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In this Communication, we provide numerical evidence indicating that the standard single-reference coupled-cluster (CC) energies can be calculated alternatively to its copybook definition. We demonstrate that the CC energies can be…

Quantum Physics · Physics 2023-02-15 Karol Kowalski

It is shown how to adapt the non-perturbative coupled cluster method of many-body theory so that it may be successfully applied to Hamiltonian lattice $SU(N)$ gauge theories. The procedure involves first writing the wavefunctions for the…

High Energy Physics - Lattice · Physics 2009-10-22 C. H. Llewellyn Smith , N. J. Watson

The coupled cluster iteration scheme is analysed as a multivariate discrete-time map using nonlinear dynamics and synergetics. The nonlinearly coupled set of equations to determine the cluster amplitudes are driven by a fraction of the…

Computational Physics · Physics 2021-10-13 Valay Agarawal , Chayan Patra , Rahul Maitra

We obtain results on both weak and almost sure asymptotic behaviour of power variations of a linear combination of independent Wiener process and fractional Brownian motion. These results are used to construct strongly consistent parameter…

Probability · Mathematics 2013-06-20 Marco Dozzi , Yuliya Mishura , Georgiy Shevchenko

The Particle Number Projected Generator Coordinate Method is formulated for the pairing Hamiltonian in a detailed way in the projection after variation and the variation after projection methods. The dependence of the wave functions on the…

Superconductivity · Physics 2009-11-11 M. A. Fernandez , J. L. Egido

Unitary coupled cluster (UCC), originally developed as a variational alternative to the popular traditional coupled cluster method, has seen a resurgence as a functional form for use on quantum computers. However, the number of excitors…

Chemical Physics · Physics 2021-01-07 Maria-Andreea Filip , Alex J. W. Thom

This paper proves a new central limit theorem for a sample that exhibits two-way dependence and heterogeneity across clusters. Statistical inference for situations with both two-way dependence and cluster heterogeneity has thus far been an…

Econometrics · Economics 2024-06-14 Luther Yap

We introduce an approach to improve single-reference coupled cluster theory in settings where the Aufbau determinant is absent from or plays only a small role in the true wave function. Using a de-excitation operator that can be efficiently…

Chemical Physics · Physics 2024-07-03 Harrison Tuckman , Eric Neuscamman

The symmetry and the locality are the two major sources of various nontrivial statements in quantum many-body systems. We demonstrate that, in gapped phases of a U(1) symmetric Hamiltonian with finite-range interactions, the bulk properties…

Statistical Mechanics · Physics 2019-02-26 Haruki Watanabe

Extremal principles can generally be divided into two rather distinct classes. There are, on the one hand side, formulations based on the Lagrangian or Hamiltonian mechanics, respectively, dealing with time dependent problems, but…

Computational Engineering, Finance, and Science · Computer Science 2023-11-08 Klaus Hackl , Jiří Svoboda , Franz Dieter Fischer

The collective Hamiltonian including isovector pairing and $\alpha$-particle type correlation degrees of freedom is constructed. The Hamiltonian is applied to description of the relative energies of the ground states of even-even nuclei…

Nuclear Theory · Physics 2021-11-16 R. V. Jolos , E. A. Kolganova , D. A. Sazonov

An extensive analysis has been carried out of the performance of standard families of basis sets with the hierarchy of coupled cluster methods CC2, CCSD, CC3 and CCSDT in computing selected Oxygen, Carbon and Nitrogen K-edge (vertical) core…

Chemical Physics · Physics 2019-08-13 Johanna P. Carbone , Lan Cheng , Rolf H. Myhre , Devin Matthews , Henrik Koch , Sonia Coriani

We introduce a range-separation approximation to coupled cluster doubles (CCD) theory that successfully overcomes limitations of regular CCD when applied to the uniform electron gas. We combine the short-range ladder channel with the…

Chemical Physics · Physics 2014-05-07 James J. Shepherd , Thomas M. Henderson , Gustavo E. Scuseria

Quantum periodic cluster methods for strongly correlated electron systems are reformulated and developed. The reformulation and development are based on a canonical transformation which periodizes the fermions in the cluster space. The…

Strongly Correlated Electrons · Physics 2007-05-23 Tran Minh-Tien

Theory of one-electron transition density matrices has been formulated within the time-independent coupled cluster method for the polarization propagator [R. Moszynski, P. S. \.Zuchowski, and B. Jeziorski, Coll. Czech. Chem. Commun. {\bf…

Chemical Physics · Physics 2014-09-25 Aleksandra M. Tucholska , Marcin Modrzejewski , Robert Moszynski

The unitary coupled cluster (UCC) approximation is one of the more promising wave-function ans\"atze for electronic structure calculations on quantum computers via the variational quantum eigensolver algorithm. However, for large systems…

Quantum Physics · Physics 2021-09-30 Jia Chen , Hai-Ping Cheng , James K. Freericks

Coupled cluster methods based exclusively on double excitations are comparatively "cheap" and interesting model chemistries, as they are typically able to capture the bulk of the dynamical electron correlation effects. The trade-off in such…

Quantum Physics · Physics 2024-06-14 Zachary W. Windom , Daniel Claudino , Rodney J. Bartlett

Two natural and widely used representations for the community structure of networks are clusterings, which partition the vertex set into disjoint subsets, and layouts, which assign the vertices to positions in a metric space. This paper…

Discrete Mathematics · Computer Science 2009-02-06 Andreas Noack

The different forms of the Hamiltonian formulations of linearized General Relativity/spin-two theories are discussed in order to show their similarities and differences. It is demonstrated that in the linear model, non-covariant…

General Relativity and Quantum Cosmology · Physics 2011-07-18 K. R. Green , N. Kiriushcheva , S. V. Kuzmin

We present a simple variational framework for planar elastica that enables distributed energies, such as gravitational loading or magnetic body torques, to be incorporated in a modular and unified manner. The formulation is based on…

Classical Physics · Physics 2026-05-28 Yimu Mao , Christopher Tropp
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