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Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, T_{g}, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for…

Disordered Systems and Neural Networks · Physics 2024-04-24 Joseph B. Schlenoff , Khalil Akkaoui

When classical systems fail to explore their entire configurational space, intriguing macroscopic phenomena like aging and glass formation may emerge. Also closed quanto-mechanical systems may stop wandering freely around the whole Hilbert…

Statistical Mechanics · Physics 2012-02-07 Giuseppe Carleo , Federico Becca , Marco Schiró , Michele Fabrizio

We use computer simulations to study the glass transition of dense fluids made of polydisperse, repulsive spheres. For hard particles, we vary the volume fraction, phi, and use compressible particles to explore finite temperatures, T>0. In…

Statistical Mechanics · Physics 2009-08-25 Ludovic Berthier , Thomas A. Witten

Foams and dense emulsions display complex mechanical behavior, including intermittent rearrangement dynamics, power-law rheology, and slow recovery after perturbation. These effects have long been considered evidence for glassy physics in…

Soft Condensed Matter · Physics 2025-08-01 Amruthesh Thirumalaiswamy , Clary Rodríguez-Cruz , Robert A. Riggleman , John C. Crocker

Glassy systems are disordered systems characterized by extremely slow dynamics. Examples are supercooled liquids, whose dynamics slow down under cooling. The specific pattern of slowing-down depends on the material considered. This…

Disordered Systems and Neural Networks · Physics 2016-04-12 Le Yan

Dynamics is central to living systems. In the last two decades, experiments have revealed that the dynamics in diverse biological systems - from intracellular cytoplasm to cellular and organismal aggregates - are remarkably similar to that…

Soft Condensed Matter · Physics 2024-03-12 Souvik Sadhukhan , Subhodeep Dey , Smarajit Karmakar , Saroj Kumar Nandi

The interrelation of dynamic processes active on separated time-scales in glasses and viscous liquids is investigated using a model displaying two time-scale bifurcations both between fast and secondary relaxation and between secondary and…

Disordered Systems and Neural Networks · Physics 2015-03-19 Andrea Crisanti , Luca Leuzzi , Matteo Paoluzzi

The principal theme of this paper is that anomalously slow, super-Arrhenius relaxations in glassy materials may be activated processes involving chains of molecular displacements. As pointed out in a preceding paper with A. Lemaitre, the…

Materials Science · Physics 2009-11-11 J. S. Langer

We study concentrated binary colloidal suspensions, a model system which has a glass transition as the volume fraction $\phi$ of particles is increased. We use confocal microscopy to directly observe particle motion within dense samples…

Soft Condensed Matter · Physics 2011-05-20 Takayuki Narumi , Scott V. Franklin , Kenneth W. Desmond , Michio Tokuyama , Eric R. Weeks

We theoretically investigate the temperature dependence of the reversible structural relaxation time and diffusion constant of metallic glasses under pressure. The compression not only changes the glassy dynamics, but also generates a…

Materials Science · Physics 2021-05-28 Nguyen K. Ngan , Anh D. Phan , Alessio Zaccone

A new class of lattice gas models with trivial interactions but constrained dynamics are introduced. These are proven to exhibit a dynamical glass transition: above a critical density, rho_c, ergodicity is broken due to the appearance of an…

Statistical Mechanics · Physics 2009-11-11 Cristina Toninelli , Giulio Biroli , Daniel S. Fisher

One of the greatest challenges in contemporary condensed matter physics is to ascertain whether the formation of glasses from liquids is fundamentally thermodynamic or dynamic in origin. While the thermodynamic paradigm has dominated…

Soft Condensed Matter · Physics 2015-06-22 Chandan K. Mishra , K. Hima Nagamanasa , Rajesh Ganapathy , A. K. Sood , Shreyas Gokhale

Understanding dynamical facilitation in nonequilibrium glass-forming systems driven by active forces remains an open challenge. In particular, it is unclear whether facilitation survives in active glasses, where persistent self-propulsion…

Soft Condensed Matter · Physics 2026-04-14 Dipanwita Ghoshal

We simulate the compression of a two-component Lennard-Jones liquid at a variety of constant temperatures using a molecular dynamics algorithm in an isobaric-isothermal ensemble. The viscosity of the liquid increases with pressure,…

chem-ph · Physics 2009-10-22 Shelly L. Shumway , Andrew S. Clarke , Hannes Jónsson

The relaxation dynamics of glass-forming systems shows a multitude of features that are absent in normal liquids, such as non-exponential relaxation and a strong temperature-dependence of the relaxation time. Connecting these dynamic…

Disordered Systems and Neural Networks · Physics 2019-04-03 Zhen Wei Wu , Walter Kob , Wei-Hua Wang , Limei Xu

Using computer simulations, we identify the mechanisms causing aggregation and structural arrest of colloidal suspensions interacting with a short-ranged attraction at moderate and high densities. Two different non-ergodicity transitions…

Condensed Matter · Physics 2009-11-07 Antonio M. Puertas , Matthias Fuchs , Michael E. Cates

If quenched fast enough, a liquid is able to avoid crystallization and will remain in a metastable supercooled state down to the glass transition, with an important increase in viscosity upon further cooling. There are important differences…

Disordered Systems and Neural Networks · Physics 2016-06-01 C. Yildirim , J. -Y. Raty , M. Micoulaut

We present results of temperature dependent measurements of dynamics of micellar nanoparticle - polymer composites of fixed volume fraction and variable polymer chain grafting density. For nanoparticles with lower grafting density we…

Soft Condensed Matter · Physics 2008-09-12 A. K. Kandar , S. Srivastava , J. K. Basu , M. K. Mukhopadhyay , S. Seifert , S. Narayanan

External stress can accelerate molecular mobility of amorphous solids by several orders of magnitude. The changes in mobility are commonly interpreted through the Eyring model, which invokes an empirical activation volume whose origin…

Soft Condensed Matter · Physics 2022-03-14 Entao Yang , Robert A. Riggleman

Fragility, quantifying the rapidity of variation of relaxation times, is analysed for a series of model glass formers, which differ in the softness of their interparticle interactions. In an attempt to rationalize experimental observations…

Soft Condensed Matter · Physics 2017-05-30 Anshul D. S. Parmar , Pallabi Kundu , Srikanth Sastry