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We theoretically demonstrate the ability of electron beams to probe the nonlinear photonic response with nanometer spatial resolution, well beyond the capabilities of existing optical techniques. Although the interaction of electron beams…

Mesoscale and Nanoscale Physics · Physics 2020-12-30 Andrea Konečná , Valerio Di Giulio , Vahagn Mkhitaryan , Claus Ropers , F. Javier García de Abajo

Chirality causes symmetry breaks in a large variety of natural phenomena ranging from particle physics to biochemistry. We investigate one of the simplest conceivable chiral systems, a laser-excited, oriented, effective one-electron Li…

Light interaction with rotating nanostructures gives rise to phenemona as varied as optical torques and quantum friction. Here we reveal that circular dichroism of rotating optically-isotropic particles has an unexpectedly strong dependence…

Mesoscale and Nanoscale Physics · Physics 2019-08-14 Deng Pan , Hongxing Xu , F. Javier García de Abajo

It has been long recognized that the spatial polarization of the electronic clouds in molecules, and the spatial arrangements of atoms into chiral molecular structures, play crucial roles in physics, chemistry and biology. However, these…

Optics · Physics 2020-04-14 David Ayuso , Andres Ordonez , Piero Decleva , Misha Ivanov , Olga Smirnova

Sometimes it appears, sometimes it does not. We present a theoretical study of circular dichroism in the second-harmonic signal of single dielectric nanostructures with different symmetries and noncentrosymmetric materials. We show that…

Optics · Physics 2023-01-24 Anastasia Nikitina , Anna Nikolaeva , Kristina Frizyuk

In this work we propose a method for probing the chirality of nanoscale electromagnetic near fields utilizing the properties of a coherent superposition of free-electron vortex states in electron microscopes. Electron beams optically…

We investigate how the direction of polarized light can affect the dichroism pattern seen in angle-resolved photoemission spectroscopy. To this end, we prepared a sample composed of highly-oriented Bi(111) micro-crystals that…

Strongly Correlated Electrons · Physics 2020-07-07 Y. Ishida , D. Chung , J. Kwon , Y. S. Kim , S. Soltani , Y. Kobayashi , A. J. Merriam , L. Yu , C. Kim

We describe a new experimental setup for the detection of magnetic circular dichroism with fast electrons (EMCD). As compared to earlier findings the signal is an order of magnitude higher, while the probed area could be significantly…

Photons experience mirror asymmetry of macroscopic chiral media, as in circular dichroism and polarization rotation, since left and right handed circular polarizations differently couple with matter handedness. Conversely, free relativistic…

Quantum Physics · Physics 2022-04-08 Alessandro Ciattoni

The occurrence of biological homochirality is attributed to symmetry breaking mechanisms which are still debatable1. Studies of symmetry breaking require tools for monitoring the population ratios of individual chiral nano-objects, such as…

Optics · Physics 2018-08-20 Eitam Vinegrad , Uri Hananel , Gil Markovich , Ori Cheshnovsky

We propose a highly efficient atomically-resolved mode of electron magnetic chiral dichroism. This method exploits the recently introduced orbital angular momentum spectrometer to analyze the inelastically scattered electrons allowing for…

Optically active achiral metasurfaces offer a promising way to detect chiral molecules based on chiroptic methods. The combination of plasmonic enhanced circular dichroism and reversible optical activity would boost the sensitivity and…

Correlative light and electron microscopy promises to combine molecular specificity with nanoscale imaging resolution. However, there are substantial technical challenges including reliable co-registration of optical and electron images,…

Maximum structural chirality refers to the highest selectivity for circularly polarized light (CPL) in nanostructures, often manifested as maximum circular dichroism (CD), optical rotation (OR), and spin-orbit coupling (SOC). However, the…

Optics · Physics 2025-04-29 WenKui Zhao , ShengYi Wang , HanZhuo Kuang , Hao Luo , Qiu Wang , Bo-Wen Jia

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

Optics · Physics 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

Over the past two decades, metamaterials have led to an increasing number of biosensing and nanophotonic applications due to the possibility of a careful control of light propagating through subwavelength features. Chiral nanostructures…

The chirality of an object can be studied by measuring the circular dichroism, that is, the difference in absorption of light with different helicity. The chiral optical response of an object, however, can have two different origins. On the…

We propose an approach to sensitively probe the chirality of molecules by measuring their coherent optical absorption spectra. It is shown that quantum dynamics of the cyclic three-level chiral molecules driven by appropriately-designed…

Quantum Physics · Physics 2015-05-28 W. Z. Jia , L. F. Wei

Nanophotonic platforms in theory uniquely enable < femtomoles of chiral biological and pharmaceutical molecules to be detected, through the highly localised changes in the chiral asymmetries of the near-fields that they induce. However,…

Two paramount challenges in carbon nanotube research are achieving chirality-controlled synthesis and understanding chirality-dependent device physics. High-throughput and in-situ chirality and electronic structural characterization of…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Kaihui Liu , Xiaoping Hong , Qin Zhou , Chenhao Jin , Jinghua Li , Weiwei Zhou , Jie Liu , Enge Wang , Alex Zettl , Feng Wang