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The work is devoted to the adaptation of the results of laboratory studies of the laser-induced dissociation of molecules of benzene adsorbed on a quartz substrate to the conditions of the interstellar medium. Adsorption was performed under…

Astrophysics of Galaxies · Physics 2019-08-14 M. S. Murga , V. N. Varakin , A. V. Stolyarov , D. S. Wiebe

Massive young stellar objects (MYSOs) with hot cores are classic sources of complex organic molecules. The origins of these molecules in such sources, as well as the small- and large-scale differentiation between nitrogen- and…

Solar and Stellar Astrophysics · Physics 2015-03-25 Edith C. Fayolle , Karin I. Öberg , Robin T. Garrod , Ewine F. van Dishoeck , Suzanne E. Bisschop

In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…

Solar and Stellar Astrophysics · Physics 2017-11-08 S. Cazaux , R. Martin-Domenech , Y. J. Chen , G. M. Munoz Caro , C. Gonzalez Diaz

H2CO is a ubiquitous molecule in the ISM and in the gas phase of prestellar cores, and is likely present in ice mantles, but its main desorption mechanism is unknown. In this paper our aim is to quantify the desorption efficiency of H2CO…

Astrophysics of Galaxies · Physics 2024-12-25 M. Faure , A. Bacmann , A. Faure , E. Quirico , P. Boduch , A. Domaracka , H. Rothard

Absorption of ultraviolet radiation by water ice coating interstellar grains can lead to dissociation and desorption of the ice molecules. These processes are thought to be important in the gas-grain chemistry in molecular clouds and…

Astrophysics · Physics 2009-11-13 S. Andersson , E. F. van Dishoeck

Astrochemistry is a well-established multidisciplinary field devoted to study molecules in space. While most astrochemists are oriented to observe molecules in the gas phase and reproduce their abundances by modeling the physical conditions…

Astrophysics of Galaxies · Physics 2025-12-10 Guillermo M. Muñoz Caro , Héctor Carrascosa de Lucas , Rafael Martín-Doménech

In dense clouds of the interstellar medium, dust grains are covered by ice mantles, dominated by H$_2$O. CO and CO$_2$ are common ice components observed in infrared spectra, while infrared inactive N$_2$ is expected to be present in the…

Earth and Planetary Astrophysics · Physics 2019-03-29 H. Carrascosa , L. -C. Hsiao , N. -E. Sie , G. M. Muñoz Caro , Y. -J. Chen

Context. Methane is among the main components of the ice mantles of insterstellar dust grains, where it is at the start of a rich solid-phase chemical network. Quantification of the photon-induced desorption yield of these frozen molecules…

Starless molecular cores are natural laboratories for interstellar molecular chemistry research. The chemistry of ices in such objects was investigated with a three-phase (gas, surface, and mantle) model. We considered the center part of…

Astrophysics of Galaxies · Physics 2015-04-24 Juris Kalvans

We present the results of chemical modeling of complex organic molecules (COMs) under conditions typical for prestellar cores. We utilize an advanced gas-grain astrochemical model with updated gas-phase chemistry, with a multilayer approach…

Astrophysics of Galaxies · Physics 2017-06-28 Anton I. Vasyunin , Paola Caselli , François Dulieu , Izaskun Jiménez-Serra

The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…

Astrophysics of Galaxies · Physics 2025-12-16 Ryota Ichimura , Hideko Nomura , Kenji Furuya , Tetsuya Hama , T. J. Millar

We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…

Astrophysics · Physics 2011-02-11 K. Willacy

Non-thermal desorption of inter- and circum-stellar ice mantles on dust grains, in particular ultraviolet photon-induced desorption, has gained importance in recent years. These processes may account for the observed gas phase abundances of…

Astrophysics of Galaxies · Physics 2019-05-08 C González Díaz , H Carrascosa de Lucas , S Aparicio , G M Muñoz Caro , N-E Sie , L-C Hsiao , Y-J Chen

To explain grain growth and destruction in warm media, ice mantle formation and sublimation in cold media, and gas line emission spectroscopy, astrochemical models must mimic the gas--solid abundance ratio. Ice-sublimation mechanisms…

Astrophysics of Galaxies · Physics 2024-04-04 F. Kruczkiewicz , F. Dulieu , A. V. Ivlev , P. Caselli , B. M. Giuliano , C. Ceccarelli , P. Theulé

Extremely large deuteration of several molecules has been observed towards prestellar cores and low-mass protostars for a decade. New observations performed towards low-mass protostars suggest that water presents a lower deuteration in the…

Astrophysics of Galaxies · Physics 2015-06-19 Vianney Taquet , Steven B. Charnley , Olli Sipilä

(Abridged) Gas-phase complex organic molecules are commonly detected in the warm inner regions of protostellar envelopes. Recent models show that photochemistry in ices followed by desorption may explain the observed abundances. This study…

Astrophysics of Galaxies · Physics 2015-05-13 K. I. Oberg , R. T. Garrod , E. F. van Dishoeck , H. Linnartz

Complex organic molecules (COMs) are thought to form on icy dust grains in the earliest phase of star formation. The evolution of these COMs from the youngest Class 0/I protostellar phases toward the more evolved Class II phase is still not…

Complex organic molecules (COMs) have been observed not only in the hot cores surrounding low- and high- mass protostars, but also in cold dark clouds. Therefore, it is interesting to understand how such species can be formed without the…

Astrophysics of Galaxies · Physics 2016-06-06 K. -J. Chuang , G. Fedoseev , S. Ioppolo , E. F. van Dishoeck , H. Linnartz

Methanol is a key species in astrochemistry since it is the most abundant organic molecule in the ISM and is thought to be the mother molecule of many complex organic species. Estimating the deuteration of methanol around young protostars…

Complex organic molecules are ubiquitous companions of young low-mass protostars. Recent observations suggest that their emission stems, not only from the traditional hot corino, but also from offset positions. In this work, 2D…

Solar and Stellar Astrophysics · Physics 2015-05-22 Maria N. Drozdovskaya , Catherine Walsh , Ruud Visser , Daniel Harsono , Ewine F. van Dishoeck