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We derive exact fluctuation equalities for open systems that recover free energy differences between two equilibrium endpoints connected by nonequilibrium processes with arbitrary dynamics and coupling. The exponential of the free energy…

Statistical Mechanics · Physics 2025-12-15 Mohammad Rahbar , Christopher J. Stein

The transient quantum fluctuation theorems of Crooks and Jarzynski restrict and relate the statistics of work performed in forward and backward forcing protocols. So far these theorems have been obtained under the assumption that the work…

Statistical Mechanics · Physics 2014-02-07 B. Prasanna Venkatesh , Gentaro Watanabe , Peter Talkner

Work is one of the most basic notion in statistical mechanics, with work fluctuation theorems being one central topic in nanoscale thermodynamics. With Hamiltonian chaos commonly thought to provide a foundation for classical statistical…

Statistical Mechanics · Physics 2017-02-01 Jiawen Deng , Alvis Mazon Tan , Peter Hanggi , Jiangbin Gong

We consider a thermal quantum harmonic oscillator weakly coupled to a heat bath at a different temperature. We analytically study the quantum heat exchange statistics between the two systems using the quantum-optical master equation. We…

Quantum Physics · Physics 2018-11-14 Tobias Denzler , Eric Lutz

We derive analogues of the Jarzynski equality and Crooks relation to characterise the nonequilibrium work associated with changes in the spring constant of an overdamped oscillator in a quadratically varying spatial temperature profile. The…

Statistical Mechanics · Physics 2015-09-30 Ian J. Ford , Robert W. Eyre

The fluctuation theorem of the Crooks type is studied for thermodynamic nonlinear- multivariate systems. In particular, a bivariate system having a limit cycle is discussed in detail. It is explicitly shown how the time reversal operation…

Statistical Mechanics · Physics 2014-02-27 Yasuyuki Matsuo

Fluctuation theorems are fundamental extensions of the second law of thermodynamics for small systems. Their general validity arbitrarily far from equilibrium makes them invaluable in nonequilibrium physics. So far, experimental studies of…

A new effective theory framework for fluctuating hydrodynamics in the relativistic regime is derived using standard thermodynamical principles and general properties of non-equilibrium stochastic dynamics. For the first time, we establish…

Nuclear Theory · Physics 2025-01-09 Nicki Mullins , Mauricio Hippert , Jorge Noronha

Determining the statistics of work done on a quantum system while strongly coupled to a reservoir is a formidable task, requiring the calculation of the full eigenspectrum of the combined system and reservoir. Here we show that this issue…

Quantum Physics · Physics 2026-05-28 Owen Diba , Harry J. D. Miller , Jake Iles-Smith , Ahsan Nazir

We apply the quantum jump approach to address the statistics of work in a driven two-level system coupled to a heat bath. We demonstrate how this question can be analyzed by counting photons absorbed and emitted by the environment in…

Quantum Physics · Physics 2015-06-16 F. W. J. Hekking , J. P. Pekola

A generalized fluctuation-response relation is found for thermal systems driven out of equilibrium. Its derivation is independent of many details of the dynamics, which is only required to be first-order. The result gives a correction to…

Statistical Mechanics · Physics 2009-07-12 Marco Baiesi , Christian Maes , Bram Wynants

The Heisenberg uncertainty relation, which links the uncertainties of the position and momentum of a particle, has an important footprint on the quantum behavior of a physical system. Analogous to this principle, we propose that…

Quantum Physics · Physics 2026-02-18 Pratik Sathe , Luis Pedro García-Pintos , Francesco Caravelli

We formulate a nonequilibrium thermodynamic description for open chemical reaction networks (CRN) described by a chemical master equation. The topological properties of the CRN and its conservation laws are shown to play a crucial role.…

Statistical Mechanics · Physics 2019-01-14 Riccardo Rao , Massimiliano Esposito

To define the work performed on a driven quantum system in a physically sound way has turned out to be a truly non-trivial task, except in some special cases of limited applicability. This topic has been in a focus of intense research…

Statistical Mechanics · Physics 2012-12-27 Jukka P. Pekola , Paolo Solinas , Alexander Shnirman , Dmitri V. Averin

The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2…

Quantum Physics · Physics 2021-04-29 Tobias Denzler , Jonas F. G. Santos , Eric Lutz , Roberto Serra

We show that work distributions and non-equilibrium work fluctuation theorems can be measured in optical spectra for a wide class of quantum systems. We consider systems where the absorption or emission of a photon corresponds to the sudden…

Statistical Mechanics · Physics 2012-07-10 Markus Heyl , Stefan Kehrein

Detailed fluctuation theorem, a microscopic version of the steady state fluctuation theorem, has been proposed by Jarzynski and demonstrated in the case of Hamiltonian systems weakly coupled with reservoirs. We show that an identical…

Statistical Mechanics · Physics 2010-07-20 K. Gururaj , G. Raghavan , M. C. Valsakumar

It is known that temperature estimates of macroscopic systems in equilibrium are most precise when their energy fluctuations are large. However, for nanoscale systems deviations from standard thermodynamics arise due to their interactions…

Quantum Physics · Physics 2018-06-14 Harry J. D. Miller , Janet Anders

The Jarzynski equality relates the free energy difference between two equilibrium states to the fluctuating irreversible work afforded to switch between them. The prescribed fixed temperature for the equilibrium states implicitly constrains…

Statistical Mechanics · Physics 2020-09-03 Tobias Thalheim , Marco Braun , Gianmaria Falasco , Klaus Kroy , Frank Cichos

We study the statistics of heat exchange of a quantum system that collides sequentially with an arbitrary number of ancillas. This can describe, for instance, an accelerated particle going through a bubble chamber. Unlike other approaches…

Quantum Physics · Physics 2020-08-26 Jader P. Santos , André M. Timpanaro , Gabriel T. Landi