A simple model for dynamic heterogeneity in glass-forming liquids
Abstract
Liquids near the glass transition exhibit dynamical heterogeneity, i.e. local relaxation rates fluctuate strongly over space and time. Here we introduce a simple continuum model that allows for quantitative predictions for the correlators describing these fluctuations. We find remarkable agreement of the model predictions for the dynamic susceptibility with numerical results for a binary hard-sphere liquid and for a Kob-Andersen Lennard-Jones mixture. Under this model, the lifetime of the heterogeneities has little effect on the position of the peak of , but it controls the decay of after the peak, and we show how to estimate it from this decay.
Keywords
Cite
@article{arxiv.2212.12991,
title = {A simple model for dynamic heterogeneity in glass-forming liquids},
author = {Rajib K. Pandit and Horacio E. Castillo},
journal= {arXiv preprint arXiv:2212.12991},
year = {2024}
}
Comments
v3: Simplified notation to improve readability. Added one figure. Fixed one error. Now 4 figures plus one figure in supplemental material. v4: One footnote added. Fig 4 color labeling fixed