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Methanol is the most complex molecule securely identified in interstellar ices and is a key chemical species for understanding chemical complexity in astrophysical environments. Important aspects of the methanol ice photochemistry are still…

Astrophysics of Galaxies · Physics 2023-05-10 W. R. M. Rocha , P. Woitke , S. Pilling , W. -F. Thi , J. K. Jørgensen , L. E. Kristensen , G. Perotti , I. Kamp

Complex organic molecules (COMs) have been detected in the gas-phase in cold and lightless molecular cores. Recent solid-state laboratory experiments have provided strong evidence that COMs can be formed on icy grains through…

Solar and Stellar Astrophysics · Physics 2020-10-21 D. Qasim , G. Fedoseev , K. -J. Chuang , V. Taquet , T. Lamberts , J. He , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Classical hot cores are rich in molecular emission, and they show a high abundance of complex organic molecules (COMs). The emergence of molecular complexity is poorly constrained in the early evolution of hot cores. Using the Atacama Large…

Astrophysics of Galaxies · Physics 2019-11-27 T. Csengeri , A. Belloche , S. Bontemps , F. Wyrowski , K. M. Menten , L. Bouscasse

Ionized carbon is the main gas-phase reservoir of carbon in the neutral diffuse interstellar medium and its 158 micron fine structure transition [CII] is the most important cooling line of the diffuse interstellar medium (ISM). We combine…

Gas-phase complex organic molecules are commonly detected toward high-mass protostellar hot cores. Detections toward low-mass protostars and outflows are comparatively rare, and a larger sample is key to investigate how the chemistry…

Astrophysics of Galaxies · Physics 2015-05-30 Karin I. Oberg , Nienke van der Marel , Lars E. Kristensen , Ewine F. van Dishoeck

Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the chemical composition of comets forming in circumstellar disks. From observations, most volatile species are found in…

Earth and Planetary Astrophysics · Physics 2011-09-01 Edith C. Fayolle , Karin I. Oberg , Herma M. Cuppen , Ruud Visser , Harold Linnartz

We present the spectra of Complex Organic Molecules (COMs) detected in HOPS 373SW with the Atacama Large Millimeter/submillimeter Array (ALMA). HOPS 373SW, which is a component of a protostellar binary with a separation of 1500 au, has been…

Solar and Stellar Astrophysics · Physics 2023-06-30 Jeong-Eun Lee , Giseon Baek , Seokho Lee , Jae-Hong Jeong , Chul-Hwan Kim , Yuri Aikawa , Gregory J. Herczeg , Doug Johnstone , John J. Tobin

Molecular clouds are the cold regions of the Milky Way where stars form. They are enriched by rather complex molecules. Many of these molecules are believed to be synthesized on the icy surfaces of the interstellar submicron-sized dust…

Astrophysics of Galaxies · Physics 2020-07-08 Stefano Pantaleone , Joan Enrique-Romero , Cecilia Ceccarelli , Piero Ugliengo , Nadia Balucani , Albert Rimola

Prestellar cores represent early sites of low-mass ($M$ $\leq$ few M$_\odot$) star and planet formation and provide insight into initial chemical conditions of complex organic molecules (COMs). Deuterated COMs trace the degree of molecular…

The interstellar medium is characterized by a rich and diverse chemistry. Many of its complex organic molecules are proposed to form through radical chemistry in icy grain mantles. Radicals form readily when interstellar ices (composed of…

Astrophysics of Galaxies · Physics 2016-09-13 Karin I. Oberg

Methanol, one of the simplest complex organic molecules in the Interstellar Medium (ISM), has been shown to be present and extended in cold environments such as starless cores. We aim at studying methanol emission across several starless…

Astrophysics of Galaxies · Physics 2021-12-22 S. Spezzano , A. Fuente , P. Caselli , A. Vasyunin , D. Navarro-Almaida , M. Rodríguez-Baras , A. Punanova , C. Vastel , V. Wakelam

We study the photo-desorption occurring in H$_2$O:CO:NH$_3$ ice mixtures irradiated with monochromatic (550 and 900 eV) and broad band (250--1250 eV) soft X-rays generated at the National Synchrotron Radiation Research Center (Hsinchu,…

Astrophysics of Galaxies · Physics 2018-11-28 A. Jimenez-Escobar , A. Ciaravella , C. Cecchi-Pestellini , C. -H. Huang , N. -E. Sie , Y. -J. Chen , G. M. Munoz Caro

The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…

Solar and Stellar Astrophysics · Physics 2015-12-02 A. Faure , M. Faure , P. Theulé , E. Quirico , B. Schmitt

The Central Molecular Zone (CMZ) contains a substantial reservoir of dense molecular gas, where numerous young stellar objects (YSOs) and dense cloud cores have been identified. However, the large distance and severe foreground extinction…

Astrophysics of Galaxies · Physics 2026-03-04 Yewon Kang , Deokkeun An , Jiwon Han , Sang-Il Han , Dayoung Pyo , A. C. Adwin Boogert , Kee-Tae Kim , Do-Young Byun

Complex organic molecules (COMs), which are the seeds of prebiotic material and precursors of amino acids and sugars, form in the icy mantles of circumstellar dust grains but cannot be detected remotely unless they are heated and released…

Solar and Stellar Astrophysics · Physics 2019-02-08 Jeong-Eun Lee , Seokho Lee , Giseon Baek , Yuri Aikawa , Lucas Cieza , Sung-Yong Yoon , Gregory Herczeg , Doug Johnstone , Simon Casassus

This paper presents a systematic survey of the deuterated and 13C isotopologues of a variety of oxygen-bearing complex organic molecules on Solar System scales toward the protostar IRAS 16293-2422B. We use the data from an unbiased…

Gaseous H2O has been detected in several cold astrophysical environments, where the observed abundances cannot be explained by thermal desorption of H2O ice or by H2O gas phase formation. These observations hence suggest an efficient…

Astrophysics · Physics 2011-02-11 Karin I. Oberg , Harold Linnartz , Ruud Visser , Ewine F. van Dishoeck

(Abridged) We aim to enlarge the number of known hot corinos and carry out a first comparative study with hot cores. The ultimate goal is to understand whether complex organic molecules form in the gas phase or on grain surfaces, and what…

Cold ($\sim$10 K) and dense ($\sim$10$^{5}$ cm$^{-3}$) cores of gas and dust within molecular clouds, known as starless and dynamically evolved prestellar cores, are the birthplaces of low-mass ($M$ $\leq$ few M$_\odot$) stars. As…

Astrophysics of Galaxies · Physics 2024-08-22 Samantha Scibelli , Yancy Shirley , Andrés Megías , Izaskun Jiménez-Serra

We present experimental measurements of photodesorption from ices of astrophysical relevance. Layers of benzene and water ice were irradiated with a laser tuned to an electronic transition in the benzene molecule. The translational energy…

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