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The pressure dependence of light-induced effects in single-crystalline BiFeO$_3$ is studied by optical spectroscopy. At low pressures, we observe three light-induced absorption features with energies just below the two crystal field…

Materials Science · Physics 2019-10-31 F. Meggle , J. Ebad-Allah , J. Kreisel , C. A. Kuntscher

We have extended the range of the high-pressure optical spectroscopy to the far-infrared region keeping the accuracy of ambient-pressure experiments. The newly-developed method offers a powerful tool for the study of pressure-induced phase…

Strongly Correlated Electrons · Physics 2014-01-15 I. Kezsmarki , R. Gaal , C. C. Homes , B. Sipos , H. Berger , S. Bordacs , G. Mihaly , L. Forro

X-ray interaction with matter is an energy-dependent process that is contingent on the atomic structure of the constituent material elements. The most advanced models to capture this relationship currently rely on Monte Carlo (MC)…

Machine Learning · Computer Science 2023-07-11 Raziye Kubra Kumrular , Thomas Blumensath

Transient X-ray absorption techniques can measure ultrafast dynamics of the elemental edges in a material or multiple layer junction, giving them immense potential for deconvoluting concurrent processes. However, the interpretation of the…

Materials Science · Physics 2021-06-10 Hanzhe Liu , Isabel M. Klein , Jonathan M. Michelsen , Scott K. Cushing

Photoabsorption spectra of N$_2$ and CO were recorded at 900K, using the vacuum-ultraviolet Fourier-transform spectrometer at the DESIRS beamline of synchrotron SOLEIL. These high-temperature and high-resolution measurements allow for…

The present paper demonstrates the feasibility of X-ray Absorption Spectroscopy (XAS) and X-ray Magnetic Circular Dichroism (XMCD) at high pressure at the Fe-K edge on the ID24 energy dispersive beamline of the ESRF. In 3d transition…

Instrumentation and Detectors · Physics 2007-05-23 Olivier Mathon , Francois Baudelet , Jean-Paul Itie , Sebastien Pasternak , Alain Polian , Sakura Pascarelli

Unprecedented bright and intense synchrotron X-rays have been widely used to unravel numerous compelling electronic and structural properties using a large variety of physical techniques, while the puzzling phenomenon is the uncertainties…

Materials Science · Physics 2017-05-09 Xinguo Hong , Matt Newville , Ho-Kwang Mao , T. Irifune , L. Huang

Recent advances of highly efficient solar cells based on organic-inorganic halide perovskites have triggered intense research efforts to establish the fundamental properties of these materials. In this work, we utilized diamond anvil cell…

Materials Science · Physics 2015-09-15 Kai Wang , Ran Liu , Yuancun Qiao , Jinxing Cui , Bo Song , Bingbing Liu , Bo Zou

In this work, we study the influence of the average crystallite size and dopant oxide on the reducibility of CeO2-based nanomaterials. Samples were prepared from commercial Gd2O3-, Sm2O3- and Y2O3-doped CeO2 powders by calcination at…

X-ray powder diffraction using a synchrotron light source reveals significant modifications to both morphology and strain state in Palladium nanocubes after oxidation. Short-range strain measured by the static component of the Debye-Waller…

Materials Science · Physics 2021-02-03 Binayak Mukherjee , Alberto Flor , Paolo Scardi

A Monte Carlo program based on a three dimensional vector approach was developed to model multiple refractive scattering of X-ray photons in objects with a fine structure. A particular interest was paid to the investigation of lung tissue.…

Medical Physics · Physics 2010-02-02 Anastasiya Khromova

We report here a study of reversible pressure-induced structural transformation between two amorphous forms of SO$_2$: molecular at pressures below 26 GPa and polymeric above this pressure, at temperatures of 77 - 300 K. The transformation…

We report the first high pressure measurement of the Fe K-edge in hematite (Fe$_2$O$_3$) by X-ray absorption spectroscopy in partial fluorescence yield geometry. The pressure-induced evolution of the electronic structure as Fe$_2$O$_3$…

Optical absorption spectra of nanocrystalline cupric oxide CuO samples, obtained using the converging spherical shock wave procedure, reveal significant spectral weight red-shift as compared with spectra of single crystalline CuO samples.…

Strongly Correlated Electrons · Physics 2007-05-23 B. A. Gizhevskii , Yu. P. Sukhorukov , N. N. Loshkareva , A. S. Moskvin , E. V. Zenkov , E. A. Kozlov

High-pressure synchrotron based angle dispersive x-ray diffraction (ADXRD) studies were carried out on SmGdO3 (SGO) up to 25.7GPa at room temperature. ADXRD results indicated a reversible pressure-induced phase transition from ambient…

Materials Science · Physics 2015-06-22 Yogesh Sharma , Pankaj Misra , Satyaprakash Sahoo , A. K. Mishra , S. M. Sharma , Ram S. Katiyar

A spectrograph is an optical instrument that disperses photons of different energies into distinct directions and space locations, and images photon spectra on a position-sensitive detector. Spectrographs consist of collimating, angular…

Optics · Physics 2015-06-11 Yuri Shvyd'ko

X-ray absorption spectroscopy is a well established tool for obtaining information about orbital and spin degrees of freedom in transition metal- and rare earth-compounds. For this purpose usually the dipole transitions of the L- (2p to 3d)…

Strongly Correlated Electrons · Physics 2014-02-21 P. Hansmann , M. W. Haverkort , A. Toschi , G. Sangiovanni , F. Rodolakis , J. P. Rueff , M. Marsi , K. Held

A new experimental setup combining X-Ray Photon Correlation Spectroscopy (XPCS) in the hard x-ray regime and a high-pressure sample environment is developed to monitor the pressure dependence of the internal motion of complex systems down…

X-ray characterisation methods have undoubtedly enabled cutting-edge advances in all aspects of materials research. Despite the enormous breadth of information that can be extracted from these techniques, the challenge of radiation-induced…

Thermoelectric (Bi1-x Sbx)2Te3 (BST-x) compounds with x=0.2, 0.7 and 0.9 have been studied using synchrotron angle-dispersive powder x-ray diffraction in a diamond anvil cell up to 25 GPa (at room temperature). The results clearly indicate…

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