Related papers: WKB-approach for the 1D hydrogen atom
The exactness of the semiclassical method for three-dimensional problems in quantum mechanics is analyzed. The wave equation appropriate in the quasiclassical region is derived. It is shown that application of the standard leading-order WKB…
A simple methodology is suggested for the efficient calculation of certain central potentials having singularities. The generalized pseudospectral method used in this work facilitates {\em nonuniform} and optimal spatial discretization.…
We consider the solution of the quantum Coulomb problem in one dimension with the most general connection condition at the origin. The divergence of the derivative of the wave function at the origin invalidates the standard current…
We consider one particle confined to a deformed one-dimensional wire. The quantum mechanical equivalent of the classical problem is not uniquely defined. We describe several possible hamiltonians and corresponding solutions for a finite…
In the present work the conditions appearing in the WKB approximation formalism of quantum mechanics are analyzed. It is shown that, in general, a careful definition of an approximation method requires the introduction of two length…
We leverage the power of neural quantum states to describe the ground state wave function of solid and liquid atomic hydrogen, including both electronic and protonic degrees of freedom. For static protons, the resulting Born-Oppenheimer…
Based on classical electrodynamics, it is argued that the Coulomb potential (which is strictly valid for two point charges at rest), commonly used in the study of energy levels of hydrogen atom is not the correct one, because the electron…
We prove a priori bounds for all derivatives of non-relativistic Coulombic eigenfunctions, involving negative powers of the distance to the singularities of the many-body potential. We use these to derive bounds for all derivatives of the…
We analyze quantitatively the accuracy of eigenfunction and eigenvalue calculations in the frame work of WKB and instanton semiclassical methods. We show that to estimate the accuracy it is enough to compare two linearly independent (with…
The numerical version of the Hamilton-Jacobi quantization method, recently proposed, is applied to the one dimensional quartic oscillator. A suitable quantization condition is formulated and various energy levels and wave functions are…
Using the method of the "exact discretization" of the Schr\"odinger equation, we propose a particular discretized version of the N=2 Supersymmetric Quantum Mechanics. After defining the corresponding shape invariance condition, we show that…
We report benchmark results for one-dimensional (1D) atomic and molecular systems interacting via the Coulomb operator $|x|^{-1}$. Using various wavefunction-type approaches, such as Hartree-Fock theory, second- and third-order…
By using the WKB quantization we deduce an analytical formula for the energy splitting in a double--well potential which is the usual Landau formula with additional quantum corrections. Then we analyze the accuracy of our formula for the…
We study the accuracy of several alternative semiclassical methods by computing analytically the energy levels for many large classes of exactly solvable shape invariant potentials. For these potentials, the ground state energies computed…
The methodology based on the association of the Variational Method with Supersymmetric Quantum Mechanics is used to evaluate the energy states of the confined hydrogen atom.
We study quasi-stationary states in quantum mechanics using the exact Wentzel--Kramers--Brillouin (WKB) analysis as a nonperturbative framework. Whereas previous works focused mainly on stable systems, we explore unstable states such as…
The electron interaction energy of two interacting electrons in a circular quantum dot (with hard wall confinement) is investigated in the framework of the semi-classical Wentzel-Kramers-Brillouin (WKB) approximation. The two electrons are…
We analyse the accuracy of the approximate WKB quantization for the case of general one-dimensional quartic potential. In particular, we are interested in the validity of semiclassically predicted energy eigenvalues when approaching the…
The hydrogen atom is a system amenable to an exact treatment within Schroedinger's formulation of quantum mechanics according to coordinates in four systems -- spherical polar, paraboloidal, ellipsoidal and spheroconical coordinates; the…
In this paper we consider the one dimensional quantum hydrodynamics (QHD) system, with a genuine hydrodynamic approach. The global existence of weak solutions with large data has been obtained in [2, 3], in several space dimensions, by…