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We report magnetic-field-induced first-order phase transitions in the ferro-quadrupole (FQ) ordered state of PrTi2Al20, in which non-Kramers Pr3+ ions with two 4f electrons have a non-magnetic Gamma3 doublet ground state in the cubic Td…

We report the results of 27Al-NMR measurements on a single crystal of PrTi2Al20. This compound shows a phase transition near 2 K associated with the quadrupole degree of freedom of Pr ions, for which the ground state of the crystalline…

Origin of the non-magnetic phase transition in PrTi$_2$Al$_{20}$, reported earlier in the macroscopic study, has been asserted microscopically using elastic and inelastic neutron scattering techniques. It has been shown spectroscopically…

Strongly Correlated Electrons · Physics 2013-05-03 Taku J Sato , Soshi Ibuka , Yusuke Nambu , Teruo Yamazaki , Akito Sakai , Satoru Nakatsuji

We provide thermodynamic evidence for the presence of a magnetic-field-induced small phase pocket near the antiferro-quadrupole (AFQ) phase boundary in the non-Kramers $\Gamma_3$ doublet system PrIr$_2$Zn$_{20}$. In particular, we measured…

Strongly Correlated Electrons · Physics 2024-08-13 Shunichiro Kittaka , Takahiro Onimaru , Keisuke T. Matsumoto , Toshiro Sakakibara

We propose novel triple-${\bm q}$ multipole orders as possible candidates for the two distinct low-temperature symmetry broken phases in quadrupolar system PrV$_2$Al$_{20}$. An analysis of the experiment under [111] magnetic fields…

Strongly Correlated Electrons · Physics 2021-12-24 Takayuki Ishitobi , Kazumasa Hattori

We performed field-angle-resolved magnetostriction and thermal-expansion measurements on PrIr$_2$Zn$_{20}$, a cubic non-Kramers compound exhibiting antiferroquadrupolar order below $T_{\rm Q}=0.125$ K. Thermal expansion exhibits two…

Strongly Correlated Electrons · Physics 2025-12-23 Naoki Okamoto , Yohei Kono , Takahiro Onimaru , Keisuke T. Matsumoto , Kazumasa Hattori , Shunichiro Kittaka

Multipolar Kondo systems offer unprecedented opportunities for designing astonishing quantum phases and functionalities beyond spin-only descriptions. A model material platform of this kind is the cubic heavy-fermion system…

Strongly Correlated Electrons · Physics 2023-08-29 Takachika Isomae , Akito Sakai , Mingxuan Fu , Takanori Taniguchi , Masashi Takigawa , Satoru Nakatsuji

Electronic states and quadrupole orders in the Pr 1-2-20 systems PrT2Al20 (T=Ti, V) are investigated on the basis of the first-principles calculations. The effective 196 orbital model is derived to reproduce the first-principles electronic…

Strongly Correlated Electrons · Physics 2022-06-22 Y. Iizuka , T. Yamada , K. Hanzawa , Y. Ōno

We investigate antiferro quadrupole orders in systems with non-Kramers doublet ground state with total angular momentum J=4 in T_d point group symmetry. We demonstrate that a pure O_2^2 antiferro quadrupole order is impossible in general…

Strongly Correlated Electrons · Physics 2015-06-17 Kazumasa Hattori , Hirokazu Tsunetsugu

We study quadrupole orders in heavy-fermion compound PrIr$_2$Zn$_{20}$ under magnetic fields on the basis of the Landau theory. Assuming $E_g$ electric quadrupolar orders in the cubic symmetry with the ordering wavenumber at the L points in…

Strongly Correlated Electrons · Physics 2026-05-06 Hitoko Okanoya , Kazumasa Hattori

Motivated by the time-reversal symmetry breaking signal in muon spin relaxation below a transition temperature without accompanying noticeable magnetic Bragg peaks in $5d^2$ Os double perovskites, a rare ferro-octupolar order was proposed…

Strongly Correlated Electrons · Physics 2026-04-16 Stashu Kozlowski , Derek Churchill , Hae-Young Kee

Our single crystal study reveals that PrTr2Al20 (Tr = Ti and V) provides the first examples of a cubic {\Gamma}3 nonmagnetic ground doublet system that shows the Kondo effect including a -ln T dependent resistivity. The {\Gamma}3…

Strongly Correlated Electrons · Physics 2015-03-19 Akito Sakai , Satoru Nakatsuji

The magnetic phase diagram for antiferro-quadrupole (AFQ) ordering in tetragonal HoB$_2$C$_2$ has been investigated by measurements of elastic constants $C_{11}$, $C_{44}$ and $C_{66}$ in fields along the basal $x$-$y$ plane as well as the…

Strongly Correlated Electrons · Physics 2009-11-11 Tatsuya Yanagisawa , Terutaka Goto , Yuichi Nemoto , Ryuta Watanuki , Kazuya Suzuki , Osamu Suzuki , Giyuu Kido

Quadrupole ordering with the ordering wavevector at the L points in PrIr$_2$Zn$_{20}$ under magnetic fields is analyzed using classical Monte Carlo simulations based on an effective $\Gamma_3$ quadrupole model on the diamond structure. We…

Strongly Correlated Electrons · Physics 2026-03-06 Kaito Sasa , Kazumasa Hattori

Effects of magnetic field on the quadrupolar ordering are investigated with inclusion of fluctuation of order parameters. For the simplest model with the nearest-neighbor quadrupolar interaction, the transition temperature and the specific…

Strongly Correlated Electrons · Physics 2009-10-30 Noboru Fukushima , Yoshio Kuramoto

Recent experiments have examined the impact of a magnetic field on ferroquadrupolar orders in the intermetallic Kondo material PrTi$_2$Al$_{20}$. Motivated by this, we use extensive Monte Carlo simulations to study a diamond lattice XY…

Strongly Correlated Electrons · Physics 2020-08-04 Frederic Freyer , SungBin Lee , Yong Baek Kim , Simon Trebst , Arun Paramekanti

The physical properties of the antiferroquadrupolar state occurring in TmTe below TQ=1.8 K have been studied using neutron diffraction in applied magnetic fields. A field-induced antiferromagnetic component k = (1/2,1/2,1/2) is observed…

Strongly Correlated Electrons · Physics 2015-06-24 J. M. Mignot , A. Gukasov , C. P. Yang , P. Link , T. Matsumura , T. Suzuki

We theoretically study electric quadrupole orders in f-electron systems on the fcc lattice. Qudrupole degrees of freedom $O_{20}$ and $O_{22}$ originate in the non-Kramers doublet ground state $\Gamma_3$ of ion with $f^2$ electron…

Strongly Correlated Electrons · Physics 2021-03-15 Hirokazu Tsunetsugu , Takayuki Ishitobi , Kazumasa Hattori

Superconducting and antiferroquadrupolar (AFQ) transitions in a Pr-based compound PrRh2Zn20 have been found to occur simultaneously at Tc=TQ=0.06 K. The superconducting transition manifests itself by zero resistance and large diamagnetic…

Strongly Correlated Electrons · Physics 2015-06-12 T. Onimaru , N. Nagasawa , K. T. Matsumoto , K. Wakiya , K. Umeo , S. Kittaka , T. Sakakibara , Y. Matsushita , T. Takabatake

Neutron diffraction measurements have been performed on the cubic compound PrPb3 in a [001] magnetic field to examine the quadrupolar ordering. Antiferromagnetic components with q=(1/2+-d 1/2 0), (1/2 1/2+-d 0) (d~1/8) are observed below…

Strongly Correlated Electrons · Physics 2009-11-11 T. Onimaru , T. Sakakibara , N. Aso , H. Yoshizawa , H. S. Suzuki , T. Takeuchi
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