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We theoretically investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the…

Mesoscale and Nanoscale Physics · Physics 2013-06-14 Aitzol Garcia-Etxarri , Jennifer A. Dionne

Strong enhancement of molecular circular dichroism has the potential to enable efficient asymmetric photolysis, a method of chiral separation that has conventionally been impeded by insufficient yield and low enantiomeric excess. Here, we…

In the close vicinity of a chiral nanostructure, the circular dichroism of a biomolecule could be greatly enhanced, due to the interaction with the local superchiral fields. Modest enhancement of optical activity using a planar…

Circular dichroism (CD), induced by chirality, is an important tool for manipulating light or for characterizing morphology of molecules, proteins, crystals and nano-structures. CD is manifested over a wide size-range, from molecules to…

Chirality is ubiquitous in nature and fundamental in science, from particle physics to metamaterials.The most established technique of chiral discrimination - photoabsorption circular dichroism - relies on the magnetic properties of a…

DNA and proteins are chiral: their three-dimensional structure cannot be superimposed with its mirror image. Circular dichroism spectroscopy is widely used to characterize chiral compounds, but data interpretation is difficult in the case…

Biomolecules · Quantitative Biology 2020-09-09 Steven Daly , Frederic Rosu , Valerie Gabelica

Chiral and axial materials offer platforms for intriguing phenomena, such as cross-correlated responses and chirality-induced spin selectivity. However, quantifying the properties of such materials has generally been considered challenging.…

Materials Science · Physics 2025-10-07 Tatsuya Miki , Hiroaki Ikeda , Michi-To Suzuki , Shintaro Hoshino

The emergence of optical circular dichroism in chiral nanoscale and molecular systems provides not only a way for analyzing the sample chirality itself but also additional degrees of freedom in manipulating light. Such manipulation can be…

Mesoscale and Nanoscale Physics · Physics 2026-02-18 Marek Zálešák , Martin Ošmera , Martin Hrtoň , Andrea Konečná

Spectroscopic techniques that are sensitive to molecular chirality are important analytical tools to quantitatively determine enantiomeric excess and purity of chiral molecular samples. Many chiroptical processes however produce weak…

Chemical Physics · Physics 2026-04-02 Sebastian Hartweg , Dusan k. Bozanic , Gustavo A. Garcia-Macias , Laurent Nahon

Chirality is at the origin of life and is ubiquitous in nature. An object is deemed chiral if it is non-superimposable with its own mirror image. This relates to how circularly polarized light interacts with such object, a circular…

Linear polarization analysis of hard x-rays is employed to probe electronic anisotropies in metal-containing complexes with very high selectivity. We use the pronounced linear dichroism of nuclear resonant x-ray scattering to determine…

Mirror symmetry is among the most fundamental concepts of physics and its spontaneous breaking at the molecular level allows chiral molecules to exist in two enantiomers that are mirror images of each other. The majority of chiro-optical…

Optics · Physics 2021-09-29 Alessandro Ciattoni

Conventional linear optical activity effects are widely used for studying chiral materials. However, poor contrast and artifacts due to sample anisotropy limit the applicability of these methods. Here we demonstrate that nonlinear…

Biological Physics · Physics 2016-02-16 Mei-Yu Chen , Mikko J. Huttunen , Che-Wei Kan , Yen-Yin Lin , Cin-Wei Ye , Meng-Jer Wu , Hsiang-Lin Liu , Shi-Wei Chu

Chirality is an intriguing property of certain molecules, materials or artificial nanostructures, which allows them to interact with the spin angular momentum of the impinging light field. Due to their chiral geometry, they can distinguish…

Optics · Physics 2016-11-03 Peter Banzer , Pawel Wozniak , Uwe Mick , Israel De Leon , Robert W. Boyd

Chiral spectroscopy is a powerful technique that enables to identify the chirality of matter through optical means. So far, experiments to check the chirality of matter or nanostructures have been carried out using free-space propagating…

Optics · Physics 2019-11-26 J. Enrique Vázquez-Lozano , Alejandro Martínez

We propose a chiral imaging modality based on optical chirality engineering, fluorescence-detected circular dichroism and structured illumination microscopy. In this method, the optical chirality of the illumination is structured and the…

Dark-field illumination is shown to make planar chiral nanoparticle arrangements exhibit circular dichroism in extinction analogous to true chiral scatterers. Circular dichrosim is experimentally observed at the maximum scattering of single…

Increasing the sensitivity of chiral spectroscopic techniques such as circular dichroism (CD) spectroscopy is a current aspiration in the research field of nanophotonics. Enhancing CD spectroscopy depends upon of two complementary…

In photoelectron circular dichroism (PECD) it is generally difficult to trace how and when the chirality of the molecule is imprinted onto the photoelectron. We present simulations of PECD in a simple model and employ chirality measures to…

Atomic Physics · Physics 2025-03-04 Marec W. Heger , Daniel M. Reich

Chirality refers to a geometric phenomenon in which objects are not superimposable on their mirror image. Structures made of nano-scale chiral elements can display chiroptical effects, such as dichroism for left- and right- handed…

Optics · Physics 2020-02-25 Behrooz Semnani , Jeremy Flannery , Rubayet Al Maruf , Michal Bajcsy
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