Related papers: Revised Models of Interstellar Nitrogen Isotopic F…

We present sub-millimeter spectra of HCN isotopologues on Titan, derived from publicly available ALMA flux calibration observations of Titan taken in early 2014. We report the detection of a new HCN isotopologue on Titan, H$^{13}$C$^{15}$,…

The abundances of the isotopes of the elements C, N and O are mainly affected by the cold CNO cycles in non-explosive stellar situations, or by the hot CNO chains that can develop in certain explosive sites, like classical novae. Helium…

The question, what is the role of freeze-out of chemical species in determining the molecular abundances in the interstellar gas is a matter of debate. We investigate a theoretical case of a dense interstellar molecular cloud core by…

Grain surface chemistry and its treatment in gas-grain chemical models is an area of large uncertainty. Whilst laboratory experiments are making progress, there is still much that is unknown about grain surface chemistry. Further, the…

We report high-sensitivity millimetre observations of several molecular species (13CO, HCN, HNC, CN, HCO+ and N2H+) in a sample of compact planetary nebulae. Some species such as HCO+ and CN are particularly abundant compared to envelopes…

Our current understanding of interstellar carbon fractionation hinges on the interpretation of astrochemical kinetic models. Yet, the various reactions included carry large uncertainties in their (estimated) rate coefficients, notably those…

The precipitation of cloud particles in brown dwarf and exoplanet atmospheres establishes an ongoing downward flux of condensable elements. To understand the efficiency of cloud formation, it is therefore crucial to quantify the…

Variations in atmospheric elemental nitrogen can considerably affect the abundance of major nitrogen-bearing species such as NH$_3$ and HCN. Also, due to vertical mixing and photochemistry, their abundance deviates from the thermochemical…

With the chemical reaction rate database UMIST95 (Millar et al. 1997) we analyze how uncertainties in rate constants of gas-phase chemical reactions influence the modelling of molecular abundances in the interstellar medium. Random…

Hypervolatile species such as carbon monoxide (CO) and molecular nitrogen (N2) have been detected in comets, and could be used to constrain comet formation temperature conditions if their presence is due to freeze-out and/or entrapment.…

Context. The recent detection of nitrogen-enhanced, metal-poor galaxies at high redshift by the James Webb Space Telescope has sparked renewed interest in exploring the chemical evolution of carbon, nitrogen, and oxygen (the CNO elements)…

In experiments where ultraviolet light produces aerosols from trace amounts of ozone, sulphur dioxide, and water vapour, the number of additional small particles produced by ionization by gamma sources all grow up to diameters larger than…

We report the first detection of the submm emission from the 13C isotope of atomic carbon in the ISM. The F = 5/2 - 3/2 component of the ^3P_2 - ^3P_1 transition was observed with the CSO in a region ~4' S of Orion IRc2, near the western…

The 12C14N/12C15N and 12C14N/13C14N isotopic ratios have been determined in comets C/1995 O1 (Hale-Bopp), C/2001 Q4 (NEAT) and C/2003 K4 (LINEAR) at heliocentric distances of, respectively, 2.7, 3.7 and 2.6 AU. These ratios have also been…

Atmospheric nitrogen may provide important constraints on giant planet formation. Following our semi-analytical work (Ohno & Fortney 2022), we further pursue the relation between observable NH3 and an atmosphere's bulk nitrogen abundance by…

We present high-resolution (FWHM ~ 0.3-1.5 km/s) spectra of interstellar Ca I absorption toward 30 Galactic stars. Comparisons of the column densities of Ca I, Ca II, K I, and other species -- for individual components identified in the…

(Abridged) We explore the chemistry of the most abundant C, O, S, and N bearing species in molecular clouds, in the context of the IRAM 30 m Large Programme Gas phase Elemental abundances in Molecular Clouds (GEMS). In this work, we aim to…

Nitrogen-bearing complex organic molecules have been commonly detected in the gas phase but not yet in interstellar ices. This has led to the long-standing question of whether these molecules form in the gas phase or in ices. $\textit{James…

Galactic chemical evolution model calculations indicate that there should be considerable scatter in the observed N/O ratios at a fixed metallicity (O/H) for galaxies with very low metallicities due to the delayed release of primary N from…

Aims. The purpose of this study is to investigate the distributions of the isomeric molecules HCN and HNC and estimate their abundance ratio in the protostellar core Cha-MMS1 located in Chamaeleon {\sc i}. Methods. The core was mapped in…