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Parity is a ubiquitous notion in science and serves as a fundamental principle for describing a physical system. Nanometer-scale metal objects are predicted to show dramatic differences in physical properties depending on the…

Mesoscale and Nanoscale Physics · Physics 2022-11-24 K. Son , D. Park , C. Lee , A. Lascialfari , S. H. Yoon , K. Y. Choi , A. Reyes , J. Oh , M. Kim , F. Borsa , G. Scheutz , Y. G. Yoon , Z. H. Jang

We study the effect of solvent granularity on the effective force between two charged colloidal particles by computer simulations of the primitive model of strongly asymmetric electrolytes with an explicitly added hard sphere solvent. Apart…

Soft Condensed Matter · Physics 2009-10-31 E. Allahyarov , H. Loewen

In a Drude-like model for the conduction electrons of Metal Nanoparticles (MNPs) in a periodic linear chain, considering dipole-dipole interactions of adjacent particles, an analytical expression is derived for each particle permittivity…

Atomic Physics · Physics 2021-11-24 Asef Kheirandish , Nasser Sepehri Javan , Hosein Mohammadzadeh

The description of forces across confined complex fluids still holds many challenges due to the possible overlap of different contributions. Here, an attempt is made to untangle the interaction between charged surfaces across nanoparticle…

Soft Condensed Matter · Physics 2021-01-06 Michael Ludwig , Regine von Klitzing

Liquids in contact with solids are submitted to intermolecular forces making liquids heterogeneous and, in a mechanical model, the stress tensor is not any more spherical as in homogeneous bulks. The aim of this article is to show that a…

Soft Condensed Matter · Physics 2009-04-14 Henri Gouin

The consequences of source charge and surface modulation are studied within the framework of the Poisson-Boltzmann theory of electrolyte solutions. Through a consideration of various examples, it is found that inherent modulation can lead…

Chemical Physics · Physics 2013-05-29 Jonathan Landy

In this paper we analyze the behavior of hydrophobic polyelectrolytes. It has been proposed that this system adopts a pearl-necklace structure reminiscent of the Rayleigh instability of a charged droplet. Using a Poisson-Boltzmann approach,…

Soft Condensed Matter · Physics 2008-04-24 Alexei Chepelianskii , Farshid Mohammad-Rafiee , Elie Raphael

A new protocol for linearization of the Poisson-Boltzmann equation is proposed and the resultant electrostatic equation coincides formally with the Debye-Huckel equation, the solution of which is well known for many electrostatic problems.…

Chemical Physics · Physics 2014-10-28 R. Tsekov

Effective interactions between like-charged particles immersed in an electrolyte solution were calculated using two integral equation theories, hypernetted-chain (HNC)-Ornstein--Zernike (OZ) and ionic Percus--Yevick 2 (IPY2)-OZ. When the…

Soft Condensed Matter · Physics 2022-10-26 Michika Takeda , Kotetsu Maruyama , Ryo Akiyama , Tatsuhiko Miyata

Strong short ranged positional correlations involving counterions can induce a net attractive force between negatively charged strands of DNA, and lead to the formation of ion pairs in dilute ionic solutions. But the long range of the…

Statistical Mechanics · Physics 2009-11-11 Yng-Gwei Chen , John D. Weeks

The interfacial tension of a liquid droplet surrounded by another liquid in the presence of microscopic ions is studied as a function of the droplet radius. An analytical expression for the interfacial tension is obtained within a linear…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Joost de Graaf , Jos Zwanikken , Rene van Roij

The Casimir force between a pair of parallell plates filled with ionic particles is considered. We use a statistical mechanical approach and consider the classical high temperature limit. In this limit the ideal metal result with no…

Statistical Mechanics · Physics 2009-03-18 J. S. Høye

We present an extension to the Poisson-Boltzmann model where the dipolar features of solvent molecules are taken explicitly into account. The formulation is derived at mean-field level and can be extended to any order in a systematic…

Soft Condensed Matter · Physics 2012-01-31 Ariel Abrashkin , David Andelman , Henri Orland

We derive the 3D spatially homogeneous Boltzmann's equation with moderately soft potentials and singular angular interaction, from an interacting particles system. The collision kernel is of the form $B(z,\sigma)=|z|^{\gamma}b\left(…

Analysis of PDEs · Mathematics 2020-12-11 Samir Salem

Electrostatic interactions between point charges embedded into interfaces separating dielectric media are omnipresent in soft matter systems and often control their stability. Such interactions are typically complicated and do not resemble…

Soft Condensed Matter · Physics 2020-09-09 Alexander Morozov , Iain Muntz , Job H. J. Thijssen , Davide Marenduzzo

Phase separation in salt-free symmetric mixtures of oppositely charged rodlike polyelectrolytes is studied using quasi-analytical calculations. Stability analyses for the isotropic-isotropic and the isotropic-nematic phase transitions in…

Soft Condensed Matter · Physics 2010-07-20 Rajeev Kumar , Debra Audus , Glenn H. Fredrickson

A model describing spin-polarized current via discrete energy levels of a metallic nanoparticle, which has strongly asymmetric tunnel contacts to two ferromagnetic leads, is presented. In absence of spin-relaxation, the model leads to a…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Y. G. Wei , C. E. Malec , D. Davidović

The description of a conducting medium in thermal equilibrium, such as an electrolyte solution or a plasma, involves nonlinear electrostatics, a subject rarely discussed in the standard electricity and magnetism textbooks. We consider in…

Chemical Physics · Physics 2018-08-01 C. G. Gray , P. J. Stiles

Electromagnetic interactions of protons and alpha particles are modeled in a form that is suitable for Monte Carlo simulation of the transport of charged particles. The differential cross section (DCS) for elastic collisions with neutral…

Nuclear Theory · Physics 2023-11-13 Francesc Salvat , Carlos Heredia

We use the recently developed soft-potential-enhanced Poisson-Boltzmann (SPB) theory to study the interaction between two parallel polyelectrolytes (PEs) in monovalent ionic solutions in the weak-coupling regime. The SPB theory is fitted to…

Soft Condensed Matter · Physics 2022-09-28 Xiang Yang , Alberto Scacchi , Hossein Vahid , Maria Sammalkorpi , Tapio Ala-Nissila
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