For the first time, a group of CaB6-typed cubic rare earth high-entropy hexaborides have been successfully fabricated into dense bulk pellets (>98.5% in relative densities). The specimens are prepared from elemental precursors via in-situ metal-boron reactive spark plasma sintering. The sintered bulk pellets are determined to be single-phase without any detectable oxides or other secondary phases. The homogenous elemental distributions have been confirmed at both microscale and nanoscale. The Vickers microhardness are measured to be 16-18 GPa at a standard indentation load of 9.8 N. The nanoindentation hardness and Young's moduli have been measured to be 19-22 GPa and 190-250 GPa, respectively, by nanoindentation test using a maximum load of 500 mN. The material work functions are determined to be 3.7-4.0 eV by ultraviolet photoelectron spectroscopy characterizations, which are significantly higher than that of LaB6.
@article{arxiv.2104.12549,
title = {Bulk High-Entropy Hexaborides},
author = {Mingde Qin and Qizhang Yan and Yi Liu and Haoren Wang and Chunyang Wang and Tianjiao Lei and Kenneth S. Vecchio and Huolin L. Xin and Timothy J. Rupert and Jian Luo},
journal= {arXiv preprint arXiv:2104.12549},
year = {2021}
}