English

Viscous liquid dynamics modeled as random walks within overlapping hyperspheres

Soft Condensed Matter 2025-05-02 v2 Disordered Systems and Neural Networks Statistical Mechanics

Abstract

The hypersphere model is a simple one-parameter model of the potential energy landscape of viscous liquids, which is defined as a percolating system of same-radius hyperspheres randomly distributed in R3N\mathbb{R}^{3N} in which NN is the number of particles. We study random walks within overlapping hyperspheres in 12 to 45 dimensions, i.e., above the percolation threshold, utilizing an algorithm for on-the-fly placement of the hyperspheres in conjunction with the kinetic Monte Carlo method. We find behavior typical of viscous liquids; thus decreasing the hypersphere density (corresponding to decreasing the temperature) leads to a slowing down of the dynamics by many orders of magnitude. The shape of the mean-square displacement as a function of time is found to be similar to that of the Kob-Andersen binary Lennard-Jones mixture and the Random Barrier Model, which predicts well the frequency-dependent fluidity of nine glass-forming liquids of different chemistry [Bierwirth et al., Phys. Rev. Lett. 119,248001(2017)\mathbf{119}, 248001\,(2017)].

Keywords

Cite

@article{arxiv.2407.19952,
  title  = {Viscous liquid dynamics modeled as random walks within overlapping hyperspheres},
  author = {Mark F. B. Railton and Eva Uhre and Jeppe C. Dyre and Thomas B. Schrøder},
  journal= {arXiv preprint arXiv:2407.19952},
  year   = {2025}
}
R2 v1 2026-06-28T17:56:47.966Z