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Recently a high precision spectroscopic investigation of the EF^1\Sigma_g^+ - X^1\Sigma_g^+ system of molecular hydrogen was reported yielding information on QED and relativistic effects in a sequence of rotational quantum states in the…

Atomic and Molecular Clusters · Physics 2013-01-04 G. D. Dickenson , E. J. Salumbides , M. Niu , Ch. Jungen , S. C. Ross , W. Ubachs

When circularly polarized light is scattered from a rotating target, a rotational Doppler shift (RDS) emerges from an exchange of angular momentum between the spinning object and the electromagnetic field. Here, we used coherently spinning…

When a strong electric field is applied to a colloidal suspension, it may cause an aggregation of the suspended particles in response to the field. In the case of a rotating field, the electrorotation (ER) spectrum can be modified further…

Soft Condensed Matter · Physics 2007-05-23 J. P. Huang , K. W. Yu , G. Q. Gu

Multidimensional optical signals are commonly recorded by varying the delays between time ordered pulses. These control the evolution of the density matrix and are described by ladder diagrams. We propose a new non-time-ordered protocol…

Quantum Physics · Physics 2015-06-18 Konstantin E. Dorfman , Shaul Mukamel

We consider the coherent control of ultracold molecule-molecule scattering, impacted by a dense set of rovibrational resonances. To characterize the resonance spectrum, a rudimentary model based on multichannel quantum defect theory has…

Atomic Physics · Physics 2023-01-18 Adrien Devolder , Timur V. Tscherbul , Paul Brumer

We employ ultrafast pump-probe spectroscopy to directly monitor electron tunneling between discrete orbital states in a pair of spatially separated quantum dots. Immediately after excitation, several peaks are observed in the pump-probe…

Electronic transitions involving core-level orbitals offer a localized, atomic-site and element specific peek window into statistical systems such as molecular liquids. Although formally understood, the complex relation between structure…

Chemical Physics · Physics 2022-09-02 Johannes Niskanen , Anton Vladyka , J. Antti Kettunen , Christoph J. Sahle

The dynamics of a system interacting with an ultrashort pulse is known to depend on the phase content of said pulse. For linear absorption, phase control is possible over time-varying quantities, such as the population of metastable states,…

Chemical Physics · Physics 2019-10-31 Cyrille Lavigne , Paul Brumer

Quantum interference between two distinct vibrational trajectories induced by two pulse femtosecond excitation in molecules is shown to result in a photon echo, providing direct evidence of the cat state superposition of Gaussian…

Quantum Physics · Physics 2007-05-23 Holger F. Hofmann , Takao Fuji , Atsushi Sugita , Takayoshi Kobayashi

The fast dynamics of molecular polaritonics is scrutinized theoretically through the implementation of two-dimensional spectroscopy protocols. We derive conceptually simple and computationally efficient formulas to calculate two-dimensional…

Quantum Physics · Physics 2024-03-08 Daniela Gallego-Valencia , Lars Mewes , Johannes Feist , José Luis Sanz-Vicario

A general method for rotational microwave spectroscopy and control of polar molecular ions via direct microwave addressing is considered. Our method makes use of spatially varying AC Stark shifts, induced by far off-resonant, focused laser…

Atomic Physics · Physics 2015-06-16 M. Shi , P. F. Herskind , M. Drewsen , I. L. Chuang

We formulate the problem of a two-level system in a linearly polarized laser field in terms of a nonlinear Riccati-type differential equation and solve the equation analytically in time intervals much shorter than half the optical period.…

Quantum Physics · Physics 2007-05-23 R. Parzynski , M. Sobczak , A. Plucinska

We evaluate the shifts imparted to vibrational and rotational levels of a linear molecule by a nonresonant laser field at intensities of up to 10^12 W/cm^2. Both types of shift are found to be either positive or negative, depending on the…

Chemical Physics · Physics 2015-03-14 Mikhail Lemeshko , Bretislav Friedrich

We explore the effects of ultrafast shaped pulses for two-level systems that do not have a single photon resonance by developing a multiphoton density-matrix approach. We take advantage of the fact that the dynamics of the intermediate…

Optics · Physics 2009-11-07 S. Abbas Hosseini , Debabrata Goswami

We investigate the resonant quantum dynamics of a multi-qubit ensemble in a microcavity. Both the quantum-dot subsystem and the microcavity mode are pumped coherently. We found that the microcavity photon statistics depends on the phase…

Quantum Physics · Physics 2016-12-21 Viorel Ciornea , Profirie Bardetski , Mihai A. Macovei

Revivals of optical coherence of molecular photoassociation driven by two ultrashort laser pulses are addressed in the Condon approach. Based on textbook examples and numerical simulation of KrF excimer molecules, a prediction is made about…

Atomic Physics · Physics 2015-06-26 Alexander G. Rudavets , Alexander M. Dykhne

Two-dimensional (2D) spectroscopy uses multiple electromagnetic pulses to infer the properties of a complex system. A paradigmatic class of target systems are molecular aggregates, for which one can obtain information on the eigenstates,…

The lack of a direct map between control fields and desired control objectives poses a significant challenge in applying quantum control theory to quantum technologies. Here, we propose an analytical framework to precisely control a limited…

Quantum Physics · Physics 2025-03-05 Qian-Qian Hong , Daoyi Dong , Niels E. Henriksen , Franco Nori , Jun He , Chuan-Cun Shu

We investigate the prospects of creating broad rotational wave packets by means of molecular interaction with long sequences of intense femtosecond pulses. Using state-resolved rotational Raman spectroscopy of oxygen, subject to a sequence…

Quantum Physics · Physics 2016-01-27 M. Bitter , V. Milner

The electromagnetic radiation of a rotating relativistic electron layers is studied numerically using particle-in-cell simulation. The results of the simulation confirm all relevant scaling properties predicted by theoretical models. These…

Astrophysics · Physics 2007-05-23 Bjoern S. Schmekel
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