Related papers: Revised Models of Interstellar Nitrogen Isotopic F…
HNC and HCN, typically used as dense gas tracers in molecular clouds, are a pair of isomers that have great potential as a temperature probe because of temperature dependent, isomer-specific formation and destruction pathways. Previous…
The recent observation of complex organic molecules (COMs) in interstellar ices by the James Webb Space Telescope (JWST), along with previous gas-phase detections, underscores the importance of grain surface and ice mantle chemistry in the…
Observations of low mass protostars which probe small enough size scales to be within likely CO depletion regions show the highest [NH2D]/[NH3] ratios yet measured, of 4--33%. These molecular D/H ratios are higher than those measured on…
The Central Molecular Zone (CMZ) contains most of the mass of our Galaxy but its star formation rate is one order of magnitude lower than in the Galactic disc. This is likely related to the fact that the bulk of the gas in the CMZ is in a…
Molecular clouds interacting with supernova remnants may be subject to a greatly enhanced irradiation by cosmic rays produced at the shocked interface between the ejecta and the molecular gas. Over the past decade, broad-band observations…
The hot intra-cluster medium (ICM) is rich in metals, which are synthesised by supernovae (SNe) and accumulate over time into the deep gravitational potential well of clusters of galaxies. Since most of the elements visible in X-rays are…
Understanding the processes that could lead to enrichment of molecules in $^{15}$N atoms is of particular interest in order to shed light on the relatively large variations observed in the $^{14}$N/$^{15}$N ratio in various solar system…
N$_2$ plays a profound role in supporting processes on the surface and in the atmosphere of Pluto, yet the origin of Pluto's N$_2$ remains a mystery. However, this may begin to change as the $^{14}$N/$^{15}$N ratio of N$_2$ was recently…
We have studied the chemistry of nitrogen--bearing species during the initial stages of protostellar collapse, with a view to explaining the observed longevity of N2H+ and NH3 and the high levels of deuteration of these species. We followed…
We show the first interferometric maps of the 14N/15N ratio obtained with the Atacama Large Millimeter Array (ALMA) towards the Solar-like forming protocluster OMC-2 FIR4. We observed N2H+, 15NNH+, N15NH+ (1-0), and N2D+ (2-1), from which…
Samples of pristine Solar System material found in meteorites and interplanetary dust particles are highly enriched in (15)N. Conspicuous nitrogen isotopic anomalies have also been measured in comets, and the (14)N/(15)N abundance ratio of…
Recent JWST observations of the z=10.6 galaxy GN-z11 have revealed a very high gas-phase nitrogen abundance (higher than four times the solar value), a very small half-light radius(~ 60 pc), and a large stellar mass (M_s ~ 10^9 M_sun) for…
We present chemical abundance ratios of 8 nitrogen-rich ([N/O]$>0.3$) galaxies at $z\sim 6-12$ identified by the first 4 years of the JWST observations, and compare these ratios with chemical evolution models. We reanalyze the JWST/NIRSpec…
Comets have similar compositions to interstellar medium ices, suggesting at least some of their molecules maybe inherited from an earlier stage of evolution. To investigate the degree to which this might have occurred we compare the…
We propose a scenario that explains the apparent nitrogen deficiency in comets in a way consistent with the fact that the surfaces of Pluto and Triton are dominated by nitrogen-rich ice. We use a statistical thermodynamic model to…
Atmospheric nitrogen may be a necessary ingredient for the habitability of a planet since its presence helps to prevent water loss from a planet. The present day nitrogen isotopic ratio, $^{15}$N/$^{14}$N, in the Earth's atmosphere is a…
Ammonia is one of the best tracers of cold dense cores. It is also a minor constituent of interstellar ices and, as such, one of the important nitrogen reservoirs in the protosolar nebula, together with the gas phase nitrogen, in the form…
The isotopic ratio of nitrogen presents a wide range of values in the Solar System and in star forming system whose origin is still unclear. Chemical reactions in the gas phase are one of the possible processes that could modify the…
We present submillimeter observations of various molecular ions toward two dense clouds, NGC 2264 IRS1 and W 3 IRS5, in order to investigate their ionization fraction. Analysis of the line intensity ratios by the way of statistical…
We describe a general yet simple method to analyse the propagation of nuclear reaction rate uncertainties in a stellar nucleosynthesis and mixing context. The method combines post-processing nucleosynthesis and mixing calculations with a…