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In the present work we investigate the photocatalytic hydrogen production (water splitting) activity of different Pt loaded TiO2 nanotube layers. Therefore, we fabricate free standing membranes and fix them in four different configurations:…

Materials Science · Physics 2016-10-14 Gihoon Cha , Kiyoung Lee , JeongEun Yoo , Manuela S. Killian , Patrik Schmuki

The electrochemical performances of the {\alpha}-MnO2/Vulcan XC-72 and {\delta}-MnO2/Vulcan XC-72 nanostructures in hydrogen peroxide (H2O2) electrosynthesis were compared herein. Both materials were synthesized by a simple hydrothermal…

Materials Science · Physics 2025-05-13 João Paulo C Moura , Vanessa S Antonin , Aline B Trench , Mauro C Santos

Electrocatalytic CO$_2$RR is an interfacial process, involving a minimum of three phases at the contact point of gaseous CO$_2$ with the electrodic surface and the liquid electrolyte. As a consequence, surface chemistry at composite…

Materials Science · Physics 2022-12-09 Michele Melchionna , Paolo Fornasiero , Maurizio Prato , Marcella Bonchio

Reduced titanium dioxide has recently attracted large attention, particularly for its unique co-catalyst-free H$_2$ heterogeneous photocatalytic application. The enhanced photocatalytic activity of the reduced TiO$_2$ was previously…

Electrocatalytic hydrogenation of nitrobenzene (Ph-NO2) reaction (EHNR) has been considered as a potential alternative to the traditional thermocatalytic process in the production of high-value aniline (Ph-NH2). However, due to the absence…

Chemical Physics · Physics 2024-03-26 Yuchen Wang , Yaoyu Liu , Zhiyue Zhao , Zhikeng Zheng , Alina M. Balu , Rafael Luque , Kai Yan

Photoreforming is a clean photocatalytic technology for simultaneous plastic waste degradation and hydrogen fuel production, but there are still limited active and stable catalysts for this process. This work introduces the brookite…

Materials Science · Physics 2024-08-21 Thanh Tam Nguyen , Kaveh Edalati

Catalysts for oxygen reduction and evolution reactions are at the heart of key renewable energy technologies including fuel cells and water splitting. Despite tremendous efforts, developing oxygen electrode catalysts with high activity at…

Materials Science · Physics 2011-08-12 Yongye Liang , Yanguang Li , Hailiang Wang , Jigang Zhou , Jian Wang , Tom Regier , Hongjie Dai

Tuning the valence state and electronic structure of catalytically active sites is crucial for improving Fenton and Fenton-like reactions, which rely on the efficient activation of the H2O2 molecule. Pure TiO2, however, has inadequate…

In this report, the preparation of Fe-carbon nitride (CN)-based electrocatalysts (ECs) with a 'core-shell' morphology for the oxygen reduction reaction (ORR) is described. The ECs consist of spherical XC-72R carbon nanoparticles, the…

Boron nitride (BN) has been explored these days because of its extraordinary optical, chemical and mechanical properties. BN is sensitive to its crystal structure that slight change in lattice parameters enormously change its properties.…

Materials Science · Physics 2019-10-01 Bikramjeet Singh , Kulwinder Singh , Manjeet Kumar , Akshay Kumar

This study reports the preparation and characterization of a new family of electrocatalysts (ECs) for the oxygen reduction reaction (ORR) exhibiting a 'core-shell' morphology. The 'core' consists of graphene sheets, which are covered by a…

In the present work, a simple strategy is used to thermally oxidize TiN nanopowder (ca. 20 nm) to an anatase phase of a TiO2:Ti3+:N compound. In contrast to the rutile phase of such a compound this photocatalyst provides photocatalytic…

Materials Science · Physics 2016-10-21 Xuemei Zhou , Eva M. Zolnhofer , Nhat Truong Nguyen , Ning Liu , Karsten Meyer , Patrik Schmuki

Electrochemical reduction is a promising way to make use of CO$_2$ as feedstock for generating renewable fuel and valuable chemicals. Several metals can be used in the electrocatalyst to generate CO and formic acid but hydrogen formation is…

A series of W, N codoped TiO2 nanotube arrays with different dopant contents were fabricated by anodizing in association with hydrothermal treatment. The samples were characterized by scanning electron microscopy, X-ray diffraction, X-ray…

Materials Science · Physics 2013-12-06 Min Zhang , Juan Wu , DanDan Lu , Jianjun Yang

Surface fluorination of TiO$_2$ (F-TiO$_2$) has complicate photocatalytic behavior in degradation of organic compounds. This work attempts to establish an elegant scenario based on the band model to understand this behavior. Density…

Materials Science · Physics 2017-11-21 Huimin Gao , Daoyu Zhang , Minnan Yang , Shuai Dong

High-entropy oxides (HEOs), containing at least five principal cations, have recently emerged as promising photocatalysts for hydrogen production via water splitting. Despite their high potential, the impact of the cation mixtures on…

Materials Science · Physics 2024-05-31 Jacqueline Hidalgo-Jimenez , Taner Akbay , Tatsumi Ishihara , Kaveh Edalati

We report here results of our density functional theory based computational studies of the electronic structure of the Pd-Co alloy electrocatalysts and energetics of the oxygen reduction reaction (ORR) on their surfaces. The calculations…

Materials Science · Physics 2015-05-28 Sebastian Zuluaga , Sergey Stolbov

The phase diagram of surface structures for the model catalyst RuO2(110) in contact with a gas environment of O2 and CO is calculated by density-functional theory and atomistic thermodynamics. Adsorption of the reactants is found to depend…

Materials Science · Physics 2009-11-10 Karsten Reuter , Matthias Scheffler

Nanocrystalline MnFe$_{2}$O$_{4}$ has shown promise as a catalyst for the oxygen reduction reaction (ORR) in alkaline solutions, but the material has been lightly studied as highly ordered thin film catalysts. To examine the role of surface…

The conversion of CO2 into high-value chemicals through a photoreduction reaction in water is a promising route to reduce the dependence on fossil fuels. Ag nanoparticles can drive this reaction via localized surface plasmon resonance, but…