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Recently, $\mathrm{BaSn_2}$ is predicted to be a strong topological insulator by the first-principle calculations. It is well known that topological insulator has a close connection to thermoelectric material, such as $\mathrm{Bi_2Te_3}$…

Materials Science · Physics 2016-12-21 San-Dong Guo , Liang Qiu

The compression of SH$_2$ and its subsequent decomposition to SH$_3$, presumably in a cubic Im$\overline{3}$m structure, has lead to the discovery of conventional superconductivity with the highest measured and confirmed $T_c$ to date, 203…

Materials Science · Physics 2019-02-20 Maximilian Amsler

Identification of novel materials with enhanced thermoelectric (TE) performance is critical for advancing TE research. In this direction, this is the first report on TE properties of low-cost, nontoxic, and abundant core-shell Cu@Cu2O…

Mesoscale and Nanoscale Physics · Physics 2020-12-02 Vikash Sharma , Gunadhor Singh Okram , Divya Verma , Niranjan Prasad Lalla , Yung-Kang Kuo

The electronic and transport properties of CuInTe2 chalcopyrite are investigated using density functional calculations combined with Boltzmann theory. The band gap predicted from hybrid functional is 0.92 eV, which agrees well with…

Materials Science · Physics 2016-01-06 J. Wei , H. J. Liu , L. Cheng , J. Zhang , J. H. Liang , P. H. Jiang , D. D. Fan , J. Shi

Half Heusler (HH) alloys with 18 valence electron count have attracted significant interest in the area of research related to thermoelectrics. Understanding the novel transport properties exhibited by these systems with semiconducting…

Materials Science · Physics 2022-02-15 Kavita Yadav , Saurabh Singh , Tsunehiro Takeuchi , K. Mukherjee

Members of the CaK(Fe$_{1-x}$Cr$_{x}$)$_{4}$As$_{4}$ series have been synthesized by high-temperature solution growth in single crystalline form and characterized by X-ray diffraction, elemental analysis, magnetic and transport…

Superconductivity · Physics 2023-04-26 M. Xu , J. Schmidt , M. A. Tanatar , R. Prozorov , S. L. Bud'ko , P. C. Canfield

The best p-type skutterudites so far are didymium filled, Fe/Co substituted, Sb-based skutterudites. Substitution at the Sb-sites influences the electronic structure, deforms the Sb4-rings, enhances the scattering of phonons on electrons…

Materials Science · Physics 2017-02-16 G. Rogl , A. Grytsiv , P. Heinrich , E. Bauerb , P. Kumar , N. Peranio , O. Eibl , J. Horky , M. Zehetbauer , P. Rogl

Low dimensional structures have demonstrated improved thermoelectric (TE) performance because of a drastic reduction in their thermal conductivity, {\kappa}l. This has been observed for a variety of materials, even for traditionally poor…

Materials Science · Physics 2012-01-31 Neophytos Neophytou , Hans Kosina

Establishing strong electron-correlations not only shed lights on overcoming the trade-off limitations for optimizing thermoelectric materials, but can also introduce new functionalities that extend the vision of conventional thermoelectric…

A drastic variation (~47%) in thermal conductivity (\k{appa}) for synthesized samples (TiCoSb1+x, x=0.0, 0.01, 0.02, 0.03, 0.04, and 0.06) is observed. The lowest \k{appa} is reported for the TiCoSb1.02 sample. Thermal variation of \k{appa}…

Modulation of the grain boundary properties in thermoelectric materials that have thermally activated electrical conductivity is crucial in order to achieve high performance at low temperatures. In this work, we show directly that the…

Materials Science · Physics 2021-04-01 Jianyun Cao , Dursun Ekren , Yudong Peng , Feridoon Azough , Ian A. Kinloch , Robert Freer

We report a study of Co-doped berthierite Fe$_{1-x}$Co$_x$Sb$_2$S$_4$ ($x$ = 0, 0.1, and 0.2). The alloy series of Fe$_{1-x}$Co$_x$Sb$_2$S$_4$ crystallize in an orthorhombic structure with the Pnma space group, similar to FeSb$_2$, and show…

Strongly Correlated Electrons · Physics 2018-04-24 Yu Liu , Chang-Jong Kang , Eli Stavitski , Qianheng Du , Klaus Attenkofer , G. Kotliar , C. Petrovic

The current transport and thermoelectric properties of Fe3O4 / SiO2 / p-type Si(001) heterostructures with Fe3O4 thicknesses of 150, 200, and 350 nm have been investigated between 100 and 300 K. We observe a sharp drop of the in-plane…

Materials Science · Physics 2015-06-19 M. Zervos , Z. Viskadourakis , G. Athanasopoulos , R. Flores , O. Conde , J. Giapintzakis

The electronic structures and thermoelectric properties of $\mathrm{Cs_2[PdCl_4]I_2}$ are investigated by the first-principles calculations and semiclassical Boltzmann transport theory. Both electron and phonon transport are considered to…

Materials Science · Physics 2016-06-21 San-Dong Guo

Defect engineering can improve the linked charge, spin, and lattice behavior of thermoelectric topological insulators. Using density functional theory with spin orbit coupling, we study structural, electronic, optical, thermoelectric,…

Materials Science · Physics 2025-12-15 Muhammad Usman Javed , Sikander Azam , Qaiser Rafiq , Hamdy Khamees Thabet

Slack's phonon-glass and electron-crystal concept has been the guiding paradigm for designing new thermoelectric materials. Zintl phases, in principle, have been shown as great contenders of the concept and thereby good thermoelectric…

Materials Science · Physics 2025-11-11 Vivek Gusain , Mohd Zeeshan , B. K. Mani

A half-Heusler material FeNb$_{0.8}$Ti$_{0.2}$Sb has been identified as a promising thermoelectric material due to its excellent thermoelectric performance at high temperatures. The origins of the efficient thermoelectric performance are…

Materials Science · Physics 2018-08-01 Hong-Jie Pang , Chen-Guang Fu , Hao Yu , Liu-Cheng Chen , Tie-Jun Zhu , Xiao-Jia Chen

Substitution of Sb in FeSb$_2$ by less than 0.5% of Te induces a transition from a correlated semiconductor to an unconventional metal with large effective charge carrier mass $m^*$. Spanning the entire range of the semiconductor-metal…

Materials Science · Physics 2016-08-14 P. Sun , M. Søndergaard , Y. Sun , S. Johnsen , B. B. Iversen , F. Steglich

We present here measurements of the thermopower, thermal conductivity, and electrical resistivity of the newly reported compound CaFe4As3. Evidence is presented from specific heat and electrical resistivity measurements that a substantial…

Strongly Correlated Electrons · Physics 2015-05-28 M. S. Kim , Z. P. Yin , L. L. Zhao , E. Morosan , G. Kotliar , M. C. Aronson

The thermoelectric properties of Sr0.61Ba0.39Nb2O6 ceramics, reduced in different conditions, were investigated in the temperature region from 323 K to 1073 K. The electrical transport behaviors of the samples are dominated by the…

Materials Science · Physics 2015-06-19 Y. Li , J. Liu , C. L. Wang , W. B. Su , Y. H. Zhu , J. C. Li , L. M. Mei