Related papers: Non-thermal desorption of complex organic molecule…
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…
Complex organic molecules (COMs) are known to be abundant toward some low-mass young stellar objects (YSOs), but how these detections relate to typical COM abundance are not yet understood. We aim to constrain the frequency distribution of…
The standard model of cosmic ray heating-induced desorption of interstellar ices is based on a continuous representation of the sporadic desorption of ice mantle components from classical (0.1 micron) dust grains. This has been re-evaluated…
Complex organic molecules (COMs) have been observed in comets, hot cores and cold dense regions of the interstellar medium. It is generally accepted that these COMs form on icy dust grain through the recombination reaction of radicals…
In molecular clouds at temperatures as low as 10 K, all species except hydrogen and helium should be locked in the heterogeneous ice on dust grain surfaces. Nevertheless, astronomical observations have detected over 150 different species in…
Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…
In cold core of dark molecular clouds, where the UV radiation from external sources is strongly attenuated, cosmic rays can induce chemical reactions on the surface of ice-covered grains promoting the ejection of the processed material to…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
The photodesorption of icy grain mantles has been claimed to be responsible for the abundance of gas-phase molecules toward cold regions. Being water a ubiquitous molecule, it is crucial to understand its role in photochemistry and its…
The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…
The destiny of complex organic molecules (COMs) in star-forming regions is interlinked with various evolutionary phases. Therefore, identifying these species in diversified environments of identical star-forming regions would help to…
Cavity-enhanced frequency comb spectroscopy for molecule detection in the mid-infrared powerfully combines high resolution, high sensitivity, and broad spectral coverage. However, this technique, and essentially all spectroscopic methods,…
The increasing sensitivity and resolution of ground-based telescopes have enabled the detection of gas-phase complex organic molecules (COMs) across a variety of environments. Many of the detected species are expected to form on the icy…
Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV…
Complex organic molecules are only detected toward a fraction of high-mass protostars. The goal of this work is to investigate whether high-mass disks can explain the lack of methanol emission from some massive protostellar systems. We…
Remote observations of comets, especially using high spectral resolution millimeter spectroscopy, have enabled the detection of over 25 molecules in comets for the last twenty years. Among the molecules identified at radio wavelengths,…
Pure acetonitrile (CH3CN) and mixed CO:CH3CN and H2O:CH3CN ices have been irradiated at 15K with Vacuum UltraViolet (VUV) photons in the 7-13.6 eV range using synchrotron radiation. VUV photodesorption yields of CH3CN and of photo-products…
Methanol and complex organic molecules have been found in cold starless cores, where a standard warm-up scenario would not work because of the absence of heat sources. A recent chemical model attributed the presence of methanol and large…
Many species of complex organic molecules (COMs) have been observed in several astrophysical environments but it is not clear how they are produced, particularly in cold, quiescent regions. One process that has been proposed as a means to…
At the low temperatures found in the interior of dense clouds and circumstellar regions, along with H$_2$O and smaller amounts of species such as CO, CO$_2$, or CH$_3$OH, the infrared features of CH$_4$ have been observed on icy dust…