The H$_2^+$ molecular ion: a solution
Quantum Physics
2015-05-27 v2 Mathematical Physics
math.MP
Atomic Physics
Abstract
Combining the WKB expansion at large distances and Perturbation Theory at small distances it is constructed a compact uniform approximation for eigenfunctions. For lowest states and this approximation provides the relative accuracy (5 s.d.) for any real in eigenfunctions and for total energy it gives 10-11 s.d. for internuclear distances . Corrections to proposed approximations are evaluated. Separation constants and the oscillator strength for the transition are calculated and compared with existing data.
Keywords
Cite
@article{arxiv.1103.4989,
title = {The H$_2^+$ molecular ion: a solution},
author = {Alexander V. Turbiner and Horacio Olivares-Pilón},
journal= {arXiv preprint arXiv:1103.4989},
year = {2015}
}
Comments
16 pages, 4 figures, 6 tables, typos are corrected and small additions are inserted, to be published at JPB (fast track comm)