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The structural arrest of a polymeric suspension might be driven by an increase of the cross--linker concentration, that drives the gel transition, as well as by an increase of the polymer density, that induces a glass transition. These…

Statistical Mechanics · Physics 2014-06-20 Nagi Khalil , Antonio Coniglio , Antonio de Candia , Annalisa Fierro , Massimo Pica Ciamarra

As liquids approach the glass transition temperature, dynamical heterogeneity emerges as a crucial universal feature of their behavior. Dynamic facilitation, where local motion triggers further motion nearby, plays a major role in this…

Amorphous solids, or glasses, are distinguished from crystalline solids by their lack of long-range structural order. At the level of two-body structural correlations, glassformers show no qualitative change upon vitrifying from a…

Soft Condensed Matter · Physics 2015-06-11 C. Patrick Royall , Stephen R. Williams

Liquid drops slide more slowly over soft, deformable substrates than over rigid solids. This phenomenon can be attributed to the viscoelastic dissipation induced by the moving wetting ridge, which inhibits a rapid motion, and is called…

We perform stringent tests of thermodynamic theories of the glass transition over the experimentally relevant temperature regime for several simulated glass-formers. The swap Monte Carlo algorithm is used to estimate the configurational…

Statistical Mechanics · Physics 2019-10-03 Misaki Ozawa , Camille Scalliet , Andrea Ninarello , Ludovic Berthier

We use numerical simulations to study the dynamics of dense assemblies of self-propelled particles in the limit of extremely large, but finite, persistence times. In this limit, the system evolves intermittently between mechanical…

Soft Condensed Matter · Physics 2023-06-09 Yann-Edwin Keta , Rituparno Mandal , Peter Sollich , Robert L. Jack , Ludovic Berthier

Systems of dense spheres interacting through very short-ranged attraction are known from theory, simulations and colloidal experiments to exhibit dynamical reentrance. The liquid state can thus be fluidized to higher densities than…

Statistical Mechanics · Physics 2020-08-13 Patrick Charbonneau , Joyjit Kundu

One of the greatest challenges in contemporary condensed matter physics is to ascertain whether the formation of glasses from liquids is fundamentally thermodynamic or dynamic in origin. While the thermodynamic paradigm has dominated…

Soft Condensed Matter · Physics 2015-06-22 Chandan K. Mishra , K. Hima Nagamanasa , Rajesh Ganapathy , A. K. Sood , Shreyas Gokhale

Enormous enhancement in the viscosity of a liquid near its glass transition is generally connected to the growing many-body static correlations near the transition, often coined as `amorphous ordering'. Estimating the length scales of such…

Building on the recently derived inhomogeneous mode-coupling theory, we extend the generalised mode-coupling theory of supercooled liquids to inhomogeneous environments. This provides a first-principles-based, systematic and rigorous way of…

Statistical Mechanics · Physics 2023-01-11 Corentin C. L. Laudicina , Chengjie Luo , Kunimasa Miyazaki , Liesbeth M. C. Janssen

We simulate a densely jammed, athermal assembly of repulsive soft particles immersed in a solvent. Starting from an initial condition corresponding to a quench from a high temperature, we find non-trivial slow dynamics driven by a gradual…

Soft Condensed Matter · Physics 2019-09-11 Rahul N. Chacko , Peter Sollich , Suzanne M. Fielding

Using molecular dynamics computer simulations we investigate how the relaxation dynamics of a simple supercooled liquid with Newtonian dynamics differs from the one with a stochastic dynamics. We find that, apart from the early…

Statistical Mechanics · Physics 2009-10-31 Tobias Gleim , Walter Kob , Kurt Binder

Supercooled liquid is described in terms of the theory of defected states of bond orientational order using the continuous theory of defects. It is shown that the initiation of a local orientation order leads to the breakdown of the initial…

Disordered Systems and Neural Networks · Physics 2008-09-10 M. G. Vasin

We identify the pattern of microscopic dynamical relaxation for a two dimensional glass forming liquid. On short timescales, bursts of irreversible particle motion, called cage jumps, aggregate into clusters. On larger time scales, clusters…

Soft Condensed Matter · Physics 2010-10-04 R. Candelier , A. Widmer-Cooper , J. K. Kummerfeld , O. Dauchot , G. Biroli , P. Harrowell , D. R. Reichman

Dynamical heterogeneity is a signature phenomenon of deeply supercooled liquids and glasses. Here, we demonstrate that the spatiotemporal correlations between local relaxation events that underpin it are the result of local relaxation…

Soft Condensed Matter · Physics 2024-12-05 Rahul N. Chacko

In a recent computer study, we have shown that the combination of spatially heterogeneous dynamics and kinetic facilitation provides a microscopic explanation for the emergence of excess wings in deeply supercooled liquids. Motivated by…

Soft Condensed Matter · Physics 2021-08-25 Camille Scalliet , Benjamin Guiselin , Ludovic Berthier

When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

Statistical Mechanics · Physics 2009-05-12 Andrea Cavagna

Recent numerical studies have identified the persistence time of active motion as a critical parameter governing glassy dynamics in dense active matter. Here we studied dynamics in liquids of granular active ellipsoids with tunable…

Soft Condensed Matter · Physics 2022-05-11 Pragya Arora , A K Sood , Rajesh Ganapathy

We study the role of elasticity-induced facilitation on the dynamics of glass-forming liquids by a coarse-grained two-dimensional model in which local relaxation events, taking place by thermal activation, can trigger new relaxations by…

Disordered Systems and Neural Networks · Physics 2023-04-05 Misaki Ozawa , Giulio Biroli

We compare theoretical and simulation results for static and dynamic properties for a model of particles interacting via a spherically symmetric repulsive ramp potential. The model displays anomalies similar to those found in liquid water,…

Statistical Mechanics · Physics 2009-11-10 Pradeep Kumar , Sergey V. Buldyrev , Francesco Sciortino , Emanuela Zaccarelli , H. Eugene Stanley