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X-Ray transition energies and isotope shifts in heavy atoms are evaluated. The energy levels with vacancies in the inner shells are calculated within the approximation of the average of nonrelativistic configuration employing the…

Atomic Physics · Physics 2018-08-29 I. I. Tupitsyn , N. A. Zubova , V. M. Shabaev , G. Plunien , Th. Stoehlker

X-ray photon correlation spectroscopy (XPCS) allows for the resolution of dynamic processes within a material across a wide range of length and time scales. X-ray speckle visibility spectroscopy (XSVS) is a related method that uses a single…

Numerical Analysis · Mathematics 2023-01-09 Shaswat Mohanty , Christopher B. Cooper , Hui Wang , Mengning Liang , Wei Cai

X-ray absorption spectroscopy is a premier element-specific technique for materials characterization. Specifically, the x-ray absorption near-edge structure (XANES) encodes important information about the local chemical environment of an…

Materials Science · Physics 2019-03-27 Matthew R. Carbone , Shinjae Yoo , Mehmet Topsakal , Deyu Lu

To date X-ray spectroscopy has become a routine tool that can reveal highly local and element-specific information on the electronic structure of atoms in complex environments. Here, we focus on nuclear dynamical effects in X-ray spectra…

Chemical Physics · Physics 2016-08-12 Sven Karsten , Sergei D. Ivanov , Saadullah G. Aziz , Sergey I. Bokarev , Oliver Kühn

The search for a new energy paradigm with net-zero carbon emissions requires new technologies for energy generation and storage that are at the crossroad between engineering, chemistry, physics, surface and materials sciences. To keep…

Materials Science · Physics 2022-03-23 Baptiste Gault , Kevin Schweinar , Siyuan Zhang , Leopold Lahn , Christina Scheu , Se-Ho Kim , Olga Kasian

In this technical review we give an introduction to optical spectroscopy for layered materials as a powerful, non-invasive tool to access details of the electronic band structure and crystal quality. Potential applications in photonics and…

Materials Science · Physics 2020-12-18 Shivangi Shree , Ioannis Paradisanos , Xavier Marie , Cedric Robert , Bernhard Urbaszek

X-ray absorption spectroscopy yields direct access to the electronic and geometric structure of hybrid inorganic-organic interfaces formed upon adsorption of complex molecules at metal surfaces. The unambiguous interpretation of…

Chemical Physics · Physics 2017-06-19 Katharina Diller , Reinhard J. Maurer , Moritz Müller , Karsten Reuter

Transit spectroscopy is a powerful tool to decode the chemical composition of the atmospheres of extrasolar planets. In this paper we focus on unsupervised techniques for analyzing spectral data from transiting exoplanets. We demonstrate…

Earth and Planetary Astrophysics · Physics 2022-01-11 Konstantin T. Matchev , Katia Matcheva , Alexander Roman

Spectral imaging is an umbrella term for energy-resolved x-ray imaging in medicine. The technique makes use of the energy dependence of x-ray attenuation to either increase the contrast-to-noise ratio, or to provide quantitative image data…

Medical Physics · Physics 2021-01-05 Erik Fredenberg

Ongoing developments in ultrafast X-ray sources offer powerful new means of probing the com- plex non-adiabatically coupled structural and electronic dynamics of photoexcited molecules. These non-Born-Oppenheimer effects are governed by…

Chemical Physics · Physics 2018-07-04 Simon P. Neville , Majed Chergui , Albert Stolow , Michael S. Schuurman

Understanding the interaction of intense, femtosecond X-ray pulses with heavy atoms is crucial for gaining insights into the structure and dynamics of matter. One key aspect of nonlinear light-matter interaction was, so far, not studied…

The advent of ultrafast pulsed X-ray free-electron lasers with very high brightness has enabled the determination of transient molecular structures of small and medium-sized organic molecules in excited states and undergoing chemical…

Chemical Physics · Physics 2025-10-07 Peter M. Weber , Brian Stankus , Adam Kirrander

Accurate simulations of transient X-ray photoelectron spectra (XPS) provide unique opportunities to bridge the gap between theory and experiment in understanding the photoactivated dynamics in molecules and materials. However, simulating…

Chemical Physics · Physics 2024-06-19 Nicholas P. Gaba , Carlos E. V. de Moura , Rajat Majumder , Alexander Yu. Sokolov

X-ray interaction with matter is an energy-dependent process that is contingent on the atomic structure of the constituent material elements. The most advanced models to capture this relationship currently rely on Monte Carlo (MC)…

Machine Learning · Computer Science 2023-07-11 Raziye Kubra Kumrular , Thomas Blumensath

Optical spectroscopy techniques such as differential reflectance and transmittance have proven to be very powerful techniques to study 2D materials. However, a thorough description of the experimental setups needed to carry out these…

In this paper we report a spectrometric approach to dual-energy digital radiography that has been developed and applied to identify specific organic substances and discern small differences in their effective atomic number. An experimental…

Instrumentation and Detectors · Physics 2008-10-06 S. V. Naydenov , V. D. Ryzhikov , G. M. Onyshchenko , P. Lecoq , C. Smith

Since its first successful applications in the early 2000s, x-ray Thomson scattering (XRTS) has emerged as one of the most successful tools for the diagnostics of extreme states of matter in the laboratory. By sampling the dynamic structure…

Plasma Physics · Physics 2026-04-28 Tobias Dornheim , Hannah Bellenbaum , Thomas Gawne , Jan Vorberger , Dirk O. Gericke

Dual-energy imaging is a clinically well-established technique that offers several advantages over conventional X-ray imaging. By performing measurements with two distinct X-ray spectra, differences in energy-dependent attenuation are…

X-ray near-field speckle-based phase-sensing approaches provide efficient means to characterise optical elements. Here, we present a theoretical review of several of these speckle methods in the frame of optical characterisation and provide…

X-ray echo spectroscopy, a space-domain counterpart of neutron spin echo, is a recently proposed inelastic x-ray scattering (IXS) technique. X-ray echo spectroscopy relies on imaging IXS spectra, and does not require x-ray…

Optics · Physics 2017-08-04 Yuri Shvyd'ko