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Liquids near the glass transition exhibit dynamical heterogeneity, i.e. local relaxation rates fluctuate strongly over space and time. Here we introduce a simple continuum model that allows for quantitative predictions for the correlators…

Soft Condensed Matter · Physics 2024-03-20 Rajib K. Pandit , Horacio E. Castillo

Athermal plastic flows were simulated for the Kob-Andersen binary Lennard-Jones system and its repulsive version in which the sign of the attractive terms is changed to a plus. Properties evaluated from simulations at different densities…

Soft Condensed Matter · Physics 2014-11-25 Edan Lerner , Nicholas P. Bailey , Jeppe C. Dyre

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

We examine the structural and dynamic properties of confined binary hard-sphere mixtures designed to mimic realizable colloidal thin films. Using computer simulations, governed by either Newtonian or overdamped Langevin dynamics, together…

Soft Condensed Matter · Physics 2015-05-01 Jonathan A. Bollinger , Avni Jain , James Carmer , Thomas M. Truskett

The relationship between spatially heterogeneous dynamics (SHD) and jamming is studied in a glass-forming binary Lennard-Jones system via molecular dynamics simulations. It has been suggested that the probability distribution of…

Disordered Systems and Neural Networks · Physics 2007-05-23 Naida Lacevic , Sharon C. Glotzer

We investigate a binary Lennard-Jones mixture with molecular dynamics simulations. We consider first a system cooled linearly in time with the cooling rate gamma. By varying gamma over almost four decades we study the influence of the…

Statistical Mechanics · Physics 2015-06-25 K. Vollmayr-Lee , W. Kob , K. Binder , A. Zippelius

The phenomenology of glass-forming liquids is often described in terms of their underlying, high-dimensional potential energy surface. In particular, the statistics of stationary points sampled as a function of temperature provides useful…

Statistical Mechanics · Physics 2021-01-06 Masanari Shimada , Daniele Coslovich , Hideyuki Mizuno , Atsushi Ikeda

The hypersphere model is a simple one-parameter model of the potential energy landscape of viscous liquids, which is defined as a percolating system of same-radius hyperspheres randomly distributed in $\mathbb{R}^{3N}$ in which $N$ is the…

Soft Condensed Matter · Physics 2025-05-02 Mark F. B. Railton , Eva Uhre , Jeppe C. Dyre , Thomas B. Schrøder

Glass-forming liquids are broadly classified as being fragile or strong, depending on the deviation from Arrhenius behavior of their relaxation times. A fragile to strong crossover is observed or inferred in liquids like water and silica,…

Soft Condensed Matter · Physics 2022-04-12 Pallai Das , Srikanth Sastry

We use molecular dynamics (MD) to simulate an unstable homogeneous mixture of binary fluids (AB), confined in a slit pore of width $D$. The pore walls are assumed to be flat and structureless, and attract one component of the mixture (A)…

Disordered Systems and Neural Networks · Physics 2009-11-11 S. K. Das , S. Puri Jawaharlal , J. Horbach , Kurt Binder

We explore the nature of glass-formation in variable spatial dimensionality ($d$) based on the generalized entropy theory, a synthesis of the Adam-Gibbs model with direct computation of the configurational entropy of polymer fluids using an…

Soft Condensed Matter · Physics 2016-11-09 Wen-Sheng Xu , Jack F. Douglas , Karl F. Freed

A thermodynamic approach to derive the liquid-glass transition line in the reduced temperature vs reduced density plane for a monatomic Lennard-Jones fluid is presented. The approach makes use of a recent reformulation of the classical…

Statistical Mechanics · Physics 2009-11-07 M. Robles , M. López de Haro

The classic Kob-Andersen (KA) binary Lennard-Jones mixtures which are designed to prevent crystallization has been extensively studied in simulation of slow dynamics. Although crystallization can occur if a liquid system is cooled slowly,…

Soft Condensed Matter · Physics 2017-03-10 Penghui Cao

Time-dependent dynamical properties of a fluid can not be estimated from a single configuration without performing a simulation. Here we show, however, that the scaling properties of both structure and dynamics can be predicted from a…

Soft Condensed Matter · Physics 2022-12-21 Thomas B. Schrøder

Glass forming liquids exhibit a rich phenomenology upon confinement. This is often related to the effects arising from wall-fluid interactions. Here we focus on the interesting limit where the separation of the confining walls becomes of…

Soft Condensed Matter · Physics 2014-07-25 S. Mandal , S. Lang , M. Gross , M. Oettel , D. Raabe , T. Franosch , F. Varnik

We study the diffusivity of a small particle immersed in a square box filled with a non-ideal multicomponent fluid in the presence of thermal fluctuations. Our approach is based on the numerical integration of fluctuating lattice Boltzmann…

Fluid Dynamics · Physics 2021-12-14 Xiao Xue , Luca Biferale , Mauro Sbragaglia , Federico Toschi

The mass transport in soft-sphere mixtures of small and big particles as well as in the disordered Lorentz gas (LG) model is studied using molecular dynamics (MD) computer simulations. The soft-sphere mixture shows anomalous small-particle…

Statistical Mechanics · Physics 2010-11-19 Jürgen Horbach , Thomas Voigtmann , Felix Höfling , Thomas Franosch

We review the physics of jamming from the theoretical, experimental and numerical perspectives. We summarize the mean-field theory of jamming and the marginally stable solid phase, with particular emphasis on the connection with the Replica…

Soft Condensed Matter · Physics 2022-09-08 Francesco Arceri , Eric I. Corwin , Corey S. O'Hern

Bulk metallic glasses (BMGs) are produced by rapidly thermally quenching supercooled liquid metal alloys below the glass transition temperature at rates much faster than the critical cooling rate R_c below which crystallization occurs. The…

We study by molecular dynamics computer simulation a binary soft-sphere mixture that shows a pronounced decoupling of the species' long-time dynamics. Anomalous, power-law-like diffusion of small particles arises, that can be understood as…

Statistical Mechanics · Physics 2013-05-29 Th. Voigtmann , J. Horbach