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Polar polyatomic molecules provide an ideal but largely unexplored platform to encode qubits in rotational states. Here, we trap cold (100-600 mK) formaldehyde (H$_2$CO) inside an electric box and perform a Ramsey-type experiment to observe…

Atomic Physics · Physics 2025-04-01 Maximilian Löw , Martin Ibrügger , Gerhard Rempe , Martin Zeppenfeld

In the interstellar cold gas, the chemistry of formaldehyde (H$_2$CO) can be essential to explain the formation of complex organic molecules. On this matter, the massive and energetic protostellar object G331 is still unexplored and, hence,…

Astrophysics of Galaxies · Physics 2023-08-09 Edgar Mendoza , Miguel Carvajal , Manuel Merello , Leonardo Bronfman , Heloisa M. Boechat-Roberty

We demonstrate an efficient high-precision optical spectroscopy technique for single trapped ions with non-closed transitions. In a double-shelving technique, the absorption of a single photon is first amplified to several phonons of a…

We propose a novel type of precision laser spectrometer for trapped, highly charged ions nearly at rest. It consists of a cylindrical open-endcap Penning trap in which an externally produced bunch of highly charged ions can be confined and…

Atomic Physics · Physics 2009-11-11 M. Vogel , D. F. A. Winters , D. M. Segal , R. C. Thompson

We perform spectroscopy on the hyperfine splitting of $^{85}$Rb atoms trapped in far-off-resonance optical traps. The existence of a spatially dependent shift in the energy levels is shown to induce an inherent dephasing effect, which…

Atomic Physics · Physics 2016-08-16 A. Kaplan , M. F. Andersen , T. Grünzweig , N. Davidson

Sympathetic cooling of trapped ions has been established as a powerful technique for manipulation of non-laser-coolable ions (Raizen1992,Waki1992,Bowe1999,Barrett2003). For molecular ions, it promises vastly enhanced spectroscopic…

Quantum Physics · Physics 2018-06-06 Soroosh Alighanbari , Michael Georg Hansen , Vladimir Korobov , Stephan Schiller

Formaldehyde (H2CO) is often observed at centimeter wavelengths as an absorption line against the cosmic microwave background (CMB). This is possible when energy level populations are cooled to the point where line excitation temperatures…

Astrophysics of Galaxies · Physics 2019-04-02 Jeremy Darling

Formaldehyde (H$_2$CO) is often observed at centimeter wavelengths as an absorption line against the cosmic microwave background (CMB). This is possible when energy level populations are anti-inverted to the point where line excitation…

Astrophysics of Galaxies · Physics 2018-10-10 Jeremy Darling

We have performed sub-Doppler spectroscopy on the narrow intercombination line of cold calcium atoms using the amplified output of a femtosecond laser frequency comb. Injection locking of a 657-nm diode laser with a femtosecond comb allows…

Atomic Physics · Physics 2010-03-19 T. M. Fortier , Y. Le Coq , J. E. Stalnaker , D. Ortega , S. A. Diddams , C. W. Oates , L. Hollberg

We demonstrate the long-term ($<$ 1 minute) trapping of Stark-decelerated OH radicals in their $X~^{2}\Pi _{3/2}~(\nu = 0,~J = 3/2,~M_{J} = 3/2,~f)$ state in a permanent magnetic trap. The trap environment was cryogenically cooled to a…

Chemical Physics · Physics 2019-08-05 Dominik Haas , Claudio von Planta , Thomas Kierspel , Dongdong Zhang , Stefan Willitsch

Improvements in both theory and frequency metrology of few-electron systems such as hydrogen and helium have enabled increasingly sensitive tests of quantum electrodynamics (QED), as well as ever more accurate determinations of fundamental…

We report on a comb-locked cavity ring-down spectrometer developed for high-precision, SI-traceable, molecular spectroscopy of air-broadened CO2 gas samples. The experimental setup relies on the use of a singly-resonant optical parametric…

We study the feasibility of nearly-degenerate two-photon rovibrational spectroscopy in ensembles of trapped, sympathetically cooled hydrogen molecular ions using a resonance-enhanced multiphoton dissociation (REMPD) scheme. Taking advantage…

Magneto-optical traps are central to atomic and molecular quantum technologies and precision tests of fundamental physics, where both sensitivity and bandwidth scale strongly with atom number and loading rate. We demonstrate that employing…

Femtosecond coherent multidimensional spectroscopy is demonstrated for an ultracold gas. For this, a setup for phase modulation spectroscopy is used to probe the $3^2\mathrm{S}_{1/2} - 2^2\mathrm{P}_{1/2, 3/2}$ transition in an 800…

Atomic Physics · Physics 2023-01-16 Friedemann Landmesser , Tobias Sixt , Katrin Dulitz , Lukas Bruder , Frank Stienkemeier

We demonstrate a laser frequency stabilization technique for laser cooling of Potassium atoms, based on saturated absorption spectroscopy in the C-Band optical telecommunication window, using ro-vibrationel transitions of the acetylene…

Two-dimensional electronic spectroscopy provides information on coupling and energy transfer between excited states on ultrafast timescales. Only recently, incoherent fluorescence detection has made it possible to combine this method with…

Optics · Physics 2025-05-14 Sanchayeeta Jana , Simon Durst , Lucas Ludwig , Markus Lippitz

We demonstrate precision laser spectroscopy of a trapped $^{173}$Yb$^+$ ion that is not directly laser cooled by coupling it to ultracold atoms. The atomic bath continuously cools the internal degrees of freedom of the ion to its hyperfine…

Atomic Physics · Physics 2026-03-24 Egor Kovlakov , Rene Gerritsma

We experimentally demonstrate optical spectroscopy of magnetically trapped atoms on an atom chip. High resolution optical spectra of individual trapped clouds are recorded within a few hundred milliseconds. Detection sensitivities close to…

Quantum Physics · Physics 2008-09-16 A. Günther , H. Bender , A. Stibor , J. Fortágh , C. Zimmermann

Measuring low light absorption with combined uncertainty < 1 permille is crucial in a wide range of applications. Popular cavity ring-down spectroscopy can provide ultra-high precision, below 0.01 permille, but its accuracy is strongly…