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We report detailed Seebeck coefficient, Hall resistivity as well as specific heat measurement on Ca$_3$Ir$_4$Sn$_{13}$ single crystals. The Seebeck coefficient exhibits a peak corresponding to the anomaly in resistivity at $T^*$, and the…

Superconductivity · Physics 2016-05-02 Kefeng Wang , C. Petrovic

Recently SnSe compound was reported to have a peak thermoelectric figure-5 of-merit (ZT) of 2.62 at 923 K, but the ZT values at temperatures below 750 K are relatively low. In this work, the electronic structures of SnSe are calculated…

Materials Science · Physics 2015-04-09 Aijun Hong , Lin Li , Haixia Zhu , Zhibo Yan , Junming Liu , Zhifeng Ren

We present the thermoelectric (TE) properties of LaCoO$_{3}$ compound in the temperature range 300-600 K. The experimental value of Seebeck coefficient ($\alpha$) at 300 K is found to be $\sim$635 $\mu$V/K. The value of $\alpha$ decreases…

Strongly Correlated Electrons · Physics 2017-04-25 Saurabh Singh , Sudhir K. Pandey

High-entropy concept introduced with a promising paradigm to obtain exotic physical properties has motivated us to explore the thermoelectric properties of Sr-substituted high-entropy rare-earth cobaltates i.e.,…

Materials Science · Physics 2023-03-07 Ashutosh Kumar , Diana Dragoe , David Bérardan , Nita Dragoe

We report on two fold increase in superconducting transition temperature of La3Co4Sn13 by substituting indium at the tin site. The transition temperature of this skutterudite is observed to increase from 2.5 K to 5.1 K for 10 % indium…

Superconductivity · Physics 2015-09-17 P. Neha , P. Srivastava , R. Jha , Shruti , V. P. S. Awana , S. Patnaik

Excellent thermoelectric performance in the out-of-layer n-doped SnSe has been observed experimentally (Chang et al., Science 360, 778-783 (2018)). However, a first-principles investigation of the dominant scattering mechanisms governing…

Materials Science · Physics 2021-09-29 Anderson S. Chaves , Daniel T. Larson , Efthimios Kaxiras , Alex Antonelli

Improvements in the thermoelectric properties of Half-Heusler materials have been achieved by means of a micrometer-scale phase separation that increases the phonon scattering and reduces the lattice thermal conductivity. A detailed study…

Lead chalcogenides are the promising thermoelectric (TE) materials having narrow band gap. The present work investigates the TE behaviour of PbSe in the temperature range 300-500 K. The transport properties of the sample have been studied…

Critical thermoelectric parameters including Seebeck coefficient, electrical conductivity, thermal conductivity and figure of merit ZT of one-dimensional coaxial Bi2Te3/Sb2Te3 nanocomposite were modeled by following the single carrier…

Materials Science · Physics 2011-01-31 Qilin Gu

Recently, a host/guest clathrate SrB3C3 with sp3-bonded boron-carbon framework was synthesized at around 50 GPa. On the basis of electron count, the structure is understood as guest Sr2+ cations intercalated in the (B3C3)3- framework.…

Materials Science · Physics 2022-03-23 Peiyu Zhang , Xue Li , Xin Yang , Hui Wang , Hanyu Liu , Yansun Yao

Superconductivity in noncentrosymmetric compounds has attracted sustained interest in the last decades. Here we present a detailed study on the transport, thermodynamic properties and the band structure of the noncentrosymmetric…

Superconductivity · Physics 2018-01-16 B. Li , C. Q. Xu , W. Zhou , W. H. Jiao , R. Sankar , F. M. Zhang , H. H. Hou , X. F. Jiang , B. Qian , B. Chen , A. F. Bangura , Xiaofeng Xu

In this work, we try to understand the experimental thermoelectric (TE) properties of a ZrNiSn sample with DFT and semiclassical transport calculations using SCAN functional. SCAN and mBJ provide the same band gap $E_{g}$ of $\sim$0.54 eV.…

Strongly Correlated Electrons · Physics 2020-06-24 Shivprasad S. Shastri , Sudhir K. Pandey

It is suggested that low dimensionality can improve the thermoelectric (TE) power factor of a device, offering an enhancement of the ZT figure of merit. In this work the atomistic sp3d5s*-spin-orbit-coupled tight-binding model and the…

Mesoscale and Nanoscale Physics · Physics 2011-06-13 Neophytos Neophytou , Hans Kosina

Lattice thermal conductivity of Cu$_2$O was studied using ab initio density functional methods. The performance of generalized gradient approximation, GGA-PBE, and PBE0 exchange-correlation functionals was compared for various electronic…

Materials Science · Physics 2017-08-01 J. Linnera , A. J. Karttunen

La3Co4Sn13 is a superconducting material with transition temperature at Tc = 2.70 K, which presents a superlattice structural transition at T* ~ 150 K, a common feature for this class of compounds. However, for this material, it is not…

The reduction of dimensionality is an efficient pathway to boost the performances of thermoelectric materials, it leads to the quantum confinement of the carriers and thus to large Seebeck coefficients (S) and it also suppresses the thermal…

Materials Science · Physics 2018-03-14 G. Bouzerar , S. Thébaud , R. Bouzerar , S. Pailhès , Ch. Adessi

We use first-principles electronic structure methods to calculate the electronic thermoelectric properties (i.e. due to electronic transport only) of single-crystalline bulk $n$-type silicon-germanium alloys vs Ge composition, temperature,…

Materials Science · Physics 2025-02-03 F. Murphy-Armando

Sr2VO{3-delta}FeAs superconductors with different oxygen deficiencies have been successfully fabricated. It is found that the superconducting transition temperature drops down monotonically with the increase of oxygen deficiency. The…

Superconductivity · Physics 2016-06-28 Fei Han , Xiyu Zhu , Gang Mu , Peng Cheng , Bing Shen , Bin Zeng , Hai-Hu Wen

We report $^{59}$Co NMR and transport measurements on $n$-type filled skutterudites Ba$_x$Yb$_y$Co$_4$Sb$_{12}$ and $A$$_x$Co$_4$Sb$_{12}$ ($A$= Ba, Sr), promising thermoelectric materials. The results demonstrate consistently that a…

Materials Science · Physics 2019-10-21 Yefan Tian , Ali A. Sirusi , Sedat Ballikaya , Nader Ghassemi , Ctirad Uher , Joseph H. Ross,

High lattice thermal conductivity in half-Heusler alloys has been the major bottleneck in thermoelectric applications. Disordered half-Heusler alloys could be a plausible alternative to this predicament. In this paper, utilizing…

Materials Science · Physics 2023-06-27 Mohd Zeeshan , Chandan Kumar Vishwakarma , B. K. Mani
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