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Two-dimensional (2D) materials such as graphene and hexagonal boron nitride (hBN) provide a versatile platform for quantum electronics. Experiments generally require encapsulating graphene within hBN flakes, forming a protective van der…

Integration of electrical contacts into van der Waals (vdW) heterostructures is critical for realizing electronic and optoelectronic functionalities. However, to date no scalable methodology for gaining electrical access to buried monolayer…

Hyperbolic phonon polaritons (HPhPs) sustained in van der Waals (vdW) materials exhibit extraordinary capabilities of confining long-wave electromagnetic fields to the deep subwavelength scale. In stark contrast to the uniaxial vdW…

Optically addressable spins associated with defects in wide-bandgap semiconductors are versatile platforms for quantum information processing and nanoscale sensing, where spin-dependent inter-system crossing (ISC) transitions facilitate…

Quantum Physics · Physics 2019-07-23 Annemarie L. Exarhos , David A. Hopper , Raj N. Patel , Marcus W. Doherty , Lee C. Bassett

Defects in hexagonal boron nitride (h-BN) layer can facilitate tunneling current through thick h-BN tunneling barriers. We have investigated such current-mediating defects as local probes for materials in two dimensional heterostructure…

Mesoscale and Nanoscale Physics · Physics 2018-08-28 Ying Liu , Zhenbing Tan , Manohar Kumar , T. S. Abhilash , Guan-jun Liu , Pertti Hakonen

In 2015, a new two dimensional (2D) carbon allotrope, called phagraphene, was theoretically proposed. Based on this structure, we propose here a new boron nitride structure called phaBN. It is composed by three types of rings: pentagons,…

Materials Science · Physics 2020-12-09 J. M. Pontes , N. F. Frazão , David L. Azevedo , Jonas R. F. Lima

Controlling and manipulating individual quantum systems in solids underpins the growing interest in development of scalable quantum technologies. Recently, hexagonal boron nitride has garnered significant attention in quantum photonic…

Key properties of nine possible defect sites in hexagonal boron nitride (h-BN) are predicted using density-functional theory and are corrected by applying results from high-level ab initio calculations. Observed h-BN electron-paramagnetic…

Computational Physics · Physics 2018-02-12 A. Sajid , Jeffrey R. Reimers , Michael J. Ford

Hexagonal boron nitride (h-BN) nanomesh, a two-dimensional insulating monolayer, grown on the (111) surface of rhodium exhibits an intriguing hexagonal corrugation pattern with a lattice constant of 3.2 nm. Despite numerous experimental and…

Materials Science · Physics 2020-08-19 Luis Henrique de Lima , Thomas Greber , Matthias Muntwiler

Detecting magnetic noise from small quantities of paramagnetic spins is a powerful capability for chemical, biochemical, and medical analysis. Quantum sensors based on optically addressable spin defects in bulk semiconductors are typically…

This study introduces an anisotropic interfacial potential that provides an accurate description of the van der Waals (vdW) interactions between water and hexagonal boron nitride (h-BN) at their interface. Benchmarked against the strongly…

Chemical Physics · Physics 2023-06-14 Zhicheng Feng , Zhangke Lei , Yuanpeng Yao , Jianxin Liu , Bozhao Wu , Wengen Ouyang

We investigate interlayer adhesion and relaxation at interfaces between graphene and hexagonal boron nitride (hBN) monolayers in van der Waals heterostructures. The adhesion potential between graphene and hBN is calculated as a function of…

Increased power density in modern microelectronics has led to thermal management challenges which can cause degradation in performance and reliability. In many high-power electronic devices, the power consumption and heat removal are…

Mesoscale and Nanoscale Physics · Physics 2019-10-01 David B. Brown , Thomas L. Bougher , Xiang Zhang , Pulickel Ajayan , Baratunde A. Cola , Satish Kumar

Solid-state quantum emitters, molecular-sized complexes releasing a single photon at a time, have garnered much attention owing to their use as a key building block in various quantum technologies. Among these, quantum emitters in hexagonal…

New techniques for probing hyperbolic phonon polaritons (HPP) in 2D materials will support the development of the emerging technologies in this field. Previous reports have shown that it is possible for WSe2 monolayers in contact with the…

Mesoscale and Nanoscale Physics · Physics 2021-10-04 Jacob J. S. Viner , Liam P. McDonnell , Pasqual Rivera , Xiaodong Xu , David C. Smith

Quantum emitters in layered hexagonal boron nitride (hBN) have recently attracted a great attention as promising single photon sources. In this work, we demonstrate resonant excitation of a single defect center in hBN, one of the most…

Covalent functionalization is a way to tune the electrochemical properties of hexagonal boron nitride (h-BN) monolayers. The wide band gap insulator h-BN may become metallic conductor upon functionalization with strong oxidants, such as…

Materials Science · Physics 2018-08-23 Karoly Nemeth

Optically active spin defects in solids are leading candidates for quantum sensing and quantum networking. Recently, single spin defects were discovered in hexagonal boron nitride (hBN), a layered van der Waals (vdW) material. Due to its…

Spin defects in hexagonal boron nitride (hBN) are promising quantum systems for the design of flexible two-dimensional quantum sensing platforms. Here we rely on hBN crystals isotopically enriched with either $^{10}$B or $^{11}$B to…

Materials Science · Physics 2023-10-03 A. Haykal , R. Tanos , N. Minotto , A. Durand , F. Fabre , J. Li , J. H. Edgar , V. Ivady , A. Gali , T. Michel , A. Dréau , B. Gil , G. Cassabois , V. Jacques

Enhanced light-matter interactions are the basis of surface enhanced infrared absorption (SEIRA) spectroscopy, and conventionally rely on plasmonic materials and their capability to focus light to nanoscale spot sizes. Phonon polariton…

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