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The spectacular performance of halide perovskites in optoelectronic devices is rooted in their tolerance to defects. Previous studies showed that defects in these materials generate shallow electronic states. However, how these shallow…

Materials Science · Physics 2025-05-20 Frederico P. Delgado , Frederico Simões , Leeor Kronik , Waldemar Kaiser , David A. Egger

Underlying the rapidly increasing photovoltaic efficiency and stability of metal halide perovskites (MHPs) is the advance in the understanding of the microstructure of polycrystalline MHP thin film. Over the past decade, intense efforts…

We present a method for incorporating image-charge effects into the description of charge transport through molecular devices. A simple model allows us to calculate the adjustment of the transport levels, due to the polarization of the…

Mesoscale and Nanoscale Physics · Physics 2015-11-23 C. J. O. Verzijl , J. A. Celis Gil , M. L. Perrin , D. Dulić , H. S. J. van der Zant , J. M. Thijssen

Photoluminescence (PL) under continuous illumination is commonly employed to assess voltage losses in solar energy conversion materials. However, the early temporal evolution of these losses remains poorly understood. Therefore, we extend…

Materials Science · Physics 2024-09-11 Hannes Hempel , Martin Stolterfoht , Orestis Karalis , Thomas Unold

This paper presents a theoretical and experimental investigation of photon diffusion in highly absorbing microscale graphite. An Nd:YAG continuous wave (CW) laser is used to heat the graphite samples with thicknesses of 40 microns and 100…

Applied Physics · Physics 2023-03-13 Avijit Das , Andrew K. Brown , Merlin L. Mah , Joseph J. Talghader

The diffusion of electron-hole pairs, which are excited in an intrinsic graphene by the ultrashort focused laser pulse in mid-IR or visible spectral region, is described for the cases of peak-like or spread over the passive region…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 F. T. Vasko , V. V. Mitin

The last five years have witnessed a remarkable progress in the field of lead halide perovskite materials and devices. Examining the existing body of literature reveals staggering inconsistencies in the reported results among different…

Halide perovskites are semiconductors that exhibit sharp optical absorption edges and small Urbach energies allowing for efficient collection of sunlight in thin-film photovoltaic devices. However, halide perovskites also exhibit large…

Materials Science · Physics 2019-07-25 Christian Gehrmann , David A. Egger

A microemulsion of decane droplets stabilized by a non-ionic surfactant film is progressively charged by substitution of a non-ionic surfactant molecule by a cationic surfactant. We check that the microemulsion droplets remain identical…

Soft Condensed Matter · Physics 2016-08-16 Jacqueline Appell , Grégoire Porte , Eric Buhler

Hybrid organic-inorganic halide perovskites are low-cost solution-processable solar cell materials with photovoltaic properties that rival those of crystalline silicon. The perovskite films are typically sandwiched between thin layers of…

The capture of photoexcited deep-band hot carriers, excited by photons with energies far above the bandgap, is of significant importance for photovoltaic and photoelectronic applications since it is directly related to the quantum…

Materials Science · Physics 2021-03-18 Jin Zhang , Hao Hong , Jincan Zhang , Chunchun Wu , Hailin Peng , Kaihui Liu , Sheng Meng

Halide perovskites (HPs) are widely viewed as promising photovoltaic and light-emitting materials for their suitable band gaps in the visible spectrum. Density functional theory (DFT) calculations employing (semi)local exchange-correlation…

Materials Science · Physics 2022-12-06 Jiyuan Yang , Tianyuan Zhu , Shi Liu

The application of ultrathin two-dimensional (2D) perovskites in near-infrared and visible-range optoelectronics has been limited owing to their inherent wide bandgaps, large excitonic binding energies and low optical absorption at higher…

Mesoscale and Nanoscale Physics · Physics 2022-05-06 Abin Varghese , Yuefeng Yin , Mingchao Wang , Saurabh Lodha , Nikhil V. Medhekar

A model is derived for the frequency- and time-domain opto-electronic response of perovskite solar cells (PSCs) that emphasizes the role of charge carrier exchange, .i.e. extraction and injection, from (to) the perovskite through the…

Materials Science · Physics 2023-11-10 Sandheep Ravishankar , Zhifa Liu , Yueming Wang , Thomas Kirchartz , Uwe Rau

Halide perovskites are a promising optical gain media with high tunability and simple solution synthesis. In this study, two gain regimes, namely amplified spontaneous emission and random lasing, are demonstrated in same MAPbBr$_3$ halide…

Migration of halide defects guides ion transport in metal halide perovskites and controls the kinetics of halide mixing and phase separation. We study the diffusion of halide vacancies and interstitials in \ce{CsPb(I_{x}Br_{1-x})_{3}} and…

Materials Science · Physics 2026-04-27 Viren Tyagi , Mike Pols , Geert Brocks , Shuxia Tao

When a fluid carrying a passive solute flows quickly through porous media, three key macroscale transport mechanisms occur. These mechanisms are diffusion, advection and dispersion, all of which depend on the microstructure of the porous…

Fluid Dynamics · Physics 2024-10-16 Lucy C Auton , Mohit P. Dalwadi , Ian M. Griffiths

This study introduces a novel method to investigate in-situ light transport within optically thick ensembles of cold atoms, exploiting the internal structure of alkaline-earth metals. A method for creating an optical excitation at the…

Hybrid organic-inorganic halide perovskites have emerged as a disruptive new class of materials, exhibiting optimum properties for a broad range of optoelectronic applications, most notably for photovoltaics. The first report of highly…

Materials Science · Physics 2018-08-21 Marina R. Filip , George Volonakis , Feliciano Giustino

The performance of organometallic perovskite solar cells has rapidly surpassed that of both conventional dye-sensitised and organic photovoltaics. High power conversion efficiency can be realised in both mesoporous and thin-film device…

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