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Optical spectroscopy of molecular radicals is an important tool in physical chemistry, and is a prerequisite for many experiments which use molecules for quantum science and precision measurement. However, even the simplest molecules have…

Chemical Physics · Physics 2025-05-07 Ashay N. Patel , Madison I. Howard , Timothy C. Steimle , Nicholas R. Hutzler

Spectroscopy is a powerful tool for studying molecules and is commonly performed on large thermal molecular ensembles that are perturbed by motional shifts and interactions with the environment and one another, resulting in convoluted…

The rich internal structure and long-range dipole-dipole interactions establish polar molecules as unique instruments for quantum-controlled applications and fundamental investigations. Their potential fully unfolds at ultracold…

We demonstrate millikelvin thermometry of laser cooled trapped ions with high-resolution imaging. This equilibrium approach is independent of the cooling dynamics and has lower systematic error than Doppler thermometry, with \pm5 mK…

Quantum Physics · Physics 2011-06-10 B. G. Norton , E. W. Streed , M. J. Petrasiunas , A. Jechow , D. Kielpinski

We present a novel method for reducing the inhomogeneous frequency broadening in the hyperfine splitting of the ground state of optically trapped atoms. This reduction is achieved by the addition of a weak light field, spatially…

Atomic Physics · Physics 2009-11-07 Ariel Kaplan , Mikkel Fredslund Andersen , Nir Davidson

We report the magnetic confinement of neutral, ground state hydroxyl radicals (OH) at a density of $\sim3\times10^{3}$ cm$^{-3}$ and temperature of $\sim$30 mK. An adjustable electric field of sufficient magnitude to polarize the OH is…

All light has structure, but only recently it has become possible to construct highly controllable and precise potentials so that most laboratories can harness light for their specific applications. In this chapter, we review the emerging…

Hyperfine-structures of highly charged ions (HCIs) are favourable spectroscopic targets for exploring fundamental physics as well as nuclear properties. Recent proposals of HCI atomic clocks highlight their importance, especially for…

A detailed treatment of an electro-optical trap for polar molecules, realized by embedding an optical trap within a uniform electrostatic field, is presented and the trap's properties analyzed and discussed. The electro-optical trap offers…

Atomic Physics · Physics 2022-06-15 Bretislav Friedrich

We present an all-optical mass spectrometry technique to identify trapped ions. The new method uses laser-cooled ions to determine the mass of a cotrapped dark ion with a sub-dalton resolution within a few seconds. We apply the method to…

Atomic Physics · Physics 2021-01-13 M. Fan , C. A. Holliman , X. Shi , H. Zhang , M. W. Straus , X. Li , S. W. Buechele , A. M. Jayich

We demonstrate a 1D magneto-optical trap of the polar free radical calcium monohydroxide (CaOH). A quasi-closed cycling transition is established to scatter $\sim 10^3$ photons per molecule, predominantly limited by interaction time. This…

In this paper we present a technique for the precise measurement of electric dipole allowed transitions in trapped ions. By applying a probe and a cooling laser in quick succession, the full transition can be probed without causing…

Atomic Physics · Physics 2015-06-19 Amy Gardner , Kevin Sheridan , William Groom , Nicolas Seymour-Smith , Matthias Keller

Ultrabroadband electro-optic sampling with few-cycle optical pulses is known to be an extremely sensitive technique to detect electric field amplitudes. By combining this method with dual-comb spectroscopy and with a new class of ultrafast…

We demonstrate Faraday spectroscopy with high duty cycle and sampling rate using atoms confined to a blue-detuned optical trap. Our trap consists of a crossed pair of high-charge-number hollow laser beams, which forms a dark, box-like…

Quantum Physics · Physics 2009-11-13 Matthew L. Terraciano , Mark Bashkansky , Fredrik Fatemi

The enhancement of a cryogenic radio frequency 22 pole trap instrument by the addition of ring electrodes is presented in detail. The ring electrodes tightly surround the poles and only a fraction of the applied electric potential…

Chemical Physics · Physics 2023-06-08 Pavol Jusko , Miguel Jiménez-Redondo , Paola Caselli

A novel, to the best of our knowledge, ultralow-temperature luminescence thermometry strategy is proposed, based on a measurement of relative intensities of hyperfine components in the spectra of Ho$^{3+}$ ions doped into a crystal. A…

Optics · Physics 2025-11-25 Marina N. Popova , Mosab Diab , Boris Z. Malkin

The accuracy of high precision and fundamental measurements of atomic transition frequencies via laser spectroscopy depends upon fitting the spectral data with a lineshape. With atomic hydrogen and antihydrogen 1S-2S two-photon…

Atomic Physics · Physics 2025-01-24 Levi Oliveira de Araujo Azevedo , Claudio Lenz Cesar

Time-resolved photoelectron spectroscopy (trPES) can directly detect transient electronic structure, thus bringing out its promising potential to clarify nonequilibrium processes arising in condensed matters. Here we report the result of…

Strongly Correlated Electrons · Physics 2015-05-20 K. Ishizaka , T. Kiss , T. Yamamoto , Y. Ishida , T. Saitoh , M. Matsunami , R. Eguchi , T. Ohtsuki , A. Kosuge , T. Kanai , M. Nohara , H. Takagi , S. Watanabe , S. Shin

Hyperspectroscopy is a new method of surface image taking, providing simultaneously high position and spectral resolutions which allow one to make some conclusions about chemical compositions of the surfaces. We are now studying…

Instrumentation and Detectors · Physics 2016-11-18 I. Rodionov , J-M. Bidault , I. Crotty , P. Fonte , F. Galy , V. Peskov , O. Zanette

We investigate the dephasing of ultra cold ^{85}Rb atoms trapped in an optical dipole trap and prepared in a coherent superposition of their two hyperfine ground states by interaction with a microwave pulse. We demonstrate that the…

Quantum Physics · Physics 2009-11-07 M. F. Andersen , A. Kaplan , N. Davidson