Related papers: Revised Models of Interstellar Nitrogen Isotopic F…
We review the reactions involving HCN and HNC in dark molecular clouds to elucidate new chemical sources and sinks of these isomers. We find that the most important reactions for the HCN-HNC system are Dissociative Recombination (DR)…
Zinc metal-silicate fractionation provides experimental access to the conditions of core formation and Zn has been used to estimate the S contents of the Earth's core and of the bulk Earth, assuming that they share similar volatility and…
We present synthetic line observations of a simulated molecular cloud, utilising a self-consistent treatment of the dynamics and time-dependent chemical evolution. We investigate line emission from the three most common CO isotopologues…
Observations have revealed that the elemental abundances of carbon and oxygen in the warm molecular layers of some protoplanetary disks are depleted compared to those is the interstellar medium by a factor of ~10-100. Meanwhile, little is…
A major motivation of spectroscopic observations of giant exoplanets is to unveil planet formation processes from atmospheric compositions. Several recent studies suggested that atmospheric nitrogen, like carbon and oxygen, can provide…
Neutral hydrogen clouds with high column density detected towards distant quasars are unique probes of elemental nucleosynthesis and chemical evolution in the low metallicity regime. They provide measurements for several elements at very…
We perform a homogeneous analysis of the Fe/Ni abundance ratio in eight Galactic planetary nebulae (PNe) and three Galactic H II regions that include the Orion nebula, where we study four nebular zones and one shocked region. We use [Fe…
The nitrogen chemical evolution during star and planet formation is still not fully understood. Ammonia (NH$_3$) is a key specie in the understanding of the molecular evolution in star-forming clouds and nitrogen isotope fractionation. In…
A new collection of photodissociation and photoionisation cross sections for 102 atoms and molecules of astrochemical interest has been assembled, along with a brief review of the basic processes involved. These have been used to calculate…
We present a first-of-its-kind analysis of the metal content across two interstellar medium (ISM) phases in a sample of 31 local star-forming galaxies from the COS Legacy Archive Spectroscopic SurveY (CLASSY), selected as analogues of…
Our aim is to measure the interstellar 14N/15N ratio across the Galaxy, to establish a standard data set on interstellar ammonia isotope ratios, and to provide new constraints on the Galactic chemical evolution. The (J, K ) = (1, 1), (2,…
We present a sensitive 3-sigma upper limit of 1.1% for the HNC/HCN abundance ratio in comet 73P/Schwassmann-Wachmann (Fragment B), obtained on May 10-11, 2006 using Caltech Submillimeter Observatory (CSO). This limit is a factor of ~7 lower…
Despite low elemental abundance of atomic deuterium in interstellar medium (ISM), observational evidences suggest that several species in gas-phase and in ices could be heavily fractionated. We explore various aspects of deuterium…
Brown dwarfs serve as ideal laboratories for studying the atmospheres of giant exoplanets on wide orbits as the governing physical and chemical processes in them are nearly identical. Understanding the formation of gas giant planets is…
Cosmic rays (CRs) have strong influences on the chemistry of dense molecular clouds (MCs). To study the detailed chemistry induced by CRs, we conducted a Yebes W band line survey towards an unshocked MC (which we named as 3C391:NML)…
Carbon isotope fractionation of CO has been reported in the disk around TW Hya,where elemental carbon is more abundant than elemental oxygen ([C/O]$_{\rm elem}$> 1). We investigated the effects of the [C/O]$_{\rm elem}$ ratio on carbon…
The 12C14N/12C15N and 12C14N/13C14N isotopic ratios are determined for the first time in a Jupiter-family comet, 88P/1981 Q1 Howell, and in the chemically peculiar Oort Cloud comet C/1999 S4 (LINEAR). By comparing these measurements to…
Motivated by the inability of Galactic chemical evolution models to reproduce some of the observed solar neighbourhood distribution of elements (and isotopes) with atomic numbers 6 < Z < 15, we have revisited the relevant stellar and…
We have constructed a 3D photoionisation model of a planetary nebula (PN) similar in structure to NGC 7009 with its outer pair of knots (also known as FLIERs --fast, low-ionization emission regions). The work is motivated by the fact that…
To trace chemical evolution in a prototypical starburst environment, we spatially resolve the carbon and oxygen isotope ratios across the central molecular zone (full size ~$\sim 600$ pc) in the nearby starburst galaxy NGC 253. We imaged…