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The exact factorization of the time-dependent electron-nuclear wavefunction has been employed successfully in the field of quantum molecular dynamics simulations for interpreting and simulating light-induced ultrafast processes. In this…

Chemical Physics · Physics 2021-09-29 Federica Agostini , E. K. U. Gross

We present a novel theory and implementation for computing coupled electronic and quantal nuclear subsystems on a single potential energy surface, moving beyond the standard Born-Oppenheimer (BO) separation of nuclei and electrons. We…

Chemical Physics · Physics 2021-11-15 Ziyong Chen , Jun Yang

Cavity electrodynamics offers a unique avenue for tailoring ground-state material properties, excited-state engineering, and versatile control of quantum matter. Merging these concepts with high-field physics in the terahertz (THz) spectral…

We provide a theoretical framework to describe the dynamics of a free-electron beam interacting with quantized bound systems in arbitrary electromagnetic environments. This expands the quantum optics toolbox to incorporate free-electron…

Molecular complexes are held together via a variety of bonds, but they all share the common feature that their individual entities are in contact. In this work, we introduce and demonstrate the concept of a \textit{molecular optical bond},…

Mesoscale and Nanoscale Physics · Physics 2025-01-03 Jahangir Nobakht , André Pscherer , Jan Renger , Stephan Götzinger , Vahid Sandoghdar

A single cavity photon mode is expected to modify the Coulomb interaction of an electron system in the cavity. Here we investigate this phenomena in a parallel double quantum dot system. We explore properties of the closed system and the…

Mesoscale and Nanoscale Physics · Physics 2016-05-17 Vidar Gudmundsson , Anna Sitek , Nzar Rauf Abdullah , Chi-Shung Tang , Andrei Manolescu

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

By analyzing the many-body problem for non-relativistic electrons strongly coupled to photon modes of a microcavity I derive the exact momentum/force balance equation for cavity quantum electrodynamics. Implications of this equation for the…

Mesoscale and Nanoscale Physics · Physics 2018-12-14 I. V. Tokatly

Recent experiments have demonstrated an open system realization of the Dicke quantum phase transition in the motional degrees of freedom of an optically driven Bose-Einstein condensate in a cavity. Relevant collective excitations of this…

Quantum Physics · Physics 2016-08-14 B. Öztop , M. Bordyuh , Ö. E. Müstecaplıoğlu , H. E. Türeci

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

A model is developed, based on the density functional perturbation theory and the inverse Kohn-Sham method, that can be used to improve relativistic nuclear energy density functionals towards an exact but unknown Kohn-Sham…

Nuclear Theory · Physics 2021-04-28 Giacomo Accorto , Tomoya Naito , Haozhao Liang , Tamara Niksic , Dario Vretenar

The prospect of controlling chemical reactivity using frequency-tunable optical microcavities has materialized over the past decade, evolving into a fascinating yet challenging new field of polaritonic chemistry, a multidisciplinary domain…

Chemical Physics · Physics 2025-10-07 Yaling Ke , Jakob Assan

This article presents a systematic theoretical enquiry concerning the conceptual foundations and the nature of phonon-mediated electron-electron interactions. Starting from the fundamental many-body Hamiltonian, we propose a simple scheme…

Materials Science · Physics 2020-09-08 R. Starke , G. A. H. Schober

The Quantum-Electrodynamical Time-Dependent Density Functional Theory (QED-TDDFT) equations are solved by time propagating the wave function on a tensor product of a Fock-space and real-space grid. Applications for molecules in cavities…

Quantum Physics · Physics 2022-11-30 Justin Malave , Alexander Ahrens , Daniel Pitagora , Cody Covington , Kálmán Varga

Electron microscopy based on high-energy electrons allows nanoscopic analytical imaging taking advantage of secondarily generated particles. Especially for cathodoluminescence, the correlation between primary incident electrons and emitted…

Instrumentation and Detectors · Physics 2025-01-28 Sotatsu Yanagimoto , Naoki Yamamoto , Tatsuro Yuge , Hikaru Saito , Keiichirou Akiba , Takumi Sannomiya

The ability to achieve ultra-strong coupling between light and matter promises to bring about new means to control material properties, new concepts for manipulating light at the atomic scale, and fundamentally new insights into quantum…

Quantum Physics · Physics 2019-05-22 Nicholas Rivera , Johannes Flick , Prineha Narang

Photonic temporal crystals host a variety of intriguing phenomena, from wave amplification and mixing to exotic band structures, all stemming from the time-periodic modulation of optical properties. While these features have been well…

Optics · Physics 2026-01-06 Junhyeon Bae , Kyungmin Lee , Bumki Min , Kun Woo Kim

A reduced-density-matrix (RDM)-based approach to {\em ab initio} cavity quantum electrodynamics (QED) is developed. The expectation value of the Pauli-Fierz Hamiltonian is expressed in terms of one- and two-body electronic and photonic…

Chemical Physics · Physics 2022-11-23 Joel D. Mallory , A. Eugene DePrince

Cavity quantum electrodynamics (cavity QED) enables the control of light-matter interactions at the single-photon level, rendering it a key component of many quantum technologies. Its practical realization, however, is complex since it…

Quantum Physics · Physics 2024-09-25 David Castells-Graells , J. Ignacio Cirac , Dominik S. Wild

Recently, condensed matter and atomic experiments have reached a length-scale and temperature regime where new quantum collective phenomena emerge. Finding such physics in systems of photons, however, is problematic, as photons typically do…

Other Condensed Matter · Physics 2007-08-01 Andrew D. Greentree , Charles Tahan , Jared H. Cole , L. C. L. Hollenberg