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In this note we review recent progress about fluctuation relations and their applicability to free energy recovery in single molecule experiments. We underline the importance of the operational definition for the mechanical work and the…

Statistical Mechanics · Physics 2015-05-27 Anna Alemany , Marco Ribezzi , Felix Ritort

How much work can be extracted from a heat bath using a thermal machine? The study of this question has a very long tradition in statistical physics in the weak-coupling limit, applied to macroscopic systems. However, the assumption that…

Quantum Physics · Physics 2015-06-17 R. Gallego , A. Riera , J. Eisert

We use the quantum Brownian model to derive the uncertainty relation for a quantum open system in an arbitrarily-squeezed initial state interacting with an environment at finite temperature. We examine the relative importance of the quantum…

General Relativity and Quantum Cosmology · Physics 2019-06-05 B. L. Hu , Yuhong Zhang

A colloidal particle immersed in a bath of bacteria is a typical example of a passive particle in an active bath. To model this, we take an overdamped harmonically trapped particle subjected to a thermal and a non-equilibrium noise arising…

Statistical Mechanics · Physics 2018-08-02 Subhasish Chaki , Rajarshi Chakrabarti

For a quantum system coupled to a heat bath environment the strong friction limit is studied starting from the exact path integral formulation. Generalizing the classical Smoluchowski limit to low temperatures a time evolution equation for…

Statistical Mechanics · Physics 2009-11-07 Joachim Ankerhold , Philip Pechukas , Hermann Grabert

We briefly introduce the quantum Jarzynski and Bochkov-Kuzovlev equalities in isolated quantum Hamiltonian systems, which includes the origin of the equalities, their derivations using a quantum Feynman-Kac formula, the quantum Crooks…

Statistical Mechanics · Physics 2015-06-19 Fei Liu , Zhong-can Ou-Yang

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo…

The work is a concept of fundamental importance in thermodynamics. An open question is how to describe the work fluctuation for quantum coherent processes in the presence of initial quantum coherence in the energy basis. With the aim of…

Quantum Physics · Physics 2022-01-05 Gianluca Francica

We theoretically explore the Bochkov-Kuzovlev-Jarzynski-Crooks work theorems in a finite system subject to external control, which is coupled to a heat reservoir. We first elaborate the mechanical energy-balance between the system and the…

Statistical Mechanics · Physics 2015-09-02 Chang Sub Kim

The relation between the distribution of work performed on a classical system by an external force switched on an arbitrary timescale, and the corresponding equilibrium free energy difference, is generalized to quantum systems. Using the…

Statistical Mechanics · Physics 2007-05-23 Shaul Mukamel

Quantum detailed balance conditions and quantum fluctuation relations are two important concepts in the dynamics of open quantum systems: both concern how such systems behave when they thermalize because of interaction with an environment.…

Quantum Physics · Physics 2018-11-14 M. Ramezani , F. Benatti , R. Floreanini , S. Marcantoni , M. Golshani , A. T. Rezakhani

In classical Markov jump processes, current fluctuations can only be reduced at the cost of increased dissipation. To explore how quantum effects influence this trade-off, we analyze the uncertainty of steady-state currents in Markovian…

Statistical Mechanics · Physics 2021-07-09 Paul Menczel , Eetu Loisa , Kay Brandner , Christian Flindt

We study work fluctuation theorems for oscillators in non-Markovian heat baths. By calculating the work distribution function for a harmonic oscillator with motion described by the generalized Langevin equation, the Jarzynski equality (JE),…

Statistical Mechanics · Physics 2009-11-11 Trieu Mai , Abhishek Dhar

This work brings together Keldysh non-equilibrium quantum theory and thermodynamics, by showing that a real-time diagrammatic technique is an equivalent of stochastic thermodynamics for non-Markovian quantum machines (heat engines,…

Mesoscale and Nanoscale Physics · Physics 2021-03-16 Robert S. Whitney

For a small driven system coupled strongly to a heat bath, internal energy and exchanged heat are identified such that they obey the usual additive form of the first law. By identifying this exchanged heat with the entropy change of the…

Statistical Mechanics · Physics 2016-02-03 Udo Seifert

One of the most important goals in quantum thermodynamics is to demonstrate advantages of thermodynamic protocols over their classical counterparts. For that, it is necessary to (i) develop theoretical tools and experimental set-ups to deal…

Quantum Physics · Physics 2019-05-01 Elisa Bäumer , Matteo Lostaglio , Martí Perarnau-Llobet , Rui Sampaio

The problem of construction of a quantum master equation for a system of sites weakly coupled to each other and to one or more reservoirs (open quantum network) is considered. Microscopic derivation of a quantum master equation requires a…

Quantum Physics · Physics 2016-07-27 A. S. Trushechkin , I. V. Volovich

The fluctuation-dissipation relation is usually formulated for a system interacting with a heat bath at finite temperature in the context of linear response theory, where only small deviations from the mean are considered. We show that for…

Quantum Physics · Physics 2013-07-11 C. H. Fleming , B. L. Hu , Albert Roura

Stochastic thermodynamics and the associated fluctuation relations provide the means to extend the fundamental laws of thermodynamics to small scales and systems out of equilibrium. The fluctuating thermodynamic variables are usually…

Statistical Mechanics · Physics 2015-05-29 Aki Kutvonen , Tapio Ala-Nissilä , Jukka P. Pekola

Environments in quantum thermodynamics usually take the role of heat baths. These baths are Markovian, weakly coupled to the system, and initialized in a thermal state. Whenever one of these properties is missing, standard quantum…

Quantum Physics · Physics 2024-08-02 Alessandra Colla , Heinz-Peter Breuer