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First-principles calculations are performed to investigate the interaction of physisorbed small molecules, including CO, H2, H2O, NH3, NO, NO2, and O2, with phosphorene, and their energetics, charge transfer, and magnetic moment are…

Materials Science · Physics 2015-02-17 Yongqing Cai , Qingqing Ke , Gang Zhang , Yong-Wei Zhang

We theoretically investigate the effects of long-range disorder and electron-electron interactions on the optical properties of hexagonal armchair graphene quantum dots consisting of up to 10806 atoms. The numerical calculations are…

Mesoscale and Nanoscale Physics · Physics 2017-02-08 A. Altıntaş , K. E. Çakmak , A. D. Güçlü

In this work, we present a systematic first-principles density-functional theory based study of geometry, electronic structure, and optical properties of armchair phosphorene nanoribbons (APNRs), with the aim of understanding the influence…

Mesoscale and Nanoscale Physics · Physics 2020-06-29 Pritam Bhattacharyya , Rupesh Chaudhari , Naresh Alaal , Tushar Rana , Alok Shukla

The central question in the field of 2D materials is how a material behaves when it is patterned at nanometer scale with different edge geometries. Due to the anisotropy inherent in the puckered structure, black phosphorene nanostructures…

Mesoscale and Nanoscale Physics · Physics 2019-12-13 Yi Ren , Pu Liu , Benliang Zhou , Xiaoying Zhou , Guanghui Zhou

Phosphorene, a single atomic layer of black phosphorus, has recently emerged as a new twodimensional (2D) material that holds promise for electronic and photonic technology. Here we experimentally demonstrate that the electronic structure…

Phosphorene, a two-dimensional (2D) analog of black phosphorous, has been a subject of immense interest recently, due to its high carrier mobilities and a tunable bandgap. So far, tunability has been predicted to be obtained with very high…

Materials Science · Physics 2015-06-23 Aaditya Manjanath , Atanu Samanta , Tribhuwan Pandey , Abhishek K. Singh

Most recently, a brand new phosphorus allotrope called green phosphorus has been predicted, which has a direct band gap up to 2.4 eV, and its single-layer form termed green phosphorene shows high stability. Here the mechanical properties…

Materials Science · Physics 2018-06-18 Guang Yang , Tianxing Ma , Xihong Peng

The neutral biexciton cascade of single quantum dots is a promising source of entangled photon pairs. The character of the entangled state is determined by the energy difference between the excitonic eigenstates known as fine-structure…

Mesoscale and Nanoscale Physics · Physics 2015-07-29 M. A. Pooley , A. J. Bennett , R. M. Stevenson , A. J. Shields , I. Farrer , D. A. Ritchie

The monolayer of black phosphorous, or phosphorene, has recently emerged as a new 2D semiconductor with intriguing highly anisotropic transport properties. Existing calculations of its intrinsic phonon-limited electronic transport…

Materials Science · Physics 2015-06-24 Bolin Liao , Jiawei Zhou , Bo Qiu , Mildred S. Dresselhaus , Gang Chen

Quantum dots are fabricated in a Ga[Al]As-heterostructure by local oxidation with an atomic force microscope. This technique, in combination with top gate voltages, allows us to generate steep walls at the confining edges and small lateral…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 A. Fuhrer , S. Luescher , T. Heinzel , K. Ensslin , W. Wegscheider , M. Bichler

Using density functional tight-binding method, we studied the elastic properties, deformation and failure of armchair (AC) and zigzag (ZZ) phosphorene nano tubes (PNTs) under uniaxial tensile strain. We found that the deformation and…

Mesoscale and Nanoscale Physics · Physics 2016-09-21 V. Sorkin , Y. W. Zhang

We theoretically investigate phosphorene zigzag nanorribons as a platform for constriction engineering. In the presence of a constriction at the upper edge, quantum confinement of edge protected states reveals resonant tunnelling…

Mesoscale and Nanoscale Physics · Physics 2016-12-14 C. J. Páez , D. A. Bahamon , Ana L. C. Pereira , P. A. Schulz

Using density-functional theory and a tight-binding approach we investigate the physical origin of distinct favourable geometries of adsorbed hydrogen atoms in various graphyne structures, and the relation with electronic properties. In…

Materials Science · Physics 2014-02-07 Hunpyo Lee , Jahyun Koo , Massimo Capone , Yongkyung Kwon , Hoonkyung Lee

The stability of graphene nanoribbons in the presence of typical atmospheric molecules is systematically investigated by means of density functional theory. We calculate the edge formation free energy of five different edge configurations…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 M. Vanin , J. Gath , K. S. Thygesen , K. W. Jacobsen

Phosphorene, a 2D allotrope of phosphorus, is technologically very appealing because of its semiconducting properties and narrow band gap. Further reduction of the phosphorene dimensionality may spawn exotic properties of its electronic…

The two-dimensional semiconductor phosphorene has attracted extensive research interests for potential applications in optoelectronics, spintronics, catalysis, sensors, and energy conversion. To harness phosphorene's potential requires a…

Materials Science · Physics 2021-07-13 Biswas Rijal , Anne Marie Z. Tan , Christoph Freysoldt , Richard G. Hennig

We give the results of density functional calculations for graphene with a widely varying fluorine adsorptions. We give a systematic analysis of the adsorption energies, lattice constants, bulk modulus, bandgap openings, and magnetic…

Materials Science · Physics 2014-11-13 Chad E. Junkermeier , Stefan C. Badescu , Thomas L. Reinecke

We use density-functional methods to study the effects of an external magnetic field on two-dimensional quantum dots with a rectangular hard-wall confining potential. The increasing magnetic field leads to spin polarization and formation of…

Strongly Correlated Electrons · Physics 2009-11-10 E. Räsänen , A. Harju , M. J. Puska , R. M. Nieminen

Two-dimensional (2D) black phosphorus (i.e., phosphorene) has become a rising star in electronics. Recently, 2D phosphorus oxides with higher stability have been synthesized. In this work, we systematically explore the structures and…

Materials Science · Physics 2016-05-11 Wei Luo , Hongjun Xiang

Density functional theory (DFT) and thermal DFT (thDFT) calculations were used to evaluate the energy band structure, bandgap, and the total energy of various graphene quantum dots (GQDs). The DFT calculations were performed using local…

Materials Science · Physics 2021-12-20 Majid Ghandchi , Ghafar Darvish , Mohammad Kazem Moravvej-Farshi