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High pressure x-ray diffraction up to 30 GPa and resonant emission x-ray spectroscopy and partial fluorescence yield x-ray absorption spectroscopy up to 52 GPa were used to study how the structural and electronic properties of UTe$_2$…

The structural and vibrational properties of phenanthrene are measured at high pressures up to 30.2 GPa by Raman spectroscopy and synchrotron x-ray diffraction techniques. Two phase transitions are observed in raman spectra under pressures…

MnMX (M = Co or Ni, X = Si or Ge) alloys, experiencing structural transformation between Ni2In-type hexagonal and TiNiSi-type orthorhombic phases, attract considerable attention due to their potential applications as room-temperature solid…

Materials Science · Physics 2021-08-03 Tingting Zhang , Yuanyuan Gong , Bin Wang , Dongyu Cen , Feng Xu

Carbon monoxide and nitrogen are among the potentially interesting high-energy density materials. However, in spite of the physical similarities of the molecules, they behave very differently at high pressures. Using density functional…

Materials Science · Physics 2013-12-06 Zamaan Raza , Chris J. Pickard , Carlos Pinilla , A. Marco Saitta

In order to probe the changes in the valence state and magnetic properties of Eu metal under extreme pressure, x-ray absorption near-edge spectroscopy, x-ray magnetic circular dichroism and synchrotron M\"ossbauer spectroscopy experiments…

Bulk single crystals of manganese phosphide (MnP) were grown from melt at 1 GPa and 1200 C by using a cubic-anvil, high-pressure, and high-temperature technique. The obtained black colored crystals exhibit a plate-like morphology, with flat…

Superconductivity · Physics 2017-11-06 Nikolai D. Zhigadlo , Nicolo Barbero , Toni Shiroka

Conclusive crystal structure determination of the high pressure phases of hydrogen remains elusive due to lack of core electrons and vanishing wave vectors, rendering standard high-pressure experimental methods moot. Ab-initio DFT…

Materials Science · Physics 2024-07-30 Meng Yang , Yishan Zhou , Rajesh Jana , Takeshi Nakagawa , Yunhua Fu , Thomas Meier

Nitrogen represents an archetypal example of material exhibiting a pressure driven transformation from molecular to polymeric state. Detailed investigations of such transformations are challenging because of a large kinetic barrier between…

This study explores the pressure evolution of the double perovskite Ba$_2$NiTeO$_6$ by employing experimental and computational techniques. For the study of structural and vibrational properties, synchrotron X-ray diffraction (XRD) and…

Pressure-induced phase transitions of multiferroic BiFeO3 have been investigated using synchrotron radiation X-ray diffraction with diamond anvil cell technique at room temperature. Present experimental data clearly show that rhombohedral…

Materials Science · Physics 2013-08-30 Zhang XiaoLi , Wu Ye , Zhang Qian , Dong JunCai , Wu Xiang , Liu Jing , Wu ZiYu , Chen DongLiang

RuP single crystals of MnP-type orthorhombic structure were synthesized by the Sn flux method. Temperature-dependent x-ray diffraction measurements reveal that the compound experiences two structural phase transitions, which are further…

Strongly Correlated Electrons · Physics 2015-03-06 R. Y. Chen , Y. G. Shi , P. Zheng , L. Wang , T. Dong , N. L. Wang

We report a study of the structural phase transitions induced by pressure in bulk black phosphorus by using both synchrotron x-ray diffraction for pressures up to 12.2 GPa and Raman spectroscopy up to 18.2 GPa. Very recently black…

Materials Science · Physics 2018-11-21 B. Joseph , S. Caramazza , F. Capitani , T. Clarté , F. Ripanti , P. Lotti , A. Lausi , D. Di Castro , P. Postorino , P. Dore

MnP is a metal that shows successive magnetic transitions from paramagnetic to ferromagnetic and helical magnetic phases at ambient pressure with decreasing temperature. With applied pressure, the magnetic transition temperatures decrease…

High-pressure synchrotron based angle dispersive x-ray diffraction (ADXRD) studies were carried out on SmGdO3 (SGO) up to 25.7GPa at room temperature. ADXRD results indicated a reversible pressure-induced phase transition from ambient…

Materials Science · Physics 2015-06-22 Yogesh Sharma , Pankaj Misra , Satyaprakash Sahoo , A. K. Mishra , S. M. Sharma , Ram S. Katiyar

The phase diagram and stability limits of diatomic solid nitrogen have been explored in a wide pressure--temperature range by several optical spectroscopic techniques. A newly characterized narrow-gap semiconducting phase $\eta$ has been…

Materials Science · Physics 2009-11-07 Eugene Gregoryanz , Alexander F. Goncharov , Russell J. Hemley , Ho-kwang Mao

Understanding high-pressure transitions in prototypical linear diatomic molecules, such as hydrogen, nitrogen, and oxygen, is an important objective in high-pressure physics. Recent ultrahigh-pressure study on hydrogen revealed that there…

Materials Science · Physics 2019-10-31 Shan Liu , Meifang Pu , Qiqi Tang , Feng Zhang , Binbin Wu , Li Lei

Nanostructured orthorhombic FeSb2 and an amorphous phase were formed by mechanical alloying starting from a mixture of high purity elemental Fe and Sb powders. The effects of high pressures on structural and optical properties were studied…

Manganese monophosphide (MnP) shows complicated magnetic states varying with both temperature and pressure. We calculate the magnetic and electronic structures of MnP at different pressures using first-principles methods and obtain spiral…

Superconductivity · Physics 2017-05-23 Yuanji Xu , Min Liu , Ping Zheng , Xiangrong Chen , Jin-guang Cheng , Jianlin Luo , Wenhui Xie , Yi-feng Yang

Quasi-hydrostatic compression of rhombohedral boron monosulfide (r-BS) has been studied up to 50 GPa at room temperature using diamond-anvil cells and angle-dispersive synchrotron X-ray diffraction. A fit of the experimental P-V data to the…

Two novel room-temperature phase transitions are observed, via synchrotron x-ray diffraction and Raman spectroscopy, in the Pb(Zr0.52Ti0.48)O3 alloy under hydrostatic pressures up to 16 GPa. A monoclinic (M)-to-rhombohedral (R1) phase…

Condensed Matter · Physics 2009-11-10 A. Sani , B. Noheda , I. A. Kornev , L. Bellaiche , P. Bouvier , J. Kreisel