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Recently, the development of efficient and non-noble metal electrocatalysts with excellent durability for the hydrogen evolution reaction (HER) has attracted increasing attention. The exotic and robust metallic surface states of topological…

Chemical Physics · Physics 2019-09-27 Qing Qu , Bin Liu , Jing Liang , Ding Pan , Iam Keong Sou

Adsorption of CO$_2$ on a semiconductor surface is a prerequisite for its photocatalytic reduction. Owing to superior photocorrosion resistance, nontoxicity and suitable band edge positions, TiO$_2$ is considered to be the most efficient…

Materials Science · Physics 2018-12-05 Shashi B. Mishra , Aditya Choudhary , Somnath C. Roy , B. R. K. Nanda

Boron carbide: A traditional ceramic material shows unique properties when explored in nano-range. Specially designed boron based nanocomposite has been synthesized by reflux method. The addition of SnO2 in base matrix increase the defect…

Electrochemical CO2 reduction reaction (CO2RR) using 2D nanomaterials has emerged as a sophisticated approach to mitigate industrial CO2 emissions. In this work, the potential application of pristine as well as strategically Fe, Co,…

Materials Science · Physics 2025-09-23 Md. Mostaqul Islam , Ahmed Zubair

First-row transition metal oxides and chalcogenides have been found to rival the performance of precious metal-based catalysts for the interconversion of water and O$_2$. The high lability of the first-row transition metal ions leads to…

In the present work we use TiO2 nanotube arrays, carrying a Pt coating that is optimally dewetted, as a photocatalyst to generate H2. In order to achieve a maximum H2-generation efficiency, on the one hand an ideal thermal dewetting of the…

In the present work, extended Argon ion bombardment was used to modify anatase TiO2 nanotube (NTs) layers. In situ X-ray photoelectron spectroscopy revealed a high content of sub-oxide formed (Ti3+, Ti2+ states) in the nanotube layers.…

Materials Science · Physics 2016-10-14 Xuemei Zhou , Ning Liu , Patrik Schmuki

The dynamic reconstruction of surfaces during electrochemical reactions plays a crucial role in determining the performance of electrocatalysts. However, because reconstructions occur at the atomic level, direct observation and elucidation…

Photocatalytic $H_2$ evolution reactions on pristine TiO$_2$ is characterized by low efficiencies due to trapping and recombination of charge carriers, and due to a sluggish kinetics of electron transfer. Noble metal (mainly Pt, Pd, Au)…

TiO$_2$ and SrTiO$_3$ are well known materials in the field of photocatalysis due to their exceptional electronic structure, high chemical stability, non-toxicity and low cost. However, owing to the wide band gap, these can be utilized only…

Materials Science · Physics 2020-09-25 Manish Kumar , Pooja Basera , Shikha Saini , Saswata Bhattacharya

A major goal of energy research is to use visible light to cleave water directly, without an applied voltage, into hydrogen and oxygen. Since the initial reports of the ultraviolet (UV) activity of TiO2 and SrTiO3 in the 1970s, researchers…

The efforts in the optimization of the physical and chemical properties related to the photocatalytic efficiency of TiO2 nanoparticles relies mainly on defect engineering strategies, been the structural and the doping the most common ones.…

Materials Science · Physics 2022-03-07 M. P. Ferreira , H. B. de Carvalho

Elucidating the catalytic descriptor that accurately characterizes the structure-activity relationships of typical catalysts for various important heterogeneous catalytic reactions is pivotal for designing high-efficient catalytic systems.…

Chemical Physics · Physics 2025-10-23 Zhen Zhu , Shan Gao , Jing Zhang , Xuxin Kang , Shunfang Li , Xiangmei Duan

The production of hydrogen from water using only a catalyst and solar energy is one of the most challenging and promising outlets for the generation of clean and renewable energy. Semiconductor photocatalysts for solar hydrogen production…

The ability to efficiently evolve hydrogen via electrocatalysis at low overpotentials holds tremendous promise for clean energy. Hydrogen evolution reaction (HER) can be easily achieved from water if a voltage above the thermodynamic…

Five bimetallic electrocatalysts (ECs) including a carbon nitride (CN) support are synthesised through the pyrolysis of a solid precursor obtained through sol-gel and gel-plastic processes. The resulting ECs are characterised through…

Chemical Physics · Physics 2018-05-23 Stefano Diodati , Enrico Negro , Keti Vezzu' Vito Di Noto , Silvia Gross

Photoelectrocatalytic (PEC) reduction of N2 to ammonia (NH3) is emerging as the potential alternative to overcome the standard Haber-Bosch approach. In this communication, solar N2 reduction was demonstrated with molybdenum carbide (Mo2C)…

Batteries are the most abundant form of electrochemical energy storage. Lithium and sodium ion batteries account for a significant portion of the battery market, but high-performance electrochemically active materials still need to be…

The CO_{2} electro-reduction reaction (CORR) is a promising avenue to convert greenhouse gases into high-value fuels and chemicals, in addition to being an attractive method for storing intermittent renewable energy. Although…

The development of high-activity and low-price cathodic catalysts to facilitate the electrochemical sluggish O$_2$ reduction reaction (ORR) is very important to achieve the commercial application of fuel cells. Here, we have investigated…

Materials Science · Physics 2023-07-14 Ashok Singh , Srimanta Pakhira