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Electronic level alignment at the interface between an adsorbed molecular layer and a semiconducting substrate determines the activity and efficiency of many photocatalytic materials. Standard density functional theory (DFT) based methods…

Materials Science · Physics 2014-08-28 Annapaoala Migani , Duncan J. Mowbray , Jin Zhao , Hrvoje Petek , Angel Rubio

The physics of electronic energy level alignment at interfaces formed between molecules and metals can in general be accurately captured by the \emph{ab initio} $GW$ approach. However, the computational cost of such $GW$ calculations for…

Materials Science · Physics 2019-06-27 Zhen-Fei Liu , Felipe H. da Jornada , Steven G. Louie , Jeffrey B. Neaton

Molecule-metal interfaces have a broad range of applications in nanoscale materials science. Accurate characterization of their electronic structures from first-principles is key in understanding material and device properties. The GW…

Materials Science · Physics 2020-02-05 Zhenfei Liu

The self-consistent theory of the correlation effects in Highly Correlated Systems(HCS) is presented. The novel Irreducible Green's Functions(IGF) method is discused in detail for the Hubbard model and random Hubbard model. The…

Strongly Correlated Electrons · Physics 2008-02-03 A. L. Kuzemsky

We present an approach to calculate the electronic structure for a range of materials using the quasiparticle self-consistent GW method with vertex corrections included in the screened Coulomb interaction W. This is achieved by solving the…

Materials Science · Physics 2023-10-10 Brian Cunningham , Myrta Gruening , Dimitar Pashov , Mark van Schilfgaarde

We present a tight-binding based GW approach for the calculation of quasiparticle energy levels in confined systems such as molecules. Key quantities in the GW formalism like the microscopic dielectric function or the screened Coulomb…

Materials Science · Physics 2009-11-10 T. A. Niehaus , M. Rohlfing , F. Della Sala , A. Di Carlo , Th. Frauenheim

Room temperature ionic liquids play an important role in many technological applications and a detailed understanding of their frontier molecular orbitals is required to optimize interfacial barriers, reactivity and stability with respect…

Materials Science · Physics 2020-07-01 J. Matthias Kahk , Ivar Kuusik , Vambola Kisand , Kevin R. J. Lovelock , Johannes Lischner

We present a quasiparticle self-consistent $GW$ (QSGW) implementation for periodic systems based on crystalline Gaussian basis sets. Our QSGW approach is based on a full-frequency analytic continuation GW scheme with Brillouin zone sampling…

Chemical Physics · Physics 2022-12-21 Jincheng Lei , Tianyu Zhu

The electronic structure of surfaces and interfaces plays a key role in the properties of quantum devices. Here, we study the electronic structure of realistic Al/InAs/Al heterojunctions using a combination of density functional theory…

Mesoscale and Nanoscale Physics · Physics 2024-11-06 H. Ness , F. Corsetti , D. Pashov , B. Verstichel , G. W. Winkler , M. van Schilfgaarde , R. M. Lutchyn

We have implemented the so called GW approximation (GWA) based on an all-electron full-potential Projector Augmented Wave (PAW) method. For the screening of the Coulomb interaction W we tested three different plasmon-pole dielectric…

Materials Science · Physics 2007-05-23 B. Arnaud , M. Alouani

By means of full-potential all-electron density-functional theory and many-body perturbation theory, we compute the band alignment at a prototypical hybrid inorganic/organic interface. The electronic properties of a model system built of…

Materials Science · Physics 2019-08-21 Dmitrii Nabok , Benjamin Höffling , Claudia Draxl

Accurate and efficient predictions of the quasiparticle properties of complex materials remain a major challenge due to the convergence issue and the unfavorable scaling of the computational cost with respect to the system size.…

Materials Science · Physics 2020-07-14 Weiyi Xia , Weiwei Gao , Gabriel Lopez-Candales , Yabei Wu , Wei Ren , Wenqing Zhang , Peihong Zhang

The calculation of quasi-particle spectra based on the GW approximation is extended to systems of hundreds of atoms, thus expanding the size range of current approaches by more than one order of magnitude. This is achieved through an…

Materials Science · Physics 2008-11-11 P. Umari , Geoffrey Stenuit , Stefano Baroni

We present low-scaling algorithms for $GW$ and constrained random phase approximation based on a symmetry-adapted interpolative separable density fitting (ISDF) procedure that incorporates the space-group symmetries of crystalline systems.…

Materials Science · Physics 2024-01-24 Chia-Nan Yeh , Miguel A. Morales

A new method which allows one to study multiple coherent reflection/transmissions by partially transparent interfaces, (e.g., in multi-layer mesoscopic structures or grain boundaries in high-Tc's), in the framework of the quasiclassical…

Superconductivity · Physics 2009-10-31 A. Shelankov , M. Ozana

Photo-emission spectroscopy directly probes individual electronic states, ranging from single excitations to high-energy satellites, which simultaneously represent multiple quasiparticles (QPs) and encode information about electronic…

We generalize a graph-based multiclass semi-supervised classification technique based on diffuse interface methods to multilayer graphs. Besides the treatment of various applications with an inherent multilayer structure, we present a very…

Machine Learning · Computer Science 2022-03-24 Kai Bergermann , Martin Stoll , Toni Volkmer

The incommensurate 30$^{\circ}$ twisted bilayer graphene (BG) possesses both relativistic Dirac fermions and quasiperiodicity with 12-fold rotational symmetry arising from the interlayer interaction…

Mesoscale and Nanoscale Physics · Physics 2022-03-14 Guodong Yu , Yunhua Wang , Mikhail I. Katsnelson , Hai-Qing Lin , Shengjun Yuan

The GW method is a many-body electronic structure technique capable of generating accurate quasiparticle properties for realistic systems spanning physics, chemistry, and materials science. Despite its power, GW is not routinely applied to…

Computational Physics · Physics 2020-02-19 Minjung Kim , Glenn J. Martyna , Sohrab Ismail-Beigi

In recent years, interface quasi-Newton methods have gained growing attention in the fluid-structure interaction community by significantly improving partitioned solution schemes: They not only help to control the inherent added-mass…

Computational Engineering, Finance, and Science · Computer Science 2020-01-23 Thomas Spenke , Norbert Hosters , Marek Behr
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