English

The H$_2^+$ molecular ion: a solution

Quantum Physics 2015-05-27 v2 Mathematical Physics math.MP Atomic Physics

Abstract

Combining the WKB expansion at large distances and Perturbation Theory at small distances it is constructed a compact uniform approximation for eigenfunctions. For lowest states 1s\sig1s\si_{g} and 2p\siu2p\si_{u} this approximation provides the relative accuracy 105\lesssim 10^{-5} (5 s.d.) for any real xx in eigenfunctions and for total energy E(R)E(R) it gives 10-11 s.d. for internuclear distances R[0,50]R \in [0,50]. Corrections to proposed approximations are evaluated. Separation constants and the oscillator strength for the transition 1s\sig\rar2p\siu1s\si_{g} \rar 2p\si_{u} are calculated and compared with existing data.

Keywords

Cite

@article{arxiv.1103.4989,
  title  = {The H$_2^+$ molecular ion: a solution},
  author = {Alexander V. Turbiner and Horacio Olivares-Pilón},
  journal= {arXiv preprint arXiv:1103.4989},
  year   = {2015}
}

Comments

16 pages, 4 figures, 6 tables, typos are corrected and small additions are inserted, to be published at JPB (fast track comm)

R2 v1 2026-06-21T17:44:34.353Z