English

Simple Model for Attraction between Like-Charged Polyions

Soft Condensed Matter 2009-10-31 v2 Statistical Mechanics

Abstract

We present a simple model for the possible mechanism of appearance of attraction between like charged polyions inside a polyelectrolyte solution. The attraction is found to be short ranged, and exists only in presence of multivalent counterions. The attraction is produced by the correlations in the condensed layers of counterions surrounding each polyion, and appears only if the number of condensed counterions exceeds the threshold, n>Z/2α n > Z/2 \alpha , where α\alpha is the valence of counterions and ZZ is the polyion charge.

Keywords

Cite

@article{arxiv.cond-mat/9806358,
  title  = {Simple Model for Attraction between Like-Charged Polyions},
  author = {Jeferson J. Arenzon and Juergen F. Stilck and Yan Levin},
  journal= {arXiv preprint arXiv:cond-mat/9806358},
  year   = {2009}
}

Comments

4 pages, 4 eps figures, also available at http://www.if.ufrgs.br/~arenzon Figure added and a more detailed discussion of conclusions