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We present a theory which allows us to calculate the interaction potential between charge-regulated metal nanoparticles inside an acid-electrolyte solution. The approach is based on the recently introduced model of charge regulation which…

Soft Condensed Matter · Physics 2020-12-11 Amin Bakhshandeh , Alexandre P. dos Santos , Yan Levin

The interaction force between likely charged particles/surfaces is usually repulsive due to the Coulomb interaction. However, the counterintuitive like-charge attraction in electrolytes has been frequently observed in experiments, which has…

Soft Condensed Matter · Physics 2016-11-08 Pei Liu , Manman Ma , Zhenli Xu

In this thesis we study the lateral electrostatic interaction between a pair of non-identical, moderately charged colloidal particles trapped at an electrolyte interface in the limit of short inter-particle separations. Using a simplified…

Soft Condensed Matter · Physics 2017-10-17 Timo Schmetzer

In this paper, we theoretically study the electrostatic interaction between a pair of identical colloids with constant surface potentials sitting in close vicinity of each other at a fluid interface. By employing a simplified yet reasonable…

Soft Condensed Matter · Physics 2020-07-29 Rick Bebon , Arghya Majee

Ions are critical to the structure and stability of polyelectrolytes such as nucleic acids. In this work, we systematically calculated the potentials of mean force between two like-charged nanoparticles in salt solutions by Monte Carlo…

Biological Physics · Physics 2015-06-15 Yuan-Yan Wu , Feng-Hua Wang , Zhi-Jie Tan

Ion-mediated interaction is important for the properties of polyelectrolytes such as colloids and nucleic acids. The effective pair interactions between two polyelectrolytes have been investigated extensively, but the many-body effect for…

Soft Condensed Matter · Physics 2016-08-19 Xi Zhang , Jin-Si Zhang , Ya-Zhou Shi , Xiao-Long Zhu , Zhi-Jie Tan

Over the past few decades the experimental literature has consistently reported observations of attraction between like-charged colloidal particles and macromolecules in solution. Examples include nucleic acids and colloidal particles in…

Soft Condensed Matter · Physics 2020-04-22 Alzbeta Kubincova , Philippe H. Hunenberger , Madhavi Krishnan

The bare Coulomb interaction between two like-charges is repulsive. When these charges are immersed in an electrolyte, the thermal fluctuations of the ions turn the bare Coulomb interaction into an effective interaction between the two…

Statistical Mechanics · Physics 2023-03-15 Gabriel Tellez

The possibility that like-charges can attract each other under the mediation of mobile counterions is by now well documented experimentally, numerically, and analytically. Yet, obtaining exact results is in general impossible, or restricted…

Statistical Mechanics · Physics 2016-03-29 Gabriel Tellez , Emmanuel Trizac

We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in presence of multivalent…

Soft Condensed Matter · Physics 2009-10-31 Jeferson J. Arenzon , Juergen F. Stilck , Yan Levin

Two overall neutral surfaces with positive and negative charged domains ("patches") have been shown in recent experiments to exhibit long-range attraction when immersed in an ionic solution. Motivated by the experiments, we calculate…

Soft Condensed Matter · Physics 2016-08-31 Ram M. Adar , David Andelman , Haim Diamant

The electrostatic interaction between two non-identical, moderately charged colloids situated in close proximity of each other at a fluid interface is studied. By resorting to a well-justified model system, this problem is analytically…

Soft Condensed Matter · Physics 2018-04-30 Arghya Majee , Timo Schmetzer , Markus Bier

In solution, electrically like-charged particles can experience a strong and long-ranged attraction that leads to the formation of stable, slowly reorganizing clusters. The attractive force underpinning this spontaneous organization process…

Soft Condensed Matter · Physics 2026-01-14 Sida Wang , Angela Le , Rowan Walker-Gibbons , Madhavi Krishnan

We study the effective interaction between differently charged polyelectrolyte-colloid complexes in electrolyte solutions via Monte Carlo simulations. These complexes are formed when short and flexible polyelectrolyte chains adsorb onto…

Soft Condensed Matter · Physics 2010-05-05 D. Truzzolillo , F. Bordi , F. Sciortino , S. Sennato

From cement cohesion to DNA condensation, a proper statistical physics treatment of systems with long range forces is important for a number of applications in physics, chemistry, and biology. We compute here the effective force between…

Soft Condensed Matter · Physics 2018-03-14 E. Trizac , G. Téllez

We solve the nonlinear Poisson-Boltzmann equation for two parallel and likely charged plates both inside a symmetric elecrolyte, and inside a 2 : 1 asymmetric electrolyte, in terms of Weierstrass elliptic functions. From these solutions we…

Classical Physics · Physics 2013-05-29 Xiangjun Xing

Metal nanoparticles are receiving increased scientific attention owing to their unique physical and chemical properties that make them suitable for a wide range of applications in diverse fields, such as electrochemistry, biochemistry, and…

Chemical Physics · Physics 2020-10-09 Bendix Petersen , Rafael Roa , Joachim Dzubiella , Matej Kanduc

We consider a one-dimensional model allowing analytical derivation of the effective interactions between two charged colloids. We evaluate exactly the partition function for an electroneutral salt-free suspension with dielectric jumps at…

Soft Condensed Matter · Physics 2021-04-23 Lucas Varela , Gabriel Tellez , Emmanuel Trizac

We investigate, within a local density functional theory formalism, the interactions between like-charged polyions immersed in a confined electrolyte. We obtain a simple condition for a repulsive effective pair potential, that can be…

Soft Condensed Matter · Physics 2009-10-31 E. Trizac

We determine exactly the short-distance effective potential between two "guest" charges immersed in a two-dimensional two-component charge-asymmetric plasma composed of positively ($q_1 = +1$) and negatively ($q_2 = -1/2$) charged point…

Soft Condensed Matter · Physics 2021-09-01 Lucas Varela , Gabriel Téllez
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