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Perovskite photovoltaics has witnessed an unprecedented increase in power conversion efficiency over the last decade. The choice of transport layers, through which photo-generated electrons and holes are transported to the electrodes, is a…

Applied Physics · Physics 2020-07-10 Eline M. Hutter , Thomas Kirchartz , Bruno Ehrler , David Cahen , Elizabeth von Hauff

We report on an element-selective study of the fate of charge carriers in photoexcited inorganic CsPbBr3 and CsPb(ClBr)3 perovskite nanocrystals (NCs) in toluene solutions using time-resolved X-ray absorption spectroscopy with 80 ps time…

Ni et al. report minimum bulk trap densities of 10^11 cm-3 and 1-4 orders change in interfacial trap densities derived from drive-level capacitance profiling of lead halide perovskites. From basic electrostatic arguments, we show that such…

Applied Physics · Physics 2020-12-01 Sandheep Ravishankar , Thomas Unold , Thomas Kirchartz

Hybrid metal-organic perovskite solar cells have astounded the solar cell community with their rapid rise in efficiency over the past three years. Despite this success, the basic processes governing the photogeneration of free charges,…

Halide perovskites are highly promising light-harvesting materials with strong ionic character, enabling in principle the combination of a solar cell and a Li-ion battery in one integrated photo-battery device. Here, we investigate Li ions…

Materials Science · Physics 2024-03-05 Wei Wei , Julian Gebhardt , Daniel F. Urban , Christian Elsässer

Lead halide perovskites show remarkable performance when used in photovoltaic and optoelectronic devices. However, the peculiarities of light-matter interactions in these materials in general are far from being fully explored experimentally…

Other Condensed Matter · Physics 2022-02-24 A. V. Trifonov , S. Grisard , A. N. Kosarev , I. A. Akimov , D. R. Yakovlev , J. Höcker , V. Dyakonov , M. Bayer

We consider the transport of conserved charges in spatially inhomogeneous quantum systems with a discrete lattice symmetry. We analyse the retarded two point functions involving the charge and the associated currents at long wavelengths,…

High Energy Physics - Theory · Physics 2017-12-20 Aristomenis Donos , Jerome P. Gauntlett , Vaios Ziogas

Organic-inorganic perovskite solar cells have attracted tremendous attention because of their remarkably high power conversion efficiencies (PCEs). To further improve the device performance, however, it is imperative to obtain fundamental…

Materials Science · Physics 2018-02-07 Zhaodong Chu , Mengjin Yang , Philip Schulz , Di Wu , Xin Ma , Edward Seifert , Liuyang Sun , Kai Zhu , Xiaoqin Li , Keji Lai

Solution-processed, lead halide-based perovskite solar cells have overcome important challenges over the recent years, offering low-cost and high solar power conversion efficiencies. However, they still undergo unoptimized light collection…

With rapidly growing photoconversion efficiencies, hybrid perovskite solar cells have emerged as promising contenders for next generation, low-cost photovoltaic technologies. Yet, the presence of nanoscale defect clusters, that form during…

Traditional inorganic semiconductors can be electronically doped with high precision. Conversely, there is still conjecture regarding the assessment of the electronic doping density in metal-halide perovskites, not to mention of a control…

Recent observations indicated that the photoelectric conversion properties of perovskite materials are intimately related to the presence of superlattice structures and other unusual nanoscale features in them. The low dimensional or mixed…

Mesoscale and Nanoscale Physics · Physics 2021-05-11 Susmita Bhattacharya , Goutam Kumar Chandra , P. Predeep

Metal halide perovskites are attracting tremendous interest for a variety of optoelectronic applications. The ability to tune the perovskite bandgap by tweaking the chemical compositions opens up new applications as coloured emitters and as…

Realizing semiconductors with high symmetry of their crystallographic structures has been a virtue of inorganic materials and has resulted in novel physical behaviors. In contrast, hybrid (organic and inorganic) crystals such as…

We describe a theory on photo-thermoelectric properties of a semiconductor, which include photo-conductivity, photo-Seebeck coefficient, and photo-Hall effect. We demonstrate that these properties provide a powerful tool for the study of…

Materials Science · Physics 2019-11-01 Zhenyu Pan , Zheng Zhu , Jeffrey J. Urban , Fan Yang , Heng Wang

While imaging individual atoms can routinely be achieved in high resolution transmission electron microscopy, visualizing the potential distribution of individually charged adsorbates leading to a phase shift of the probing electron wave is…

Mesoscale and Nanoscale Physics · Physics 2017-08-08 Tatiana Latychevskaia , Flavio Wicki , Conrad Escher , Hans-Werner Fink

Investigation of the inherent field-driven charge transport behaviour of 3D lead halide perovskites has largely remained a challenging task, owing primarily to undesirable ionic migration effects near room temperature. In addition, the…

To be able to increase the efficiency of perovskite solar cells which is one of the most substantial challenges ahead in photovoltaic industry, the structural and optical properties of perovskite CH3NH3PbI3-xBrx for values x=1-3 have been…

We present a perspective on recent observations of the photoinduced phase separation of halides in multi-component lead-halide perovskites. The spontaneous phase separation of an initial homogeneous solid solution under steady-state…

Applied Physics · Physics 2020-07-15 David T. Limmer , Naomi S. Ginsberg

Halide perovskite solar cells presented a unique opportunity to apply modern computational materials science techniques to an (initially) poorly understood new material. In this review, we recount the key understanding developed during the…

Mesoscale and Nanoscale Physics · Physics 2018-11-07 Jarvist Moore Frost