English
Related papers

Related papers: Full Coupled-Cluster Reduction for Accurate Descri…

200 papers

The distinguishable cluster approximation applied to coupled cluster doubles equations greatly improves absolute and relative energies. We apply the same approximation to the triples equations and demonstrate that it can also improve…

Chemical Physics · Physics 2019-05-01 Daniel Kats , Andreas Köhn

Strongly correlated electron systems require the development of new theoretical schemes in order to describe their unusual and unexpected properties. The usual perturbation schemes are inadequate and new concepts must be introduced. In our…

Strongly Correlated Electrons · Physics 2016-08-31 F. Mancini , A. Avella

Size extensivity, defined as the correct scaling of energy with system size, is a desirable property for any many-body method. Traditional CI methods are not size extensive hence the error increases as the system gets larger. Coupled…

Chemical Physics · Physics 2022-07-27 Vibin Abraham , Nicholas J. Mayhall

Projected Hartree-Fock theory provides an accurate description of many kinds of strong correlation but does not properly describe weakly correlated systems. Coupled cluster theory, in contrast, does the opposite. It therefore seems natural…

Strongly Correlated Electrons · Physics 2017-08-22 Ethan Qiu , Thomas M. Henderson , Gustavo E. Scuseria

We analyze the heavy quark bound state spectrum using an order-dependent conformal mapping to re-sum the perturbative expansion for current correlators. The procedure consists of two main steps. Firstly, the Borel plane structure of the…

High Energy Physics - Phenomenology · Physics 2009-10-31 H. F. Jones , A. Ritz , I. L. Solovtsov

A method is proposed to improve the accuracy of approximate techniques for strongly correlated electrons that use reduced Hilbert spaces. As a first step, the method involves a change of basis that incorporates exactly part of the short…

Statistical Mechanics · Physics 2009-10-30 E. Dagotto , G. B. Martins , J. Riera , A. L. Malvezzi , C. Gazza

In quantum chemistry, one of the most important challenges is the static correlation problem when solving the electronic Schr\"odinger equation for molecules in the Born--Oppenheimer approximation. In this article, we analyze the tailored…

Numerical Analysis · Mathematics 2019-11-21 Fabian M. Faulstich , Andre Laestadius , Örs Legeza , Reinhold Schneider , Simen Kvaal

We propose a streamlined combination scheme of the transcorrelation (TC) and coupled cluster (CC) theory, which not only increases the convergence rate with respect to the basis set, but also extends the applicability of the lowest order CC…

Strongly Correlated Electrons · Physics 2021-07-28 Ke Liao , Thomas Schraivogel , Hongjun Luo , Daniel Kats , Ali Alavi

The fermionic many-body problem in the strong correlation regime is notoriously difficult to tackle. In a previous work (Phys. Rev. B 101, 045109 (2020)), we have proposed to extend the single-reference coupled-cluster (SRCC) method to the…

Strongly Correlated Electrons · Physics 2024-11-13 Dominic Bergeron

Most dimensionality reduction methods employ frequency domain representations obtained from matrix diagonalization and may not be efficient for large datasets with relatively high intrinsic dimensions. To address this challenge, Correlated…

Machine Learning · Statistics 2022-06-10 Yuta Hozumi , Rui Wang , Guo-Wei Wei

One method of representing a high-rank tensor as a (hyper-)product of lower-rank tensors is the tensor hypercontraction (THC) method of Hohenstein et al. This strategy has been found to be useful for reducing the polynomial scaling of…

Chemical Physics · Physics 2025-03-26 Avdhoot Datar , Devin A. Matthews

A comprehensive and detailed account is presented for the finite-temperature many-body perturbation theory for electrons that expands in power series all thermodynamic functions on an equal footing. Algebraic recursions in the style of the…

Statistical Mechanics · Physics 2021-09-21 So Hirata

We study the pairing within the Peierls-Hubbard Model for electron- and hole-doped analogs of C$_{60}$ accessible to exact diagonalization techniques (cube, truncated tetrahedron, {\it etc.}). We discuss how inclusion of electron-phonon…

Condensed Matter · Physics 2007-05-23 J. Tinka Gammel F. Guo , D. Guo , K. C. Ung , S. Mazumdar

We determine the product structure on Hochschild cohomology of commutative algebras in low degrees, obtaining the answer in all degrees for complete intersection algebras. As applications, we consider cyclic extension algebras as well as…

Commutative Algebra · Mathematics 2014-01-13 Ragnar-Olaf Buchweitz , Collin Roberts

We develop a general technique for finding self-adjoint extensions of a symmetric operator that respect a given set of its symmetries. Problems of this type naturally arise when considering two- and three-dimensional Schr\"odinger operators…

Mathematical Physics · Physics 2015-12-24 A. G. Smirnov

Coupled-cluster (CC) theory is often considered the gold standard of quantum chemistry, but its high computational cost limits routine access to accurate energies, forces and response properties. While the right-hand $T$-amplitudes…

While restricted single-reference coupled cluster theory truncated to singles and doubles (CCSD) provides very accurate results for weakly correlated systems, it usually fails in the presence of static or strong correlation. This failure is…

Chemical Physics · Physics 2016-02-25 Ireneusz W. Bulik , Thomas M. Henderson , Gustavo E. Scuseria

We review briefly the fundamental equations of a semi-microscopic core-particle coupling method that makes no reference to an intrinsic system of coordinates. We then demonstrate how an intrinsic system can be introduced in the strong…

Nuclear Theory · Physics 2008-11-26 Pavlos Protopapas , Abraham Klein

The present calculations in perturbative QCD reach the order $\alpha_s^4$ for several correlators calculated to five loops, and the huge computational difficulties make unlikely the full six-loop calculation in the near future. This…

High Energy Physics - Phenomenology · Physics 2019-10-02 Irinel Caprini

We consider $\mathcal{N}=2$ superconformal quiver gauge theories in four dimensions and evaluate the chiral/anti-chiral correlators of single-trace operators. We show that it is convenient to form particular twisted and untwisted…

High Energy Physics - Theory · Physics 2021-11-10 M. Billo , M. Frau , F. Galvagno , A. Lerda , A. Pini