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We have performed high resolution x-ray scattering measurements on single crystal samples of Ba(Fe(1-x)Cr(x))2As2 (x = 0 to 0.335). These measurements examine the effect of Cr-doping on the high temperature tetragonal (I4/mmm) to low…

Strongly Correlated Electrons · Physics 2012-03-06 J. P. Clancy , B. D. Gaulin , A. S. Sefat

In ferroelectricity, atomic-scale dipole moments interact collectively to produce strong electro-mechanical coupling and switchable macroscopic polarization. Hence, the functionality of ferroelectrics emerges at a solid-solid phase…

Materials Science · Physics 2019-08-21 Maya Barzilay , Hemaprabha Elangovan , Yachin Ivry

We have investigated the electronic structure of the transition metal oxide Ca3Ru2O7 within density functional theory using the generalized gradient approximation while considering strong Coulomb correlations in the framework of the fully…

Strongly Correlated Electrons · Physics 2024-04-22 V. N. Antonov , D. A. Kukusta , L. V. Bekenov

Charged domain walls and boundaries in ferroelectric materials display distinct phenomena, such as an increased conductivity due to the accumulation of bound charges. Here, we report the electron microscopy observations of atomic-scale…

A correlation between structure and vibrational properties related to a ferroelectric to paraelectric phase transition in perovskite Pb(1-x)(Na0.5Sm0.5)xTiO3 (PNST - x) polycrystalline powders is discussed. Substitution leads to reduction…

We report the temperature dependent x-ray powder diffraction of the FeAs-based superconductors in the range between 300 K and 95 K. In the case of NdOFeAs we have detected the structural phase transition from the tetragonal phase, with…

Superconductivity · Physics 2009-01-12 Alessandro Ricci , Michela Fratini , Antonio Bianconi

The structural phase transition in hexagonal BaMnO$_3$ occurring at $T_c$=130 K was studied in ceramic samples using electron and X-ray diffraction, second harmonic generation as well as by dielectric and lattice dynamic spectroscopies. The…

The compound, Nd7Rh3, crystallizing in Th7Fe3-type hexagonal structure, was previously known to exhibit two magnetic transitions, one at 32 K and the other at 10 K (in zero magnetic field). Here, we report the existence of a field-induced…

Strongly Correlated Electrons · Physics 2009-11-11 Kausik Sengupta , E. V. Sampathkumaran

The crystal structures of the triangular lattice, layered anhydrous alums KCr(SO4)2, RbCr(SO4)2 and KAl(SO4)2 are characterized by X-ray and neutron powder diffraction at temperatures between 1.4 and 773 K. The compounds all crystallize in…

Materials Science · Physics 2009-02-24 D. V. West , Q. Huang , H. W. Zandbergen , T. M. McQueen , R. J. Cava

Full pattern Le-Bail refinement using x-ray powder diffraction profiles of Sr1-xCaxTiO3 for x=0.02, 0.04 in the temperature range 12 to 300 K reveals anomalies in the unit cell parameters at 170, 225 K due to an antiferrodistortive (cubic…

Materials Science · Physics 2015-05-13 Sanjay Kumar Mishra , Dhananjai Pandey

Motivated by the recent observation of superconductivity with $T_c \sim 80$ K in pressurized La3Ni2O7 [Nature 621, 493 (2023)], we explore the structural and electronic properties in A3Ni2O7 bilayer nickelates (A=La-Lu, Y, Sc) as a function…

In this study, we succeeded in synthesizing new antiperovskite phosphides $M$Pd$_3$P ($M$ = Ca, Sr, Ba) and discovered the appearance of a superconducting phase (0.17 $\leq$ $x$ $\leq$ 0.55) in a solid solution (Ca$_{1-x}$Sr$_x$)Pd$_3$P.…

Hybrid organometallic systems offer a wide range of functionalities, including magnetoelectric interactions. However, the ability to design on-demand ME coupling remains challenging despite a variety of host-guest configurations and ME…

La$_3$Ni$_2$O$_7$, a bilayer nickelate with Ruddlesden-Popper structure, undergoes a pressure-induced structural transition from a tilted Amam phase to an untilted Fmmm (or I4/mmm) phase near 10-15 GPa, concomitant with the emergence of…

Atomic structure and electronic band structure are fundamental properties for understanding the mechanism of superconductivity. Motivated by the discovery of pressure-induced high-temperature superconductivity at 80 K in the bilayer…

In the present study, structural changes due to gradual doping of Sr in BaTiO3 were investigated by both x-ray and neutron powder diffraction techniques. Ba1-xSrxTiO3 (x=0.0, 0.5 and 1.0) samples were synthesized by PVA evaporation method…

Materials Science · Physics 2020-07-03 I. B. Elius , B. M. Asif , J. Maudood , T. K. Datta , A. K. M. Zakaria , S. Hossain , M. S. Aktar , I. Kamal

We investigate the optical conductivity of Sr$_{1-x}$Ca$_x$RuO$_3$ across the ferromagnetic to paramagnetic transition that occurs at $x=0.8$. The thin films were grown by metalorganic aerosol deposition with $0 \leq x \leq 1$ onto…

Strongly Correlated Electrons · Physics 2016-06-09 Diana Geiger , Uwe S. Pracht , Martin Dressel , Jernej Mravlje , Melanie Schneider , Philipp Gegenwart , Marc Scheffler

Charged polar interfaces such as charged ferroelectric domain walls or heterostructured interfaces of ZnO/(Zn,Mg)O and LaAlO3/SrTiO3, across which the normal component of electric polarization changes suddenly, can host large…

Materials Science · Physics 2016-06-06 F. -T. Huang , F. Xue , B. Gao , L. H. Wang , X. Luo , W. Cai , X. Lu , J. M. Rondinelli , L. Q. Chen , S. -W. Cheong

Scanning tunnelling spectroscopy measurements were performed on La0.7Sr0.3MnO3 thin films both at room temperature and liquid nitrogen temperature. While no inhomogeneities were recorded at liquid nitrogen temperature on any sample, a clear…

Strongly Correlated Electrons · Physics 2009-11-11 R. Di Capua , C. A. Perroni , V. Cataudella , F. Miletto Granozio , P. Perna , M. Salluzzo , U. Scotti Di Uccio , R. Vaglio

Samples of Y0.4Pr0.6Ba2-xSrxCu3O7 have been synthesized by a solid- state reaction route. The samples with x = 0.60 crystallize in an orthorhombic structure (with orthorhombic distortion decreasing with increasing x), while the samples with…