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A detailed high pressure investigation is carried out using x-ray diffraction, Raman spectroscopy and low temperature resistivity measurements on hexagonal ZrSe$_{2}$ having an excess of 3 at.\% Zr. Structural studies show that the sample…

Strongly Correlated Electrons · Physics 2022-09-21 Bishnupada Ghosh , Mrinmay Sahu , Debabrata Samanta , Pinku Saha , Anshuman Mandal , Goutam Dev Mukherjee

The hydrostatic pressure is expected to be an effective knob to tune the magnetostructural phase transitions of hexagonal MMX alloy. In this study, magnetization measurements under hydrostatic pressure were performed on a MMX martensitic…

Materials Science · Physics 2021-06-08 Qingqi Zeng , Jianlei Shen , Enke Liu , Xuekui Xi , Wenhong Wang , Guangheng Wu , Xixiang Zhang

Results of X-ray diffraction experiments on solid oxygen at low temperature and at pressures up to 10 GPa are presented.A careful sample preparation and annealing around 240 K allowed to obtain very good diffraction patterns in the…

Materials Science · Physics 2009-11-07 Federico A. Gorelli , Mario Santoro , Lorenzo Ulivi , Michael Hanfland

The stability of MgH$_2$ has been studied up to 20~GPa using density-functional total-energy calculations. At ambient pressure $\alpha$-MgH${_2}$ takes a TiO$_2$-rutile-type structure. $\alpha$-MgH$_2$ is predicted to transform into…

Materials Science · Physics 2009-11-07 P. Vajeeston , P. Ravindran , A. Kjekshus , H. Fjellvåg

We study the effect of temperature up to 1000K on the structure of dense molecular para-hydrogen and ortho-deuterium, using the path-integral Monte Carlo method. We find a structural phase transition from orientationally disordered…

Materials Science · Physics 2009-11-07 T. Cui , Y. Takada , Q. Cui , Y. Ma , G. Zou

We have studied the high-pressure iron bcc to hcp phase transition by simultaneous X-ray Magnetic Circular Dichroism (XMCD) and X-ray Absorption Spectroscopy (XAS) with an X-ray dispersive spectrometer. The combination of the two techniques…

Other Condensed Matter · Physics 2009-11-10 O. Mathon , F. Baudelet , J. P. Itie , A. Polian , M. D'Astuto , J. C. Chervin , S. Pascarelli

We report on the crystal structure and electronic properties of the heavy fermion superconductor UTe2 at high pressure up to 11 GPa, as investigated by X-ray diffraction and electrical resistivity experiments. The X-ray diffraction…

X-ray diffraction (XRD) experiments have been carried out on quartz-like GaPO4 at high pressure and room temperature. A transition to a high pressure disordered crystalline form occurs at 13.5 GPa. Slight heating using a YAG infrared laser…

Condensed Matter · Physics 2009-10-31 James Badro , Jean-Paul Itie , Alain Polian

We report a joint experimental and theoretical study of the structural, vibrational, and electronic properties of layered monoclinic arsenic sulfide (alpha-As2S3), aka mineral orpiment, under compression. X-ray diffraction and Raman…

A pressure-induced phase transition, associated with an increase of the coordination number of In and Ta, is detected beyond 13 GPa in InTaO4 by combining synchrotron x-ray diffraction and Raman measurements in a diamond anvil cell with…

The crystal structure of CH3NH3PbBr3 perovskite has been investigated under high-pressure by synchrotron-based powder X-ray diffraction. We found that after the previously reported phase transitions in CH3NH3PbBr3 (Pm-3m->Im-3->Pmn21),…

We report experimental evidence for pressure instabilities in the model multiferroic BiFeO3 and namely reveal two structural phase transitions around 3 GPa and 10 GPa by using diffraction and far-infrared spectroscopy at a synchrotron…

Materials Science · Physics 2011-07-26 R. Haumont , P. Bouvier , A. Pashkin , K. Rabia , S. Frank , B. Dkhil , W. A. Crichton , C. A. Kuntscher , J. Kreisel

We report the discovery of a first-order phase transition at around 125 K in NbCrP, which is a nonsymmorphic crystal with Pnma space group. From the resistivity, magnetic susceptibility, and nuclear magnetic resonance measurements using the…

Unprecedented bright and intense synchrotron X-rays have been widely used to unravel numerous compelling electronic and structural properties using a large variety of physical techniques, while the puzzling phenomenon is the uncertainties…

Materials Science · Physics 2017-05-09 Xinguo Hong , Matt Newville , Ho-Kwang Mao , T. Irifune , L. Huang

We have performed a combined experimental and theoretical study of ethane and methane at high pressures up to 120 GPa at 300 K using x-ray diffraction and Raman spectroscopy and the USPEX ab-initio evolutionary structural search algorithm,…

We present a systematic pressure study of poly- and single crystalline SrFe2As2 by electrical resistivity and X-ray diffraction measurements. SrFe2As2 exhibits a structural phase transition from a tetragonal to an orthorhombic phase at…

The ambient- and high-pressure behavior of the ferrimagnet Ni4Nb2O9 (orthorhombically distorted honeycomb structure), is investigated using NMR, Raman spectroscopy, and synchrotron XRD. Ambient-pressure NMR measurements reveal, despite its…

Materials Science · Physics 2026-03-03 Rajesh Jana , Xinyu Wang , Takeshi Nakagawa , Hirofumi Ishii , Alka Garg , Rekha Rao , Thomas Meier

Using X-ray diffraction, DSC and magnetization measurements, a magnoestructural map of the (Mn,Fe)3(Si,P) system was assembled and reported in the current paper. Besides the already known cubic phase for Mn3-xFexSi system and the tetragonal…

Materials Science · Physics 2014-10-01 J. V. Leitão , You Xinmin , L. Caron , E. Brück

From new neutron powder diffraction experiments on the chiral cubic ($P2{_1}3$) magnet manganese germanide MnGe, we analyse all of the possible crystal symmetry-allowed magnetic superstructures that are determined successfully from the…

Strongly Correlated Electrons · Physics 2023-01-18 V. Pomjakushin , I. Plokhikh , J. S. White , Y. Fujishiro , N. Kanazawa , Y. Tokura , E. Pomjakushina

In this paper we report a new high-pressure rhombohedral phase of Ce2Zr2O8 observed from high-pressure angle-dispersive x-ray diffraction and Raman spectroscopy studies up to nearly 12 GPa. The ambient-pressure cubic phase of Ce2Zr2O8…

Materials Science · Physics 2012-03-12 D. Errandonea , R. S. Kumar , S. N. Achary , O. Gomis , F. J. Manjon , R. Shukla , A. K. Tyagi