English

A simple model for dynamic heterogeneity in glass-forming liquids

Soft Condensed Matter 2024-03-20 v4 Disordered Systems and Neural Networks

Abstract

Liquids near the glass transition exhibit dynamical heterogeneity, i.e. local relaxation rates fluctuate strongly over space and time. Here we introduce a simple continuum model that allows for quantitative predictions for the correlators describing these fluctuations. We find remarkable agreement of the model predictions for the dynamic susceptibility χ4(t)\chi_4(t) with numerical results for a binary hard-sphere liquid and for a Kob-Andersen Lennard-Jones mixture. Under this model, the lifetime τex\tau_{\rm ex} of the heterogeneities has little effect on the position t=t4ταt = t_4 \sim \tau_{\alpha} of the peak of χ4(t)\chi_4(t), but it controls the decay of χ4(t)\chi_4(t) after the peak, and we show how to estimate it from this decay.

Keywords

Cite

@article{arxiv.2212.12991,
  title  = {A simple model for dynamic heterogeneity in glass-forming liquids},
  author = {Rajib K. Pandit and Horacio E. Castillo},
  journal= {arXiv preprint arXiv:2212.12991},
  year   = {2024}
}

Comments

v3: Simplified notation to improve readability. Added one figure. Fixed one error. Now 4 figures plus one figure in supplemental material. v4: One footnote added. Fig 4 color labeling fixed