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Related papers: A High-Entropy Silicide: (Mo0.2Nb0.2Ta0.2Ti0.2W0.2…

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We report the synthesis, crystal structure and physical properties of two new high-entropy silicides (HESs), namely (Nb$_{0.1}$Mo$_{0.3}$W$_{0.3}$Re$_{0.2}$Ru$_{0.1}$)$_{5}$Si$_{3}$ and…

Superconductivity · Physics 2023-02-03 Bin Liu , Wuzhang Yang , Guorui Xiao , Qinqing Zhu , Shijie Song , Guang-Han Cao , Zhi Ren

Five single-phase WB2- and MoB2-containing high-entropy borides (HEBs) have been made via reactive spark plasma sintering of elemental boron and metals. A large reactive driving force enables the full dissolution of 10-20 mol. % WB2 to form…

Materials Science · Physics 2020-05-15 Mingde Qin , Joshua Gild , Haoren Wang , Tyler Harrington , Kenneth S. Vecchio , Jian Luo

We report on the discovery of a high-entropy alloy with a hexagonal crystal structure. Equiatomic samples in the alloy system Ho-Dy-Y-Gd-Tb were found to solidify as homogeneous single-phase high-entropy alloys. The results of our electron…

Materials Science · Physics 2018-03-22 Michael Feuerbacher , Markus Heidelmann , Carsten Thomas

Six high-entropy rare earth tetraborides of the tetragonal UB4-prototyped structure have been successfully synthesized for the first time. The specimens are prepared from elemental precursors via high-energy ball mill and in-situ reactive…

Materials Science · Physics 2020-12-24 Mingde Qin , Qizhang Yan , Haoren Wang , Kenneth S. Vecchio , Jian Luo

A new type of compositionally complex (medium- or high-entropy) M5Si3 silicides is synthesized. Both (V1/5Cr1/5Nb1/5Ta1/5W1/5)5Si3 and (Ti1/5Zr1/5Nb1/5Mo1/5Hf1/5)5Si3 form single-phase homogenous solid solutions. Notably,…

Materials Science · Physics 2021-12-16 Sashank Shivakumar , Mingde Qin , Dawei Zhang , Chongze Hu , Qizhang Yan , Jian Luo

Molybdenum disilicide (MoSi$_2$) is a very promising material for high temperature structural applications due to its high melting point (2030 {\deg}C), low density, high thermal conductivity and good oxidation resistance. However, MoSi$_2$…

We report the synthesis and characterization of metal deficient (Ti$_{0.2}$Zr$_{0.2}$Hf$_{0.2}$Nb$_{0.2}$Ta$_{0.2}$)$_{1-\delta}$B$_{2}$ high-entropy diborides (HEBs). A single homogeneous AlB$_{2}$-type phase is successfully obtained over…

Materials Science · Physics 2023-02-16 Wuzhang Yang , Qinqing Zhu , Guorui Xiao , Zhi Ren

Topological superconductors have drawn significant interest from the scientific community due to the accompanying Majorana fermions. Here, we report the discovery of electronic structure and superconductivity in high-entropy ceramics…

High-purity and superfine high-entropy metal diboride powders, namely (Hf0.2Zr0.2Ta0.2Nb0.2Ti0.2)B2, were successfully synthesized via a facile borothermal reduction method at 1973 K for the first time. The as-synthesized powders with an…

Materials Science · Physics 2019-03-01 Da Liu , Tongqi Wen , Beilin Ye , Yanhui Chu

Single-phase high-entropy monoborides (HEMBs) of the CrB prototype structure have been synthesized for the first time. Reactive spark plasma sintering of ball milled mixtures of elemental precursor powders produced bulk…

Materials Science · Physics 2020-08-12 Mingde Qin , Qizhang Yan , Haoren Wang , Kenneth S. Vecchio , Jian Luo

High-entropy ceramics (HECs) are solid solutions of inorganic compounds with one or more Wyckoff sites shared by equal or near-equal atomic ratios of multi-principal elements. Material design and property tailoring possibilities emerge from…

The high-entropy concept was applied to the synthesis of transition-metal antimonides, M1-xPtxSb (M = equimolar Ru, Rh, Pd, and Ir). High-entropy antimonide samples crystallized in a pseudo-hexagonal NiAs-type crystal structure with a…

Superconductivity · Physics 2025-04-01 Daigorou Hirai , Naoto Uematsu , Koh Saitoh , Naoyuki Katayama , Koshi Takenaka

High-entropy materials often outperform their lower-entropy relatives in various aspects, such as thermal stability and fracture toughness. While there are extensive research activities in the field of high-entropy alloys, comparably little…

Materials Science · Physics 2018-03-01 Paul H. Mayrhofer , Alexander Kirnbauer , Philipp Ertelthaler , Christian M. Koller

Here, we designed two promising schemes to realize the high-entropy structure in a series of quasi-two-dimensional compounds, transition metal dichalcogenides (TMDCs). In the intra-layer high-entropy plan, (HEM)X2 compounds with…

Materials Science · Physics 2021-04-20 Hong Xiang Chen , Sheng Li , Shu Xian Huang , Li An Ma , Sheng Liu , Fang Tang , Yong Fang , Pin Qiang Dai

Fe and 2Si were co-deposited on Si (111) surface at 853 K. The formation of silicides was investigated by Mossbauer spectroscopy and electron microscopy. Depending on the thickness of the deposited films different phases were formed. At low…

Materials Science · Physics 2011-09-23 I. Dézsi , Cs. Fetzer , F. Tanczikó , P. B. Barna , O. Geszti , G. Sáfrán , L. Székely

For the first time, a group of CaB6-typed cubic rare earth high-entropy hexaborides have been successfully fabricated into dense bulk pellets (>98.5% in relative densities). The specimens are prepared from elemental precursors via in-situ…

Recently, robustness of superconductivity (transition temperature, Tc) under high pressures has been observed in high-entropy alloy (HEA), bcc-type Ti-Zr-Hf-Nb-Ta, and HEA-type compounds (Ag,In,Sn,Pb,Bi)Te with a NaCl-type structure. Since…

Ternary silicides MI(MII0.5, Si0.5)2 (MI=Sr and Ba, MII=Al and Ga) were prepared by Ar arc melting. Powder X-ray diffraction indicates that they have the AlB2-type structure, in which Si and MII atoms are arranged in honeycomb layers and MI…

Superconductivity · Physics 2009-11-07 Motoharu Imai , Kenji Nishida , Takashi Kimura , Hideaki Kitazawa , Hideki Abe , Hijiri Kito , Kenji Yoshii

Samples of aligned MgB2 crystallites have been prepared, allowing for the first time the direct identification of an upper critical field anisotropy Hc2^{ab}/Hc2^{c}= xi_{ab}/xi_{c} ~ 1.73; with xi_{o,ab} ~ 70 A, xi_{o,c} ~ 40 A, and a mass…

Superconductivity · Physics 2009-11-07 O. F. de Lima , R. A. Ribeiro , M. A. Avila , C. A. Cardoso , A. A. Coelho

Molybdenum Disulphide (MoS2) is an interesting material which exists in atomically thin multilayers and can be exfoliated into monolayer or a few layers for multiple applications. It has emerged as a promising material for development of…

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