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In this tutorial-style review we discuss basic concepts of coupled cluster theory and recent developments that increase its computational efficiency for calculations of molecules, solids and materials in general. We will touch upon the…

Materials Science · Physics 2020-04-15 Igor Ying Zhang , Andreas Grüneis

Electronic structure methods built around double-electron excitations have a rich history in quantum chemistry. However, it seems to be the case that such methods are only suitable in particular situations and are not naturally equipped to…

Chemical Physics · Physics 2024-07-12 Zachary W. Windom , Ajith Perera , Rodney J. Bartlett

We give an alternative proof of several sharp commutator estimates involving Riesz transforms, Riesz potentials, and fractional Laplacians. Our methods only involve harmonic extensions to the upper half-space, integration by parts, and…

Analysis of PDEs · Mathematics 2018-11-29 Enno Lenzmann , Armin Schikorra

The many-body expansion (MBE) is an efficient tool which has a long history of use for calculating interaction energies, binding energies, lattice energies, and so on. In the past, applications of MBE to correlation energy have been…

Strongly Correlated Electrons · Physics 2021-08-11 Vibin Abraham , Nicholas Mayhall

We present an efficient algorithm for one- and two-component relativistic exact-decoupling calculations. Spin-orbit coupling is thus taken into account for the evaluation of relativistically transformed (one-electron) Hamiltonian. As the…

Chemical Physics · Physics 2013-05-10 Daoling Peng , Nils Middendorf , Florian Weigend , Markus Reiher

While coupled cluster theory accurately models weakly correlated quantum systems, it often fails in the presence of strong correlations where the standard mean-field picture is qualitatively incorrect. In many cases, these failures can be…

Nuclear Theory · Physics 2020-05-14 Y. Qiu , T. M. Henderson , T. Duguet , G. E. Scuseria

We obtain descriptions of central operator-valued Schur and Herz-Schur multipliers, akin to a classical characterisation due to Grothendieck, that reveals a close link between central (linear) multipliers and bilinear multipliers into the…

Functional Analysis · Mathematics 2021-01-05 Andrew McKee , Reyhaneh Pourshahami , Ivan G. Todorov , Lyudmila Turowska

We present the working equations for a reduced-scaling method of evaluating the perturbative triples (T) energy in coupled-cluster theory, through the tensor hypercontraction (THC) of the triples amplitudes ($t_{ijk}^{abc}$). Through our…

Chemical Physics · Physics 2024-06-12 Andy Jiang , Justin M. Turney , Henry F. Schaefer

Cluster variables have recently revolutionized numerical work in certain models involving fermionic variables. This novel representation of fermionic partition functions is continuing to find new applications. After describing results from…

High Energy Physics - Lattice · Physics 2007-05-23 Shailesh Chandrasekharan

We present an implementation of a perturbative triples correction for the coupled cluster ansatz including single and double excitations based on the transcorrelated Hamiltonian. Transcorrelation introduces explicit electron correlation in…

Chemical Physics · Physics 2025-02-19 Maximilian Mörchen , Alberto Baiardi , Michał Lesiuk , Markus Reiher

Cluster perturbation theory is a technique for calculating the spectral weight of Hubbard models of strongly correlated electrons, which combines exact diagonalizations on small clusters with strong-coupling perturbation theory at leading…

Strongly Correlated Electrons · Physics 2009-11-07 D. Sénéchal , D. Pérez , D. Plouffe

We compare the different convergence criteria available for cluster expansions of polymer gases subjected to hard-core exclusions, with emphasis on polymers defined as finite subsets of a countable set (e.g. contour expansions and more…

Mathematical Physics · Physics 2015-05-18 Rodrigo Bissacot , Roberto Fernández , Aldo Procacci

We investigate a novel approach to approximate tensor-network contraction via the exact, matrix-free decomposition of full tensor-networks. We study this method as a means to eliminate the propagation of error in the approximation of…

Chemical Physics · Physics 2025-06-23 Karl Pierce

The aim of this work is to develop the relevant formalism for performing coupled-cluster (CC) calculations in nuclear matter and neutron star matter, including thereby important correlations to infinite order in the interaction and testing…

Nuclear Theory · Physics 2013-11-18 G. Baardsen , A. Ekström , G. Hagen , M. Hjorth-Jensen

Recently it has been introduced an algorithm Baker-Campbell-Hausdorff (BCH) formula, which extends the Van-Brunt and Visser recent results, leading to new closed forms of BCH formula. More recently, it has been shown that there are {\it 13…

Mathematical Physics · Physics 2016-11-11 Marco Matone

Let $T$ be a bilinear Calder\'{o}n-Zygmund singular integral operator and $T_*$ be its corresponding truncated maximal operator. The commutators in the $i$-$th$ entry and the iterated commutators of $T_*$ are defined by $$…

Classical Analysis and ODEs · Mathematics 2013-12-16 Yong Ding , Ting Mei , Qingying Xue

The mathematical foundation of the so-called extended coupled-cluster method for the solution of the many-fermion Schr\"odinger equation is here developed. We prove an existence and uniqueness result, both in the full infinite-dimensional…

Numerical Analysis · Mathematics 2017-02-15 Andre Laestadius , Simen Kvaal

By a novel exact diagonalization technique we show that bound pairs propagate between repulsive Hubbard clusters in a superconducting fashion. The size of the matrices that must be handled depends on the number of fermion configurations…

Superconductivity · Physics 2009-11-07 Michele Cini , Gianluca Stefanucci , Enrico Perfetto , Agnese Callegari

A novel implementation of the coupled-cluster singles and doubles (CCSD) approach is presented that is specifically tailored for the treatment of large, symmetric systems. It fully exploits Abelian point-group symmetry and the use of the…

Chemical Physics · Physics 2023-12-07 Tommaso Nottoli , Jürgen Gauss , Filippo Lipparini

We prove weak and strong convergence theorems for a double Krasnoselskij type iterative method to approximate coupled solutions of a bivariate nonexpansive operator F : C x C --> C, where C is a nonempty closed and convex subset of a…

Functional Analysis · Mathematics 2014-02-21 V. Berinde , A. R. Khan , M. Pacurar
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