photocatalytic properties of semiconductor-based materials. Nevertheless, the effects of site-occupancy disorder on the mixing stability and electronic properties…

Materials Science · Physics 2018-12-11 Joel Shenoy , Judy N. Hart , Ricardo Grau-Crespo , Neil L. Allan , Claudio Cazorla

We theoretically investigate Sn(II) phosphates as optoelectronic materials using first principles calculations. We focus on known prototype materials Sn$_n$P$_2$O$_{5+n}$ (n=2, 3, 4, 5) and a previously unreported compound, SnP$_2$O$_6$…

Materials Science · Physics 2016-12-06 Qiaoling Xu , Yuwei Li , Lijun Zhang , Weitao Zheng , David J. Singh , Yanming Ma

We realize Mn $\delta$-doping into Si and Si/Ge interfaces using Mn atomic chains on Si(001). Highly sensitive X-ray absorption fine structure techniques reveal that encapsulation at room temperature prevents the formation of silicides /…

The electronic structures of Mn-doped zincblende GaAs and wurtzite GaN are calculated using both standard local-density functional theory (LSDA), and a novel pseudopotential self-interaction-corrected approach (pseudo-SIC), able to account…

Mesoscale and Nanoscale Physics · Physics 2025-06-10 Alessio Filippetti , Nicola A. Spaldin , Stefano Sanvito

Although $\beta$-TeO$_2$ is a promising $p$-type transparent conducting oxide (TCO) due to the large optical gap ($\sim$ 3.7 eV) and a light effective hole mass, its hole dopability still remains unexplored. In this work, electronic…

Materials Science · Physics 2025-11-20 Vu Thi Ngoc Huyen , Soungmin Bae , Rafael Costa-Amaral , Yu Kumagai

We investigate the electronic and magnetic properties of Mn-doped CdTe nanocrystals (NCs) with 2 nm in diameter which can be experimentally synthesized with Mn atoms inside. Using the density-functional theory, we consider two doping cases:…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 C. Echeverría-Arrondo , J. Pérez-Conde , A. Ayuela

Motivated by a recent theoretical suggestion that doping electrons into various CaAl$_2$Si$_2$-type Zintl phase compounds may give rise to high thermoelectric performance, we explore the possibility of n-type (electron carrier) doping of…

Materials Science · Physics 2022-06-01 Kazutaka Nishiguchi , Masayuki Ochi , Chul-Ho Lee , Kazuhiko Kuroki

We have performed first-principles investigations on the native defects in the full Heusler alloys Co$_2$Ti$Z$ ($Z$ one of the group IV elements Si, Ge, Sn), determining their formation energies and how they influence the transport…

Materials Science · Physics 2017-09-06 Voicu Popescu , Peter Kratzer , Sebastian Wimmer , Hubert Ebert

Mg2NiH4 is a promising hydrogen storage material with fast (de)hydrogenation kinetics. Its hydrogen desorption enthalpy, however, is too large for practical applications. In this paper we study the effects of transition metal doping by…

Materials Science · Physics 2007-09-11 M. J. van Setten , G. A. de Wijs , G. Brocks

Realistic oxide materials are often semiconductors, in particular at elevated temperatures, and their surfaces contain undercoordiated atoms at structural defects such as steps and corners. Using hybrid density-functional theory and ab…

Mn ions' doping site and valence were studied in PbTiO$_{3}$ (PT) with the native vacancy defects by the first-principles calculations. Firstly, the native vacancy defects of Pb, O and Ti in PT were investigated and it was found that Pb…

Materials Science · Physics 2021-06-28 H. Xin , Q. Pang , D. L. Gao , L. Li , P. Zhang , J. Zhao

Various types of defects in MoS2 monolayers and their influence on the electronic structure and transport properties have been studied using the Density-Functional based Tight-Binding method in conjunction with the Green's Function…

Materials Science · Physics 2014-03-04 Mahdi Ghorbani-Asl , Andrey N. Enyashin , Agnisezka Kuc , Gotthard Seifert , Thomas Heine

In this work, doping-defect interactions relevant to self-compensation in p-type GaN were investigated using atom probe tomography. The 3D visualization of ion distribution revealed the formation of spherical Mg-rich clusters and the…

We use hybrid density functional calculations to assess n-type doping in monoclinic (Al$_x$Ga$_{1-x}$)$_2$O$_3$ alloys. We focus on Si, the most promising donor dopant, and study the structural properties, formation energies and…

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