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Unitary cluster expansions of the electronic wavefunction have recently gained much interest because of their use in conjunction with quantum algorithms. In this contribution, we investigate some aspects of an ansatz using generalized…

Chemical Physics · Physics 2022-10-12 Andreas Köhn , Jeppe Olsen

Fixed effects models are very flexible because they do not make assumptions on the distribution of effects and can also be used if the heterogeneity component is correlated with explanatory variables. A disadvantage is the large number of…

Methodology · Statistics 2015-12-17 Moritz Berger , Gerhard Tutz

The Coupled-Cluster theory is one of the most successful high precision methods used to solve the stationary Schr\"odinger equation. In this article, we address the mathematical foundation of this theory with focus on the advances made in…

Chemical Physics · Physics 2019-09-04 Andre Laestadius , Fabian M. Faulstich

We consider two simple models of higher-derivative and nonlocal quantu systems.It is shown that, contrary to some claims found in literature, they can be made unitary.

Quantum Physics · Physics 2008-11-26 Katarzyna Bolonek , Piotr Kosinski

In truncated coupled-cluster (CC) theories, non-variational and/or generally complex ground-state energies can occur. This is due to the non-Hermitian nature of the similarity transformed Hamiltonian matrix in combination with CC…

Chemical Physics · Physics 2023-09-22 Tanner Culpitt , Erik I. Tellgren , Fabijan Pavosevic

Energetic particle effects in magnetic confinement fusion devices are commonly studied by hybrid kinetic-fluid simulation codes whose underlying continuum evolution equations often lack the correct energy balance. While two different…

Plasma Physics · Physics 2019-01-23 Alexander R. D. Close , Joshua W. Burby , Cesare Tronci

A wide class of coupled-cluster methods is introduced, based on Arponen's extended coupled-cluster theory. This class of methods is formulated in terms of a coordinate transformation of the cluster operators. The mathematical framework for…

Chemical Physics · Physics 2020-12-02 Simen Kvaal , Andre Laestadius , Tilmann Bodenstein

In this paper, we study how the probability of presence of a particle is distributed between the two parts of a composite fermionic system. We uncover that the difference of probability depends on the energy in a striking way and show the…

Statistical Mechanics · Physics 2020-10-20 Filiberto Ares , José G. Esteve , Fernando Falceto , Alberto Usón

Comparing clusterings is central to evaluating unsupervised models, yet the many existing similarity measures can produce widely divergent, sometimes contradictory, evaluations. Clustering similarity measures are typically organized into…

Machine Learning · Statistics 2025-11-06 Alexander J. Gates

It has been hypothesized that some form of "modular" structure in artificial neural networks should be useful for learning, compositionality, and generalization. However, defining and quantifying modularity remains an open problem. We cast…

Machine Learning · Computer Science 2022-06-23 Richard D. Lange , David S. Rolnick , Konrad P. Kording

We apply the coupled cluster method (CCM) to the Hamiltonian version of the latticised O(4) non-linear sigma model. The method, which was initially developed for the accurate description of quantum many-body systems, gives rise to two…

High Energy Physics - Lattice · Physics 2009-10-30 N. E. Ligterink , N. R. Walet , R. F. Bishop

A central problem in many-body quantum physics is the determination of the ground state of a thermodynamically large physical system. We construct a cluster expansion for ground states of local Hamiltonians, which naturally incorporates…

Statistical Mechanics · Physics 2016-07-29 Alvise Bastianello , Spyros Sotiriadis

Motivated by recent progress on non-Hermitian topological band theories, we study the energy spectrum of a generic two-band non-Hermitian Hamiltonian. We prove rigorously that the complex energy spectrum of such a non-Hermitian Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2019-05-24 Jonatan Melkær Midtgaard , Zhigang Wu , Yu Chen

The flexibility of a power generation unit determines how quickly and often it can ramp up or down. In energy models, it depends on assumptions on the technical characteristics of the unit, such as its installed capacity or turbine…

Computers and Society · Computer Science 2025-09-05 Chiara Fusar Bassini , Alice Lixuan Xu , Jorge Sánchez Canales , Lion Hirth , Lynn H. Kaack

The variational cluster approximation is applied to the calculation of the single particle spectral function of NiO. Trial self energies and the numerical value of the Luttinger-Ward functional are obtained by exact diagonalization of…

Strongly Correlated Electrons · Physics 2009-11-13 R. Eder

The coupled cluster iteration scheme for determining the cluster amplitudes involves a set of nonlinearly coupled difference equations. In the space spanned by the amplitudes, the set of equations are analysed as a multivariate…

We present the first formulation and application of relativistic unitary coupled cluster theory to atomic properties. The remarkable features of this theory are highlighted, and it is used to calculate the lifetimes of $5^{2}D_{3/2}$ and…

Atomic Physics · Physics 2007-05-23 Chiranjib Sur , Rajat K Chaudhuri , Bijaya K. Sahoo , B. P. Das , D. Mukherjee

A pedagogical introduction to the cluster-perturbation theory, the variational cluster approximation and to self-energy-functional theory is given. Some standard applications and the relation to dynamical mean-field theory are discussed.

Strongly Correlated Electrons · Physics 2014-09-23 Michael Potthoff

A variational principle for two-fluid mixtures is proposed. The Lagrangian is constructed as the difference between the kinetic energy of the mixture and a thermodynamic potential conjugated to the internal energy with respect to the…

Classical Physics · Physics 2008-02-06 Sergey Gavrilyuk , Henri Gouin , Yurii Perepechko

Coordinate scaling of each spin density separately is considered in spin density functional theory. A virial theorem relates the spin-scaled correlation energy to the spin-scaled correlation potentials. An adiabatic connection formula…

Materials Science · Physics 2009-11-07 R. J. Magyar , T. K. Whittingham , K. Burke