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We introduce a new form of density functional theory for the {\em ab initio} description of electronic systems in contact with a molecular liquid environment. This theory rigorously joins an electron density-functional for the electrons of…

Soft Condensed Matter · Physics 2009-11-11 Sahak Petrosyan , Jean-Francois Briere , David Roundy , T. A. Arias

Strong light-matter coupling within an optical cavity leverages the collective interactions of molecules and confined electromagnetic fields, giving rise to the possibilities of modifying chemical reactivity and molecular properties. While…

Chemical Physics · Physics 2025-05-29 Shravan Kumar Sharma , Hsing-Ta Chen

We describe vacuum fluctuations and photon-field correlations in interacting quantum mechanical light-matter systems, by generalizing the application of mixed quantum-classical dynamics techniques. We employ the multi-trajectory…

Quantum Physics · Physics 2019-06-26 Norah M. Hoffmann , Christian Schäfer , Angel Rubio , Aaron Kelly , Heiko Appel

In the field of polaritonic chemistry, strong light-matter interactions are used to alter a chemical reaction inside an optical cavity. To explain and understand these processes, the development of reliable theoretical models is essential.…

Chemical Physics · Physics 2021-06-21 Fabijan Pavošević , Johannes Flick

The generation of nonclassical light states bears a paramount importance in quantum optics and is largely relying on the interaction between intense laser pulses and nonlinear media. Recently, electron beams, such as those used in ultrafast…

Optics · Physics 2025-09-23 Valerio Di Giulio , F. Javier García de Abajo

Coherent light-matter interactions between a quantum gas and light in a high-finesse cavity can drive self-ordering phase transitions. To date, such phenomena have involved exclusively single-atom coupling to light, resulting in coupled…

By applying the Born-Huang expansion, originally developed for coupled nucleus-electron systems, to the full nucleus-electron-photon Hamiltonian of non-relativistic quantum electrodynamics (QED) in the long-wavelength approximation, we…

Quantum Physics · Physics 2018-10-10 Christian Schäfer , Michael Ruggenthaler , Angel Rubio

Embedding materials in optical cavities has emerged as an intriguing perspective for controlling quantum materials, but a key challenge lies in measuring properties of the embedded matter. Here, we propose a framework for probing strongly…

Strongly Correlated Electrons · Physics 2025-12-22 Lukas Grunwald , Emil Viñas Boström , Mark Kamper Svendsen , Dante M. Kennes , Angel Rubio

Full control over the dynamics of interacting, indistinguishable quantum particles is an important prerequisite for the experimental study of strongly correlated quantum matter and the implementation of high-fidelity quantum information…

Polaritonic chemistry has ushered in new avenues for controlling molecular dynamics. However, two key questions remain: (i) Can classical light sources elicit the same effects as certain quantum light sources on molecular systems? (ii) Can…

Quantum Physics · Physics 2023-12-13 Leonardo F. Calderón , Humberto Triviño , Leonardo A. Pachón

Cavity-polaritons in semiconductor microstructures have emerged as a promising system for exploring nonequilibrium dynamics of many-body systems. Key advances in this field, including the observation of polariton condensation,…

Mesoscale and Nanoscale Physics · Physics 2019-04-05 Aymeric Delteil , Thomas Fink , Anne Schade , Sven Höfling , Christian Schneider , Ataç Imamoğlu

We investigate optical nonlinear interactions in a dynamic environment by studying generation of photons in spontaneous parametric down conversion inside a nonlinear cavity where the optical path length is periodically modulated in time. We…

Optics · Physics 2019-10-16 Usman A. Javid , Qiang Lin

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

We use a non-Markovian master equation to describe the transport of Coulomb interacting electrons through an electromagnetic cavity with one quantized photon mode. The central system is a finite parabolic quantum wire that is coupled weakly…

Mesoscale and Nanoscale Physics · Physics 2012-03-15 Vidar Gudmundsson , Olafur Jonasson , Chi-Shung Tang , Hsi-Sheng Goan , Andrei Manolescu

The interaction of a molecule with the quantized electromagnetic field of a nano-cavity gives rise to light-induced conical intersections between polaritonic potential energy surfaces. We demonstrate for a realistic model of a polyatomic…

Chemical Physics · Physics 2022-06-13 Csaba Fábri , Gábor J. Halász , Ágnes Vibók

The key features of density-functional theory (DFT) within a minimalistic implementation of quantum electrodynamics are demonstrated, thus allowing to study elementary properties of quantum-electrodynamical density-functional theory…

We introduce a model description of a diatomic molecule in an optical cavity, with pump and fluorescent fields, and electron and nuclear motion are treated on equal footing and exactly. The model accounts for several optical response…

Quantum Physics · Physics 2024-05-30 Megha Gopalakrishna , Emil Viñas Boström , Claudio Verdozzi

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Strong coupling between molecular excitations and quantized electromagnetic fields in optical cavities provides a powerful means to control the physical and chemical properties of molecular systems. Here, we study electron transfer (ET)…

Chemical Physics · Physics 2026-03-02 Takumi Hidaka , Tomohiro Fukushima , Nguyen Thanh Phuc

The interaction of organic molecules and molecular aggregates with electromagnetic fields that are strongly confined inside optical cavities within nanoscale volumes, has allowed the observation of exotic quantum regimes of light-matter…

Quantum Physics · Physics 2018-01-30 Felipe Herrera , Frank C. Spano
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