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Structural changes in REMnO3 (RE= Y, Ho, Lu) under high pressure were examined by synchrotron x-ray diffraction methods at room temperature. Compression occurs more readily in the ab plane than along the c-axis. Under hydrostatic pressure…

Materials Science · Physics 2015-05-20 P. Gao , Z. Chen , T. A. Tyson , T. Wu , K. H. Ahn , Z. Liu , R. Tappero , S. B. Kim , S. -W. Cheong

Controlling the Mott transition through strain engineering is crucial for advancing the development and application of memristive and neuromorphic computing devices. Yet, Mott insulators are heterogeneous due to intrinsic phase boundaries…

Materials Science · Physics 2024-07-02 Ziming Shao , Aileen Luo , Eti Barazani , Tao Zhou , Zhonghou Cai , Martin V. Holt , Yoav Kalcheim , Andrej Singer

We have measured the V 2p3/2 and O 1s x-ray absorption spectra of single crystal V2O5 and V6O13 and compared to linear combinations of atomic orbitals (LCAO) density of states (DOS) calculations. The spectra change dramatically with…

Condensed Matter · Physics 2009-10-22 E. Goering , O. Müller , M. Klemm , J. P. Urbach , H. Petersen , C. Jung , M. L. denBoer , S. Horn

In this article, we demonstrate the viability of highly monochromatic full-field X-ray absorption near edge structure based tomography using a laboratory-scale Johann-type X-ray absorption spectrometer based on a conventional X-ray tube…

Instrumentation and Detectors · Physics 2022-10-04 Ari-Pekka Honkanen , Simo Huotari

We have studied the electronic structure of unoccupied states measured by O K-edge and Cu L-edge x-ray absorption spectroscopy (XAS), combined with crystal structure studied by high resolution powder x-ray diffraction (HRPXRD), of…

Superconductivity · Physics 2014-03-28 S. Agrestini , S. Sanna , K. Zheng , R. De Renzi , E. Pusceddu , G. Concas , N. L. Saini , A. Bianconi

We have measured the intricate temperature dependence of the Co L2,3 x-ray absorption spectra (2p-3d excitations) of CoO. To allow for accurate total electron yield measurements, the material has been grown in thin film form on a metallic…

Strongly Correlated Electrons · Physics 2008-06-24 M. W. Haverkort , A. Tanaka , Z. Hu , H. H. Hsieh , H. -J. Lin , C. T. Chen , L. H. Tjeng

Wide bandgap semiconductor heterostructures based on nanowires have attracted great interest as one of the nanoscale building blocks for the development of novel optoelectronic devices. Owing to the critical role of heterogeneities and…

Enhanced optical absorption of molecules in the vicinity of metallic nanostructures is key to a number of surface-enhanced spectroscopies and of great general interest to the fields of plasmonics and nano-optics. Yet, experimental access to…

The adsorption of polymer and surfactant molecules onto colloidal particles or droplets in solution can be characterized non-destructively by scattering techniques. In a first part, the general framework of Dynamic Light Scattering, Small…

Soft Condensed Matter · Physics 2007-05-24 Julian Oberdisse

V2O3 is an archetypal system for the study of correlation induced, Mott-Hubbard metal-insulator transitions. Despite decades of extensive investigations, the accurate description of its electronic properties remains an open problem in the…

The angular distribution of the intensity in photoemission experiments is affected by electron diffraction patterns and by a smoothly varying ISO contribution originated by both intrumental details and physical properties of the samples.…

Materials Science · Physics 2007-05-23 F. Bruno , L. Floreano , A. Verdini , D. Cvetko , R. Gotter , A. Morgante , M. Canepa , S. Terreni

Photoabsorption of atomic oxygen in the energy region below the $\rm 1s^{-1}$ threshold in x-ray spectroscopy from {\it Chandra} and {\it XMM-Newton} is observed in a variety of x-ray binary spectra. Photoabsorption cross sections…

High Energy Astrophysical Phenomena · Physics 2015-06-16 B. M. McLaughlin , C. P. Ballance , K. P. Bowen , D. J. Gardenghi , W. C. Stolte

The high-pressure behavior of silicon telluride (Si2Te3), a two-dimensional (2D) layered material, was investigated using synchrotron X-ray powder diffraction in a diamond anvil cell to 11.5 GPa coupled with first-principles theory. Si2Te3…

Materials Science · Physics 2024-10-10 Bohan Li , Frank Cerasoli , Ethan Chen , Martin Kunz , Davide Donadio , Kristie J. Koski

Until now, the spectral changes observed from persistent to dipping intervals in dipping low-mass X-ray binaries were explained by invoking progressive and partial covering of an extended emission region. Here, we propose a novel and…

Astrophysics · Physics 2009-11-11 L. Boirin , M. Diaz Trigo , M. Mendez , A. N. Parmar , J. S. Kaastra

We present an ab initio description of optical and shallow-core x-ray absorption spectroscopies in a unified formalism based on the pseudopotential plane-wave method at the level of the Bethe-Salpeter equation (BSE) within Green's functions…

Materials Science · Physics 2023-06-07 M. Laura Urquiza , Matteo Gatti , Francesco Sottile

The present paper deals with the results of a research work on the optical properties of colloidal InP/ZnS nanocrystals stabilized with a heterobifunctional polyvinylpyrrolidone polymer. We have analyzed the absorption and photoluminescence…

Materials Science · Physics 2023-01-31 S. S. Savchenko , A. S. Vokhmintsev , M. S. Karabanalov , A. M. A. Henaish , I. A. Weinstein

Based on ab initio density-functional-theory using generalized gradient approximation, we systematically study the optical and electronic properties of the insulating dense sodium phase (Na-hp4) reported recently [Ma \textit{et al.}, Nature…

Materials Science · Physics 2015-05-18 Dafang Li , Hanyu Liu , Bao-Tian Wang , Hongliang Shi , Shao-Ping Zhu , Jun Yan , Ping Zhang

In situ high-pressure energy dispersive x-ray diffraction experiments on polycrystalline powder TiN with NaCl-type structure have been conducted with the pressure up to 30.1 GPa by using the diamond anvil cell instrument with synchrotron…

Materials Science · Physics 2009-11-11 J. G. Zhao , L. X. Yang , Y. Yu , S. J. You , R. C. Yu , L. C. Chen , F. Y. Li , C. Q. Jin , X. D. Li , Y. C. Li , J. Liu

We develop a first-principles theory of phonon-assisted optical absorption in semiconductors and insulators which incorporates the temperature dependence of the electronic structure. We show that the Hall-Bardeen-Blatt theory of indirect…

Materials Science · Physics 2015-10-22 Marios Zacharias , Christopher E. Patrick , Feliciano Giustino

We report a novel high pressure structural sequence for the functionally graded thermoelectric, narrow band gap semiconductor AgSbTe$_{2}$, using angle dispersive x-ray diffraction in a diamond anvil cell with synchrotron radiation at room…