Related papers: WKB-approach for the 1D hydrogen atom
A new approach to chemical bonding is introduced in order to provide an improved understanding of the connection between basic quantum mechanics and the covalent pair bond. It's focus is on the fact that the energy of the bond is largely…
We develop a quantum algorithm for estimating the free energy as well as the total Gibbs state of interacting quantum Coulomb gases and molecular systems in dimensions $d \in \{2,3\}$ at finite temperature. These systems lie beyond the…
Combining the WKB expansion at large distances and Perturbation Theory at small distances it is constructed a compact uniform approximation for eigenfunctions. For lowest states $1s\si_{g}$ and $2p\si_{u}$ this approximation provides the…
The leading long-distance 1-loop quantum corrections to the Coulomb potential are derived for scalar QED and their gauge-independence is explicitly checked. The potential is obtained from the direct calculation of the 2-particle scattering…
For one-dimensional power-like potentials $|x|^m, m > 0$ the Bohr-Sommerfeld Energies (BSE) extracted explicitly from the Bohr-Sommerfeld quantization condition are compared with the exact energies. It is shown that for the ground state as…
This article illustrates the bound states of Kemmer equation for spin-1 particles. The asymptotic, exact and Coulomb field solutions are obtained by using action principle. In the conclusion the energy spectrum of spin-1 particles moving in…
Extending our previous work \cite{filinov-etal.jpa03ik} we present a detailed discussion of accuracy and practical applications of finite-temperature pseudopotentials for two-component Coulomb systems. Different pseudopotentials are…
We discuss the equivalent form of Levy-Leblond equation [1, 2] such that the nilpotent matrices are two dimensional. We show that this equation can be obtained in the non-relativistic limit of the (2+1) dimensional Dirac equation.…
We substantiate the need for account of the proper electromagnetic field of the electron in the canonical problem of hydrogen in relativistic quantum mechanics. From mathematical viewpoint, the goal is equivalent to determination of the…
We show that the exact wave function for two electrons, interacting through a Coulomb potential but constrained to remain on the surface of a $\mathcal{D}$-sphere ($\mathcal{D} \ge 1$), is a polynomial in the interelectronic distance $u$…
It usually writes the boundary condition of the wave equation in the Coulomb field as a rough form without considering the size of the atomic nucleus. The rough expression brings on that the solutions of the Klein-Gordon equation and the…
The hydrogen atom perturbed by a constant 1-dimensional weak quadratic potential $\lambda z^2$ is solved at first-order perturbation theory using the eigenstates of the total angular momentum operator - the coupled basis. Physical…
Easy physics-inspired approximations of the total and binding energies for the ${\rm H}$ atom and for the molecular ions $${\rm H}_2^{(+)} ({\rm ppe}), {\rm H}_3^{(2+)} ({\rm pppe}), ({\rm HeH})^{++} (\al {\rm p e}), {\rm He}_2^{(3+)} (\al…
We prove a new lower bound on the indirect Coulomb energy in quantum mechanics in terms of the single particle density of the system. The new universal lower bound is an alternative to the classical Lieb--Oxford bound (with a smaller…
In this thesis, we construct an approximate series solution of the Wigner equation in terms of Airy functions, which are semiclassically concentrated on certain Lagrangian curves in two-dimensional phase space. These curves are defined by…
We propose a general method for constructing system-dependent basis functions for correlated quantum chemical calculations. Our construction combines features from several traditional approaches: plane waves, localized basis functions, and…
A novel method for the exact solvability of quantum systems is discussed and used to obtain closed analytical expressions in arbitrary dimensions for the exact solutions of the hydrogenic atom in the external potential $\Delta…
The position and momentum probability densities of a multidimensional quantum system are fully characterized by means of the radial expectation values $\langle r^\alpha \rangle$ and $\left\langle p^\alpha \right\rangle$, respectively. These…
We report on a multiband microscopic theory of many-exciton complexes in self-assembled quantum dots. The single particle states are obtained by three methods: single-band effective-mass approximation, the multiband $k\cdot p$ method, and…
We present a definition of the two-sided inverse of position operator in general case of deformed Heisenberg algebra leading to minimal length. Energy spectrum and eigenfunctions in momentum space for 1D Coulomb-like potential in deformed…